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Title: A TOUGH2 equation-of-state module for the simulation of two-phase flow of air, water, and a miscible gelling liquid

Technical Report ·
DOI:https://doi.org/10.2172/10104343· OSTI ID:10104343
; ;  [1]
  1. Lawrence Berkeley Lab., CA (United States). Earth Sciences Div.

The injection of grout into the subsurface can be used to encapsulate contaminated regions of an aquifer, or to form underground barriers for the isolation of contaminant sources and to prevent the spreading of existing plumes. This requires identifying grouts, or barrier fluids, which when injected into the subsurface exhibit a large increase in viscosity and eventually solidify, sealing the permeable zones in the aquifer. Simulation and modeling analysis are indispensable tools for designing the injection and predicting the performance of the barrier. In order to model flow and transport in such systems, the thermophysical properties of the fluid mixtures have to be provided, and the governing mass- and energy-balance equations for multiphase flow in porous media have to be solved numerically. The equation-of-state module EOS11 described herein is an extension of the EOS7 module of the TOUGH2 code for flow of saline water and air. In the modeling approach, the chemical grout is treated as a miscible fluid the viscosity of which is a function of time and concentration of the gelling agent in the pore water. If a certain high viscosity is reached and the movement of the grout plume ceases, the gel is assumed to solidify, leading to a new porous medium with changed soil characteristics, i.e. reduced porosity and permeability, increased capillary strength for a given water content, and changed initial saturation distribution.

Research Organization:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC03-76SF00098
OSTI ID:
10104343
Report Number(s):
LBL-36086; ON: DE95004816; TRN: AHC29502%%46
Resource Relation:
Other Information: PBD: May 1994
Country of Publication:
United States
Language:
English