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Licensed Unlicensed Requires Authentication Published by De Gruyter January 23, 2020

Partitioning of V and 19 other trace elements between rutile and silicate melt as a function of oxygen fugacity and melt composition: Implications for subduction zones

  • Megan Holycross EMAIL logo and Elizabeth Cottrell
From the journal American Mineralogist

Abstract

Vanadium is a multivalent element that can speciate as V2+, V3+, V4+, and V5+ over a range of geologically relevant oxygen fugacities (fo2).The abundance of V in planetary materials can be exploited as a proxy for fo2when its partitioning behavior is known. The mineral rutile (TiO2) is an important carrier of the high field strength elements Nb and Ta in the solid Earth, but it can also incorporate substantial quantities of vanadium (up to ~2000 ppm; e.g., Zack et al. 2002). However, little work has been done to systematically investigate how the partitioning of V in rutile-bearing systems changes as a function of both fo2and composition. We measured the partitioning of V and 19 other trace elements (Sc, Cr, Y, Zr, Nb, La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Yb, Lu, Hf, and Ta) between rutile and three silicate melt compositions equilibrated at 1 atm pressure, 1300 °C and fo2values from two log units below the quartz-fayalite-magnetite oxygen buffer (QFM-2) to air (QFM+6.5). Rutile/melt partition coefficients (DVrt/melt)change dynamically over an eight-log unit range of fo2and are greatest at fo2=QFM-2in all compositions. Vanadium solubility in rutile declines continuously as fo2increases from QFM-2 and approaches unity in air. Trace-element partitioning between rutile and melt is also correlated with melt composition, with the greatest values of Drt/melt measured in the most polymerized melt systems containing the least TiO2. We do not find any circumstances where V becomes incompatible in rutile. Our results indicate that rutile is a considerable sink for V at terrestrial fo2values and will contribute to the retention of V in refractory slab residues in subduction zones. In agreement with previous work, we find that DTart/melt>DNbrt/meltunder all conditions investigated, suggesting that rutile fractionation does not lead to low Nb/Ta ratios in Earth’s continental crust.

Acknowledgments and Funding

We thank T. Gooding for his assistance with sample preparation and lab maintenance, R. Wardell for help on the Raman and T. Rose for his oversight of the analytical laboratories. Conversations with M. Ackerson helped shape our discussion of TiO2. We are grateful for editorial handling by K. Kiseeva and thorough reviews by P. Sossi, R. Arató, and anonymous reviewer, which improved the quality of this manuscript. This study was made possible by a Smithsonian Peter Buck Fellowship to M.H. and a gift from the Lyda Hill Foundation to E.C.

References cited

Albarede, F., and Bottinga, Y. (1972) Kinetic disequilibrium in trace element partitioning between phenocrysts and host lava. Geochimica et Cosmochimica Acta, 36, 141–156.10.1016/0016-7037(72)90003-8Search in Google Scholar

Anderson, A.T., Boyd, F.R., Bunch, T.E., Cameron, E.N., El Goresy, A., Finger, L.W., Haggerty, S.E., James, O.B., Keil, K., Prinz, M., and Ramdohr, P. (1970) Armalcolite: a new mineral from the Apollo 11 samples. Geochimica et Cosmochimica Acta Supplement, 1, 55.Search in Google Scholar

Arató, R., and Audétat, A. (2017) Experimental calibration of a new oxybarometer for silicic magmas based on vanadium partitioning between magnetite and silicate melt. Geochimica et Cosmochimica Acta, 209, 284–295.10.1016/j.gca.2017.04.020Search in Google Scholar

Arndt, N., Lehnert, K., and Vasilev, Y. (1995) Meimechites—highly magnesian lithosphere contaminated alkalkine magmas from deep subcontinental mantle. Lithos, 34, 41–59.10.1016/0024-4937(95)90009-8Search in Google Scholar

Aulbach, S., and Stagno, V. (2016) Evidence for a reducing Archean ambient mantle and its effects on the carbon cycle. Geology, 44, 751–754.10.1130/G38070.1Search in Google Scholar

Bak, T., Bogdanoff, P., Fiechter, S., and Nowotny, J. (2012) Defect engineering of titanium dioxide: full defect disorder. Advanced Applied Ceramics, 111, 62–71.10.1179/1743676111Y.0000000027Search in Google Scholar

Barth, M.G., Rudnick, R.L., Horn, I., McDonough, W.F., Spicuzza, M.J., Valley, J.W., and Haggerty, S.E. (2001) Geochemistry of xenolithic eclogites from West Africa, Part I: A link between low MgO eclogites and Archean crust formation. Geochimica et Cosmochimica Acta, 65, 1499–1527.10.1016/S0016-7037(00)00626-8Search in Google Scholar

Berry, A.J., Stewart, G.A., O’Neill, H.S.C., Mallmann, G., and Mosselmans, J.F.W. (2018) A re-assessment of the oxidation state of iron in MORB glasses. Earth and Planetary Science Letters, 483, 114-12310.1016/j.epsl.2017.11.032Search in Google Scholar

Blundy, J., and Wood, B. (2003) Partitioning of trace elements between crystals and melts. Earth and Planetary Science Letters, 210, 383–397.10.1016/S0012-821X(03)00129-8Search in Google Scholar

Borisov, A.A. (2012) The Ti4+/Ti3+ ratio of magmatic melts: application to the problem of the reduction of lunar basalts. Petrology, 20, 391–398.10.1134/S0869591112040030Search in Google Scholar

Borisov, A.A. (2013) Mutual interaction of redox pairs in silicate melts: V5+/V4+/V3+/V2+ tetrad and other equilibria. Petrology, 21, 305–315.10.1134/S0869591113040036Search in Google Scholar

Bromiley, G.D., and Redfern, S.A.T. (2008) The role of TiO2 phases during melting of subduction-modified crust: implications for deep mantle melting. Earth and Planetary Science Letters, 267, 301–308.10.1016/j.epsl.2007.11.033Search in Google Scholar

Canil, D. (1997) Vanadium partitioning and the oxidation state of Archean komatiite magmas. Nature, 389, 842–845.10.1038/39860Search in Google Scholar

Canil, D. (2002) Vanadium in peridotites, mantle redox and tectonic environments: Archean to present. Earth and Planetary Science Letters, 195, 75–90.10.1016/S0012-821X(01)00582-9Search in Google Scholar

Canil, D., and Fedortchouk, Y. (2000) Clinopyroxene-liquid partitioning for vanadium and the oxygen fugacity during formation of cratonic and oceanic lithosphere. Journal of Geophysical Research: Solid Earth, 105, B, 11, 26003–26016.10.1029/2000JB900221Search in Google Scholar

Canil, D., and Fedortchouk, Y. (2001) Olivine-liquid partitioning of vanadium and other trace elements, with applications to modern and ancient picrites. Canadian Mineralogist, 39, 319–330.10.2113/gscanmin.39.2.319Search in Google Scholar

Cherniak, D.J., and Watson, E.B. (2019) Al and Si diffusion in rutile. American Mineralogist, 104, 1638–1649.10.1130/abs/2018AM-318479Search in Google Scholar

Cooper, L.B., Ruscitto, D.M., Plank, T., Wallace, P.J., Syracuse, E.M., and Manning, C.E. (2012) Global variations in H2O/Ce: I. Slab surface temperatures beneath volcanic arcs. Geochemistry, Geophysics, Geosystems, 13, 1–27.10.1029/2011GC003902Search in Google Scholar

Cottrell, E., and Kelley, K.A. (2011) The oxidation state of Fe in MORB glasses and the oxygen fugacity of the upper mantle. Earth and Planetary Science Letters, 305, 270–282.10.1016/j.epsl.2011.03.014Search in Google Scholar

Dasgupta, R., Jackson, M.G., and Lee, C.T.A. (2010) Major element chemistry of ocean island basalts—conditions of mantle melting and heterogeneity of mantle source. Earth and Planetary Science Letters, 289, 377–392.10.1016/j.epsl.2009.11.027Search in Google Scholar

Dickenson, M.P., and Hess, P.C. (1986) The structural role and homogeneous redox equilibria of iron in peraluminous, metaluminous and peralkaline silicate melts. Contributions to Mineralogy and Petrology, 92, 207–217.10.1007/BF00375294Search in Google Scholar

Dingwell, D.B. (1992) Density of some titanium-bearing silicate liquids and the compositional dependence of the partial molar volume of TiO2 Geochimica et Cosmochimica Acta, 56, 3403–3407.10.1016/0016-7037(92)90387-XSearch in Google Scholar

Dohmen, R., Marschall, H.R., Ludwig, T., and Polednia, J. (2018) Diffusion of Zr, Hf, Nb and Ta in rutile: effects of temperature, oxygen fugacity, and doping level, and relation to rutile point defect chemistry. Physics and Chemistry of Minerals, 1–22.10.1007/s00269-018-1005-7Search in Google Scholar

Donaldson, C.H. (1979) Composition changes in a basalt melt contained in a wire loop of Pt80Rh20 effects of temperature, time and oxygen fugacity. Mineralogical Magazine, 43, 115–119.10.1180/minmag.1979.043.325.09Search in Google Scholar

Downs, R.T. (2006) The RRUFF Project: an integrated study of the chemistry, crystallography, Raman and infrared spectroscopy of minerals. Program and Abstracts of the 19th General Meeting of the International Mineralogical Association; Kobe, Japan.Search in Google Scholar

Ducea, M.N., Saleeby, J.B., and Bergantz, G. (2015) The architecture, chemistry and evolution of continental magmatic arcs. Annual Review of Earth and Planetary Sciences, 43, 299–331.10.1146/annurev-earth-060614-105049Search in Google Scholar

Dygert, N., Liang, Y., and Hess, P. (2013) The importance of melt TiO2 in affecting major and trace element partitioning between Fe-Ti oxides and lunar picritic glass melts. Geochimica et Cosmochimica Acta, 106, 134–151.10.1016/j.gca.2012.12.005Search in Google Scholar

Elliott, T. (2003) Tracers of the slab. AGU Geophysical Monograph, 138, 23–45.10.1029/138GM03Search in Google Scholar

Farges, F., and Brown, G.E. (1997) Coordination chemistry of titanium (IV) in silicate glasses and melts: IV. XANES studies of synthetic and natural volcanic glasses and tektites at ambient temperature and pressure. Geochimica et Cosmochimica Acta, 61, 1863–1870.10.1016/S0016-7037(97)00050-1Search in Google Scholar

Farges, F., Brown, G.E., and Rehr, J.J. (1996) Coordination chemistry of Ti (IV) in silicate glasses and melts: I. XAFS study of titanium coordination in oxide model compounds. Geochimica et Cosmochimica Acta, 60, 3023–3038.10.1016/0016-7037(96)00144-5Search in Google Scholar

Frost, D.J., and McCammon, C.A. (2008) The redox state of the Earth’s mantle. Annual Reviews in Earth and Planetary Science, 36, 389–420.10.1146/annurev.earth.36.031207.124322Search in Google Scholar

Foley, S.F., Barth, M.G., and Jenner, G.A. (2000) Rutile/melt partition coefficients for trace elements and an assessment of the influence of rutile on the trace element characteristics of subduction zone magmas. Geochimica et Cosmochimica Acta, 64, 933–938.10.1016/S0016-7037(99)00355-5Search in Google Scholar

Gaetani, G.A., Asimow, P.D., and Stolper, E.M. (2008) A model for rutile saturation in silicate melts with applications to eclogite partial melting in subduction zones and mantle plumes. Earth and Planetary Science Letters, 272, 720–729.10.1016/j.epsl.2008.06.002Search in Google Scholar

Gale, A., Dalton, C.A., Langmuir, C.H., Su, Y., and Schilling, J. (2013) The mean composition of ocean ridge basalts. Geochemistry, Geophysics, Geosystems, 14, 489–518.10.1029/2012GC004334Search in Google Scholar

Gill, J.B. (1981) Orogenic Andesites and Plate Tectonics. Springer-Verlag.10.1007/978-3-642-68012-0Search in Google Scholar

Greegor, R.B., Lytle, W.B., Sandstrom, D.R., Wong, J., and Schultz, P. (1983) Investigation of TiO2-SiO2 glasses by X‑ray absorption spectroscopy. Journal of Non-Crystalline Solids, 55, 27–43.10.1016/0022-3093(83)90005-4Search in Google Scholar

Green, T.H. (2000) New partition coefficient determinations pertinent to hydrous melting processes in subduction zones. In J.P. Davidson, J.A. Davidson, and R.C. Price, Eds., State of the Arc 2000: Processes and Timescales, pp.92–95. Carolyn Bain Publishing House, Wellington.Search in Google Scholar

Green, T.H., and Pearson, N.J. (1986) Ti-rich accessory phase saturation in hydrous mafic-felsic compositions at high P, T. Chemical Geology, 54, 185–201.10.1016/0009-2541(86)90136-1Search in Google Scholar

Green, T.H., and Pearson, N.J. (1987) An experimental study of Nb and Ta partitioning between Ti-rich minerals and silicate liquids at high temperature and pressure. Geochimica et Cosmochimica Acta, 51, 55–62.10.1016/0016-7037(87)90006-8Search in Google Scholar

Grove, T.L. (1982) Use of FePt alloys to eliminate the iron loss problem in 1 atmosphere gas mixing experiments: Theoretical and practical considerations. Contributions to Mineralogy and Petrology, 78, 298–304.10.1007/BF00398924Search in Google Scholar

Guignard, M., Cormier, L., Montouillout, V., Menguy, N., and Massiot, D. (2010) Structural fluctuations and role of Ti as nucleating agent in an aluminosilicate glass. Journal of Non-Crystalline Solids, 356, 1368–1373.10.1016/j.jnoncrysol.2010.04.004Search in Google Scholar

Guo, S., Tang, P., Su, B., Chen, B., Ye, K., Zhang, L., Gao, Y., Liu, J., and Yang, Y. (2017) Unusual replacement of Fe-Ti oxides by rutile during retrogression in amphibolite-hosted veins (Dabie UHP terrane): A mineralogical record of fluid-induced oxidation processes in exhumed UHP slabs. American Mineralogist, 102, 2268–2283.10.2138/am-2017-6120Search in Google Scholar

Hermann, J. (2002) Allanite: thorium and light rare earth element carrier in subducted crust. Chemical Geology, 192, 289–306.10.1016/S0009-2541(02)00222-XSearch in Google Scholar

Hermann, J., and Rubatto, D. (2009) Accessory phase control on the trace element signature of sediment melts in subduction zones. Chemical Geology, 265, 512–526.10.1016/j.chemgeo.2009.05.018Search in Google Scholar

Hills, D.V., and Haggerty, S.E. (1989) Petrochemistry of eclogites from the Koidu kimberlite complex, Sierra Leone. Contributions to Mineralogy and Petrology, 1989, 397–422.10.1007/BF01041749Search in Google Scholar

Hoff, C.M. (2019) Defect thermometry using rutile and feldspar. Ph.D. thesis, Rensselaer Polytechnic Institute.Search in Google Scholar

Hofmann, A.W. (1988) Chemical differentiation of the Earth: the relationship between mantle, continental crust, and oceanic crust. Earth and Planetary Science Letters, 90, 297–314.10.1016/0012-821X(88)90132-XSearch in Google Scholar

Holycross, M.E., and Watson, E.B. (2016) Diffusive fractionation of trace elements in basaltic melts. Contributions to Mineralogy and Petrology, 171, 80–95.10.1007/s00410-016-1289-xSearch in Google Scholar

Holycross, M.E., and Watson, E.B. (2018) Trace element diffusion and kinetic fractionation in wet rhyolitic melt. Geochimica et Cosmochimica Acta, 232, 14–29.10.1016/j.gca.2018.04.006Search in Google Scholar

Horng, W.S., and Hess, P.C. (2000) Partition coefficients of Nb and Ta between rutile and anhydrous haplogranite melts. Contributions to Mineralogy and Petrology, 138, 176–185.10.1007/s004100050016Search in Google Scholar

Jenner, G.A., Foley, S.F., Jackson, S.E., Green, T.H., Fryer, B.J., and Longerich, H.P. (1993) Determination of partition coefficients for trace elements in high pressure-temperature experimental run products by laser ablation microprobe-inductively coupled plasma-mass spectrometry (LAM-ICP-MS). Geochimica et Cosmochimica Acta, 58, 5099–5103.10.1016/0016-7037(93)90611-YSearch in Google Scholar

John, T., Klemd, R., Klemme, S., Pfander, J.A., Hoffmann, J.E., and Gao, J. (2011) Nb-Ta fractionation by partial melting at the titanite-rutile transition. Contributions to Mineralogy and Petrology, 161, 35–45.10.1007/s00410-010-0520-4Search in Google Scholar

Kelemen, P.B., Hanghoj, K., and Greene, A.R. (2003) One view of the geochemistry of subduction-related magmatic arcs, with an emphasis on primitive andesite and lower crust. Treatise on Geochemistry, 3, 659.Search in Google Scholar

Klemme, S., Blundy, J.D., and Wood, B.J. (2002) Experimental constraints on major and trace element partitioning during partial melting of eclogite. Geochimica et Cosmochimica Acta, 66, 3109–3123.10.1016/S0016-7037(02)00859-1Search in Google Scholar

Klemme, S., Prowatke, S., Hametner, K., and Günther, D. (2005) Partitioning of trace elements between rutile and silicate melts: implications for subduction zones. Geochimica et Cosmochimia Acta, 69, 2361–2371.10.1016/j.gca.2004.11.015Search in Google Scholar

Klimm, K., Blundy, J.D., and Green, T.H. (2008) Trace element partitioning and accessory phase saturation during H2O-saturated melting of basalt with implications for subduction zone chemical fluxes. Journal of Petrology, 49, 523–553.10.1093/petrology/egn001Search in Google Scholar

Kofstad, P. (1972) Nonstoichiometry, diffusion and electrical conductivity in binary metal oxides. Wiley, New York.Search in Google Scholar

Kylander-Clark, A.R.C., Hacker, B.R., and Mattinson, J.M. (2008) Slow exhumation of UHP terranes: titanite and rutile ages of the Western Gneiss Region, Norway. Earth and Planetary Science Letters, 272, 531–540.10.1016/j.epsl.2008.05.019Search in Google Scholar

Lanzirotti, A., Dyar, M.D., Sutton, S., Newville, M., Head, E., Carey, C.J., McCanta, M., Lee, L. King, P.L., and Jones, J. (2018) Accurate predictions of microscale oxygen barometry in basaltic glasses using V K-edge X‑ray absorption spectroscopy: A multivariate approach. American Mineralogist, 103, 1282–1297.10.2138/am-2018-6319Search in Google Scholar

Laubier, M., Grove, T.L., and Langmuir, C.H. (2014) Trace element mineral/melt partitioning for basaltic and basaltic andesitic melts: An experimental and laser ICP-MS study with application to the oxidation state of mantle source regions. Earth and Planetary Science Letters, 392, 265–278.10.1016/j.epsl.2014.01.053Search in Google Scholar

Lee, C.T.A., Leeman, W.P., Canil, D., and Li, Z.X.A. (2005) Similar V/Sc systematics in MORB and arc basalts: implications for the oxygen fugacities of their mantle source regions. Journal of Petrology, 46, 2313–2336.10.1093/petrology/egi056Search in Google Scholar

Lee, C.T., Cheng, X., and Horodyskyj, U. (2006) The development and refinement of continental arcs by primary basaltic magmatism, garnet pyroxenite accumulation, basaltic recharge and delamination: insights from the Sierra Nevada, California. Contributions to Mineralogy and Petrology, 151, 222–242.10.1007/s00410-005-0056-1Search in Google Scholar

Leitzke, F.P., Fonesca, R.O.C., Michely, L.T., Sprung, P., Munker, C., Heuser, A., and Blanchard, H. (2016) The effect of titanium on the partitioning behavior of high-field strength elements between silicates, oxides and lunar basaltic melts with applications to the origin of mare basalts. Chemical Geology, 440, 219–238.10.1016/j.chemgeo.2016.07.011Search in Google Scholar

Leitzke, F.P., Fonesca, R.O.C., Göttlicher, J., Steininger, R., Jahn, S., Prescher, C., and Lagos, M. (2018) Ti K-edge XANES study on the coordination number and oxidation state of titanium in pyroxene, olivine, armacolite, ilmenite and silicate glass during mare basalt petrogenesis. Contributions to Mineralogy and Petrology, 173, 103.10.1007/s00410-018-1533-7Search in Google Scholar

Liou, J.G., Zhang, R., Ersnt, W.G., Liu, J., and McLimans, R. (1998) Mineral paragenesis in the Pianpalaudo eclogitic body, Gruppo di Voltri, western Ligurian Alps. Schweizerische Mineralogische und Petrographische Mitteilungen, 78, 317–335.Search in Google Scholar

Liu, L., Xiao, Y., Aulbach, S., Li, D., and Hou, Z. (2014) Vanadium and niobium behavior in rutile as a function of oxygen fugacity: evidence from natural samples. Contributions to Mineralogy and Petrology, 167, 1026.10.1007/s00410-014-1026-2Search in Google Scholar

Mallmann, G., and O’Neill, H.St.C. (2007) The effect of oxygen fugacity on the partitioning of Re between crystals and silicate melt during mantle melting. Geochimica et Cosmochimica Acta, 71, 2837–2857.10.1016/j.gca.2007.03.028Search in Google Scholar

Mallmann, G., and O’Neill, H.St.C. (2009) The crystal/melt partitioning of V during mantle melting as a function of oxygen fugacity compared with some other elements (Al, P, Ca, Sc, Ti, Cr, Fe, Ga, Y, Zr and Nb). Journal of Petrology, 50, 1765–1794.10.1093/petrology/egp053Search in Google Scholar

Mallmann, G., Fonesca, R.O.C., and Silva, A.B. (2014) An experimental study of the partitioning of rutile and silicate melt as a function of oxygen fugacity. Anais da Academia Brasileira de Ciências, 86, 1609–1629.10.1590/0001-3765201420140014Search in Google Scholar

Marschall, H.R., Dohmen, R., and Ludwig, T. (2013) Diffusion-induced fractionation of niobium from tantalum during continental crust formation. Earth and Planetary Science Letters, 375, 361–371.10.1016/j.epsl.2013.05.055Search in Google Scholar

McCallum, I.S., and Charette, M.P. (1978) Zr and Nb partition coefficients: implications for the genesis of mare basalts, KREEP and sea floor basalts. Geochimica et Cosmochimica Acta, 42, 859–869.10.1016/0016-7037(78)90098-4Search in Google Scholar

Meinhold, G. (2010) Rutile and its applications in earth sciences. Earth-Science Reviews, 102, 1–28.10.1016/j.earscirev.2010.06.001Search in Google Scholar

Mysen, B.O. (1983) The structure of silicate melts. Annual Review of Earth and Planetary Sciences, 11, 7597.10.1146/annurev.ea.11.050183.000451Search in Google Scholar

Nowotny, M.K., Sheppard, L.R., Bak, T., and Nowotny, J. (2008) Defect chemistry of titanium dioxide. Application of defect engineering in processing TiO2-based photocatalysts. Journal of Physical Chemistry C, 112, 5275–5300.10.1021/jp077275mSearch in Google Scholar

Papike, J.J., Simon, S.B., Burger, P.V., Bell, A.S., Shearer, C.K., and Karner, J.M. (2016) Chromium, vanadium, and titanium valence systematics in Solar System pyroxene as a recorder of oxygen fugacity, planetary provenance, and processes. American Mineralogist, 101, 907–918.10.2138/am-2016-5507Search in Google Scholar

Paton, C., Hellstrom, J., Paul, B., Woodhead, J., and Hergt, J. (2011) Iolite: Freeware for the visualization and processing of mass spectrometric data. Journal of Analytical Atomic Spectrometry, 26, 2508–2518.10.1039/c1ja10172bSearch in Google Scholar

Pearce, N.J., Perkins, W.T., Westgate, J.A., Gorton, M.P., Jackson, S.E., Neal, C.R., and Chenery, S.P. (1997) A compilation of new and major published major and trace element trace element data for NIST SRM 610 and NIST SRM 612 glass reference materials. Geostandards Newsletter, 21, 115–144.10.1111/j.1751-908X.1997.tb00538.xSearch in Google Scholar

Plank, T., Cooper, L.B., and Manning, C.E. (2009) Emerging geothermometers for estimating slab surface temperatures. Nature Geoscience, 2, 611–615.10.1038/ngeo614Search in Google Scholar

Righter, K., Sutton, S., Danielson, L., Pando, K., Schmidt, G., Yang, H., Berthet, S., Newville, M., Choi, Y., Downs, R.T., and Malavergne, V. (2011) The effect of fo2on the partitioning and valence of V and Cr in garnet/melt pairs and the relation to terrestrial mantle V and Cr content. American Mineralogist, 96, 1278–1290.10.2138/am.2011.3690Search in Google Scholar

Rodriguez-Vargas, A., Koester, E., Mallmann, G., Conceição, R.V., Kawashita, K., and Weber, M.B.I. (2005) Mantle diversity beneath the Colombian Andes, Northern Volcanic Zone: Constraints from Sr and Nd isotopes. Lithos, 82, 471–484.10.1016/j.lithos.2004.09.027Search in Google Scholar

Romano, C., Paris, E., Poe, B.T., Giuli, G., Dingwell, D.B., and Mottana, A. (2000) Effect of aluminum of Ti-coordination in silicate glasses: A XANES study. American Mineralogist, 85, 108–117.10.2138/am-2000-0112Search in Google Scholar

Rudnick, R.L., Barth, M., Horn, I., and McDonough, W.F. (2000) Rutile-bearing refractory eclogites: missing link between continents and the depleted mantle. Science, 287, 278–281.10.1126/science.287.5451.278Search in Google Scholar

Ryerson, P.J., and Hess, P.C. (1978) Implications of liquid-liquid distribution coefficients to mineral-liquid partitioning. Geochimica et Cosmochimica Acta, 42, 921–932.10.1016/0016-7037(78)90103-5Search in Google Scholar

Ryerson, F.J., and Watson, E.B. (1987) Rutile saturation in magmas: implications for Ti-Nb-Ta depletion in island-arc basalts. Earth and Planetary Science Letters, 86, 225–239.10.1016/0012-821X(87)90223-8Search in Google Scholar

Schmidt, M.W., Dardon, A., Chazot, G., and Vannucci, R. (2004) The dependence of Nb and Ta rutile-melt partitioning on melt composition and Nb/Ta fractionation during subduction processes. Earth and Planetary Science Letters, 226, 415–432.10.1016/j.epsl.2004.08.010Search in Google Scholar

Shannon, R.D. (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallography, A32, 751–766.10.1107/S0567739476001551Search in Google Scholar

Shervais, J.W. (1982) Ti-V plots and the petrogenesis of modern and ophiolitic lavas. Earth and Planetary Science Letters, 59, 101–118.10.1016/0012-821X(82)90120-0Search in Google Scholar

Shishkina, T.A., Portnyagin, M.V., Botcharnikov, R.E., Almeev, R.R., Simonyan, A.V., Garbe-Shönberg, D., Schuth, S., Oeser, M., and Holtz, F. (2018) Experimenal calibration and implications of olivine-melt vanadium oxybarometry for hydrous basaltic arc magmas. American Mineralogist, 103, 369–383.10.2138/am-2018-6210Search in Google Scholar

Sisson, T.W., and Kelemen, P.B. (2018) Near-solidus melts of MORB + 4 wt% H2O at 0.8-2.8 GPa applied to issues of subduction magmatism and continent formation. Contributions to Mineralogy and Petrology, 173, 70–93.10.1007/s00410-018-1494-xSearch in Google Scholar

Snetsinger, K.G., Bunch, T.E., and Keil, K. (1968) Electron microprobe analysis of vanadium in the presence of titanium. American Mineralogist, 53, 1770–1773.Search in Google Scholar

Sossi, P.A., and O’Neill, H.St.C. (2016) Liquidus temperatures of komatiites and the effect of cooling rate on element partitioning between olivine and komatiitic melt. Contributions to Mineralogy and Petrology, 171, 49–74.10.1007/s00410-016-1260-xSearch in Google Scholar

Sossi, P.A., Prytulak, J., and O’Neill, H.St.C. (2018) Experimental calibration of vanadium partitioning and stable isotope fractionation between hydrous granitic melt and magnetite at 800 C and 0.5 GPa. Contributions to Mineralogy and Petrology, 173, 27–45.10.1007/s00410-018-1451-8Search in Google Scholar

Stolper, D.A., and Bucholz, C.E. (2019) Neoproterozoic to early Phanerozoic rise in island arc redox state due to deep ocean oxygenation and increased marine sulfate levels. Proceedings of the National Academy of Sciences, 116, 8746–8755.10.1073/pnas.1821847116Search in Google Scholar PubMed PubMed Central

Sutton, S.R., Karner, J., Papike, J., Delaney, J.S., Shearer, C., Newville, M., Eng, P., Rivers, M., and Dyar, M.D. (2005) Vanadium K edge XANES of synthetic and natural basaltic glasses and application to microscale oxygen barometry. Geochimica et Cosmochimica Acta, 69, 2333–2348.10.1016/j.gca.2004.10.013Search in Google Scholar

Syracuse, E.M., van Keken, P.E., and Abers, G.A. (2010) The global range of subduction zone thermal models. Physics of the Earth and Planetary Interiors, 183, 73–90.10.1016/j.pepi.2010.02.004Search in Google Scholar

Tang, M., Lee, C.T.A., Chen, K., Erdman, M., Costin, G., and Jiang, H. (2019) Nb/Ta systematics in arc magma differentiation and the role of arclogites in continent formation. Nature Communications, 10, 235.10.1038/s41467-018-08198-3Search in Google Scholar PubMed PubMed Central

Toplis, M.J., and Corgne, A. (2002) An experimental study of element partitioning between magnetite, clinopyroxene and iron-bearing silicate liquids with a particular emphasis on vanadium. Contributions to Mineralogy and Petrology, 144, 22–37.10.1007/s00410-002-0382-5Search in Google Scholar

Trail, D., Tailby, N., Wang, Y., Harrison, T.M., and Boehnke, P. (2017) Aluminum in zircon as evidence for peraluminous and metaluminous melts from the Hadean to present. Geochemistry, Geophysics, Geosystems, 18, 1580–1593.10.1002/2016GC006794Search in Google Scholar

Turner, S.J., and Langmuir, C.H. (2015) What processes control the chemical compositions of arc front stratovolcanoes? Geochemistry, Geophysics, Geosystems, 16, 1865–1893.10.1002/2014GC005633Search in Google Scholar

van Keken, P.E., Kiefer, P.B., and Peacock, S.M. (2002) High-resolution models of subduction zones: implications for mineral dehydration reactions and transport of water into the deep mantle. Geochemistry Geophysics Geosystems, 3, 1056.10.1029/2001GC000256Search in Google Scholar

Walker, D., Juerwicz, S., and Watson, E.B. (1988) Adcumulus dunite growth in a laboratory thermal-gradient. Contributions to Mineralogy and Petrology, 99, 306–319.10.1007/BF00375364Search in Google Scholar

Wang, J., Xiong, X., Takahashi, E., Zhang, L., Li, L., and Liu, X. (2019) Oxidation state of the arc mantle revealed by partitioning of V, Sc, and Ti between mantle minerals and basaltic minerals. Journal of Geophysical Research: Solid Earth, 124, 4617–4638. https://doi.org/10.1029/2018JB01673110.1029/2018JB016731Search in Google Scholar

Watson, E.B. (1976) Two-liquid partition coefficients: experimental data and geochemical implications. Contributions to Mineralogy and Petrology, 56, 119–134.10.1007/BF00375424Search in Google Scholar

Watson, E.B., and Müller, T. (2009) Non-equilibrium isotopic and elemental fractionation during diffusion-controlled crystal growth under static and dynamic conditions. Chemical Geology, 267, 111–124.10.1016/j.chemgeo.2008.10.036Search in Google Scholar

Wendlandt, R.F. (1990) Partitioning of niobium and tantalum between rutile and silicate melt. EOS AGU Fall Meeting, 71, 1658.Search in Google Scholar

Xiao, Y., Sun, W., Hoefs, J., Simon, K., Zhang, Z., Li, S., and Hofmann, A.W. (2006) Making continental crust through slab melting: constraints from niobium-tantalum fractionation in UHP metamorphic rutile. Geochimica et Cosmochimica Acta, 70, 4770–4782.10.1016/j.gca.2006.07.010Search in Google Scholar

Xiong, X.L., Adam, J., and Green, T.H. (2005) Rutile stability and rutile/melt HFSE partitioning during partial melting of hydrous basalt: implications for TTG genesis. Chemical Geology, 218, 339–359.10.1016/j.chemgeo.2005.01.014Search in Google Scholar

Xiong, X., Keppler, H., Audetat, A., Gudfinnsson, G., Sun, W., Song, M., Xiao, W., and Yuan, L. (2009) Experimental constraints on rutile saturation during partial melting of metabasalt at the amphibolite to eclogite transition, with application to TTG genesis. American Mineralogist, 94, 1175–1186.10.2138/am.2009.3158Search in Google Scholar

Xiong, X., Keppler, H., Audetat, A., Ni, H., Sun, W., and Li, W. (2011) Partitioning of Nb and Ta between rutile and felsic melt and the fractionation of Nb/Ta during partial melting of hydrous metabasalt. Geochimica et Cosmochimica Acta, 75, 1673–1692.10.1016/j.gca.2010.06.039Search in Google Scholar

Zack, T., and Kooijman, E. (2017) Petrology and geochronology of rutile. Reviews in Mineralogy and Geochemistry, 83, 443–467.10.1515/9783110561890-015Search in Google Scholar

Zack, T., Kronz, A., Foley, S.F., and Rivers, T. (2002) Trace element abundances in rutiles from eclogites and associated garnet mica schists. Chemical Geology, 184, 97–122.10.1016/S0009-2541(01)00357-6Search in Google Scholar

Zhang, H.L., Cottrell, E., Solheid, P.A., Kelley, K.A., and Hirschmann, M.M. (2018) Determination of Fe3+/ΣFe of XANES basaltic glass standards by Mössbauer spectroscopy and its application to the oxidation state of iron in MORB. Chemical Geology, 479, 166–175.10.1016/j.chemgeo.2018.01.006Search in Google Scholar

Xirouchakis, D., Hirschmann, M.M., and Simpson, J.A. (2001) The effect of titanium on the silica content and on mineral-liquid partitioning of mantle-equilibrated melts. Geochimica et Cosmochimica Acta, 65, 2201–2217.10.1016/S0016-7037(00)00549-4Search in Google Scholar

Received: 2019-02-20
Accepted: 2019-10-01
Published Online: 2020-01-23
Published in Print: 2020-02-25

© 2020 Walter de Gruyter GmbH, Berlin/Boston

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