石炭科学会議発表論文集
Online ISSN : 2423-8309
Print ISSN : 2423-8295
ISSN-L : 2423-8295
第31回石炭科学会議
会議情報

62.高圧DTA法による芳香族化合物の水素化(3) : デカリンの水素化開裂
山本 光義前河 涌典小谷川 毅
著者情報
会議録・要旨集 フリー

p. 245-248

詳細
抄録

Hydrocracking of cis and trans-Decalin was investigated in the presence of Ru/NiO-ZrO_2-Al_2O_3, Ru/ZnO-ZrO_2-Al_2O_3 and Ru/Fe_2O_3-ZrO_2-Al_2O_3 as catalysts by a high pressure DTA techniques. The Ru/NiO-ZrO_2-Al_2O_3 did not show effective activity for the nuclear hydrocracking of the decalins. On the contrary the Ru/Fe_2O_3-ZrO_2-Al_2O_3 showed a good activity for the nuclear hydrocracking. However, the main products were alkylated cyclohexanes. Any of the catalysts did not show sufficient activity to form paraffinic hydrocarbons. When initial pressure of hydrogen was reduced from 10MPa to 1MPa, the dehydrogenation activity of the decalins was predominant and tetralin was mainly formed. Based on these results, a role of ruthenium is concluded to be the promoter of the hydrocracking of decalins.

著者関連情報
© 1994 一般社団法人 日本エネルギー学会
前の記事 次の記事
feedback
Top