板内玄武岩来源于再循环碳酸盐化榴辉岩的地球化学证据: 以四子王旗新生代玄武岩为例

吴亚东; 杨进辉; 朱昱升

doi:10.18654/1000-0569/2023.09.04

板内玄武岩来源于再循环碳酸盐化榴辉岩的地球化学证据: 以四子王旗新生代玄武岩为例

- 1.
  中国科学院地质与地球物理研究所, 岩石圈演化国家重点实验室, 北京 100029
- 2.
  中国科学院大学地球与行星科学学院, 北京 100049
- 3.
  中国科学院地质与地球物理研究所矿产资源研究院重点实验室, 北京 100029
基金项目:
本文受国家自然科学基金项目(42288201)资助

详细信息

作者简介:
吴亚东, 男, 1991年生, 博士后, 矿物学、岩石学、矿床学专业, E-mail: yadongwu@mail.iggcas.ac.cn

中图分类号: P588.145;P597.2

收稿日期: 2023-04-11

修回日期: 2023-06-11

刊出日期: 2023-09-01

Geochemical evidence for the generation of intraplate basalts from a carbonated eclogite source: A case study from Cenozoic Siziwangqi basalts

- 1.
  State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
- 2.
  College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
- 3.
  Key Laboratory of Mineral Resources, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China

Received Date: 11 April 2023

Revised Date: 11 June 2023

Publish Date: 01 September 2023

摘要

摘要:
本文对中国东部中新世四子王旗玄武岩开展了详细的全岩和橄榄石主、微量元素及全岩Sr-Nd-Pb-Hf-Mg同位素研究, 据此探讨它们的成因及源区性质。研究发现, 四子王旗玄武岩具有类似于高μ(HIMU)型地幔起源熔体的微量元素分布特征, Zr、Hf、Ti的负异常, 高的Zr/Hf比值(Zr/Hf=49.3~54.8), 以及低于正常地幔范围的δ²⁶Mg值(-0.51‰~-0.49‰), 表明其来源于碳酸盐化地幔源区。它们还具有低的Sc含量(10.1×10^-6~10.5×10^-6)和高的Gd/Yb比值(8.7~9.4), 结合它们橄榄石斑晶低的Fo值, 高的NiO含量和Fe/Mn比值, 揭示其母岩浆为碳酸盐化榴辉岩部分熔融产生。四子王旗玄武岩具有亏损的Sr-Nd-Hf同位素(⁸⁷Sr/⁸⁶Sr=0.70370~0.70449;ε_Nd=+6.3~+6.4;ε_Hf=+9.7~+10.3), 以及较低的Pb同位素组成(²⁰⁶Pb/²⁰⁴Pb=17.94, ²⁰⁷Pb/²⁰⁴Pb=15.44, ²⁰⁸Pb/²⁰⁴Pb=37.89), 指示它们源区为年轻的再循环洋壳物质, 很有可能来自于滞留的西太平洋板片。四子王旗玄武岩位于南北重力梯度带以西并远离海沟, 意味着滞留的西太平洋板片在物质上对上覆地幔的影响范围较之前认识的要更广。
- 中国东部 /
- 新生代玄武岩 /
- 碳酸盐化榴辉岩 /
- 西太平洋板片
Abstract:
A detailed study of whole rock and olivine major and trace element and whole rock Sr-Nd-Pb-Hf-Mg isotopic compositions was conducted for the Miocene Siziwangqi basalts in eastern China, to investigate their petrogenesis and the nature of the source. The Siziwangqi basalts exhibit HIMU-like trace element pattern, negative anomalies in Zr, Hf, and Ti, high Zr/Hf ratios (Zr/Hf=49.3~54.8), and δ²⁶Mg values (δ²⁶Mg=-0.51‰~-0.49‰) lower than that of normal mantle range, indicating their derivation from a carbonated mantle source. They have low Sc contents (10.1×10^-6~10.5×10^-6) and high Gd/Yb ratios (8.7~9.4). These characteristics, combined with the low Fo, and high NiO and Fe/Mn of olivine phenocrysts, indicate that the primary melt of the Siziwangqi basalts was generated by the partial melting of carbonated eclogite. The Siziwangqi basalts have depleted Sr-Nd-Hf isotopic compositions (⁸⁷Sr/⁸⁶Sr=0.70370~0.70449; ε_Nd=+6.3~+6.4; ε_Hf=+9.7~+10.3) and relative low Pb isotopic compositions (²⁰⁶Pb/²⁰⁴Pb=17.94, ²⁰⁷Pb/²⁰⁴Pb=15.44, ²⁰⁸Pb/²⁰⁴Pb=37.89), suggesting a young recycled oceanic material in the source that is most likely from the stagnant western Pacific slab. The Siziwangqi basalts are situated to the west of the North-South Gravity Lineament and far from the trench, which implies that the material influence of the stagnant western Pacific slab on the overlying mantle is broader than previously recognized.
- Eastern China /
- Cenozoic basalts /
- Carbonated eclogite /
- Western Pacific slab

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图 1

中国东部新生代玄武岩分布及四子王旗玄武岩采样点

Figure 1.

Distribution of Cenozoic basalts in eastern China and sampling location of the Siziwangqi basalts

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图 2

四子王旗玄武岩典型照片

Figure 2.

Typical photographs of the Siziwangqi basalts

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图 3

四子王旗玄武岩TAS图解(a, 据Le Bas et al., 1986)和原始地幔标准化微量元素蛛网图(b，标准化值据McDonough and Sun, 1995)

Figure 3.

Total alkali versus SiO₂ diagram (a, after Le Bas et al., 1986) and primitive mantle-normalized trace element spider diagram (b, normalization value after McDonough and Sun, 1995) for the Siziwangqi basalts

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图 4

四子王旗玄武岩同位素组成特征

Figure 4.

Isotopic characteristics of the Siziwangqi basalts

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图 5

四子王旗玄武岩微量元素比值和同位素组成关系图解

Figure 5.

Correlation diagrams of trace element ratios and isotopic compositions of the Siziwangqi basalts

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图 6

典型的四子王旗玄武岩橄榄石斑晶(a)和捕掳晶(b)成分剖面

Figure 6.

Typical compositional profiles of olivine phenocryst (a) and xenocryst (b) of the Siziwangqi basalts

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图 7

四子王旗玄武岩橄榄石斑晶成分图

Figure 7.

Diagrams of olivine phenocryst compositions of the Siziwangqi basalts

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图 8

四子王旗玄武岩全岩Mg^#值和橄榄石斑晶核部Fo值图解

Figure 8.

Diagram of host whole-rock Mg^# values versus Fo contents of olivine core for Siziwangqi basalts

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图 9

四子王旗玄武岩的Gd/Yb和Sc组成以及与模拟的碳酸盐化橄榄岩(a)和碳酸盐化辉石岩(b)熔体对比

Figure 9.

Gd/Yb and Sc in Siziwangqi basalts, compared with modeled values of carbonated peridotite (a) and carbonated pyroxenite (b)

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图 10

四子王旗玄武岩原生熔体成分与实验获得的碳酸盐化辉石岩起源熔体成分在从透辉石[Di]投影的橄榄石(Ol)-霞石+钾霞石+钙铝尖晶石(NeKsCal)-石英(Q)相图中对比

Figure 10.

Comparison between Siziwangqi primary melt compositions and experimental partial melts of carbonated pyroxenite in the phase diagram of olivine-nepheline+kalsilite+calcium-aluminum spinel+quartz projected from diopside

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图 11

四子王旗玄武岩源区再循环洋壳组分Pb模式演化蒙特卡洛模拟结果

Figure 11.

Results of Monte Carlo simulations for Pb model evolution of the recycled oceanic crust in the source of Siziwangqi basalts

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表 1

四子王旗新生代玄武岩的主量元素(wt%)、微量元素(×10^-6)和Sr-Nd-Pb-Hf-Mg同位素组成

Table 1.

The measured whole rock major element (wt%), trace element (×10^-6), and Sr-Nd-Pb-Hf-Mg isotope compositions of Cenozoic Siziwangqi basalts

样品号	19JH127	19JH128	样品号	19JH127	19JH128	样品号	19JH127	19JH128
SiO₂	44.31	44.00	Y	24.7	24.9	⁸⁷Sr/⁸⁶Sr	0.703703	0.704494
TiO₂	2.39	2.38	Zr	355	344	1SE	0.000009	0.000005
Al₂O₃	14.16	14.14	Nb	99.8	97.4	¹⁴³Nd/¹⁴⁴Nd	0.512951	0.512959
Fe₂O₃^T	12.04	12.11	Ba	385	390	1SE	0.000004	0.000003
MnO	0.16	0.16	La	67.0	68.5	ε_Nd	6.3	6.4
MnO	0.16	0.16	La	67.0	68.5	¹⁷⁶Hf/¹⁷⁷Hf	0.283076	0.283059
MgO	7.95	7.80	Ce	118	126	1SE	0.000004	0.000003
CaO	7.42	7.52	Pr	14.9	15.1	ε_Hf	10.3	9.7
Na₂O	5.19	5.12	Nd	59.6	60.7	Δε_Hf	-0.6	-1.5
K₂O	2.02	2.28	Sm	11.6	12.2	U^a	0.554	0.581
K₂O	2.02	2.28	Sm	11.6	12.2	Th^a	2.44	2.36
P₂O₅	1.41	1.43	Eu	3.76	3.76	Pb^a	1.36	1.43
LOI	2.17	1.97	Gd	10.1	10.0	²⁰⁶Pb/²⁰⁴Pb^a	17.940	17.940
Total	99.21	98.91	Tb	1.31	1.41	1SE	0.0003	0.0003
Li	10.8	10.6	Dy	6.40	6.48	²⁰⁷Pb/²⁰⁴Pb^a	15.442	15.443
Be	3.9	4.0	Ho	0.97	0.99	1SE	0.0003	0.0003
Sc	10.5	10.1	Er	1.81	2.07	²⁰⁸Pb/²⁰⁴Pb^a	37.892	37.893
Ti	14615	14156	Tm	0.23	0.23	1SE	0.008	0.007
V	123	120	Yb	1.06	1.16	²⁰⁶Pb/²⁰⁴Pb_i	17.855	17.855
Cr	126	129	Lu	0.14	0.15	²⁰⁷Pb/²⁰⁴Pb_i	15.438	15.439
Co	43.3	41.9	Hf	6.47	6.98	²⁰⁸Pb/²⁰⁴Pb_i	37.767	37.779
Ni	143	131	Ta	5.90	6.11	δ²⁵Mg(‰)	-0.26	-0.25
Zn	152	148	Pb	3.85	3.99	2SD^b	0.03	0.01
Rb	25.9	40.6	Th	7.30	7.34	δ²⁶Mg(‰)	-0.51	-0.49
Sr	1537	1725	U	2.35	2.33	2SD^b	0.02	0.05
注：^a淋滤后残余样品粉末U-Th-Pb含量(×10^-6)和Pb同位素比值；^b2SD=重复3次测量同一样品溶液获得的两倍标准差

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表 2

估计的四子王旗玄武岩原生岩浆主量元素(wt%)和Mg同位素组成

Table 2.

Estimated major element (wt%) and Mg isotopic compositions of primary melt of Siziwangqi basalts

样品号	19JH127	19JH128	平均值	样品号	19JH127	19JH128	平均值^*
SiO₂	46.31	46.03	46.17	Na₂O	5.66	5.59	5.62
TiO₂	2.60	2.60	2.60	K₂O	2.21	2.49	2.35
Al₂O₃	15.36	15.36	15.36	K₂O	2.21	2.49	2.35
FeO^T	11.46	11.59	11.52	P₂O₅	1.53	1.56	1.55
MnO	0.17	0.17	0.17	Mg^#	55	55	55
MgO	6.70	6.77	6.74	δ²⁶Mg(‰)	-0.56	-0.53	-0.55
CaO	8.02	8.15	8.09	2SD	0.04	0.07	0.03
注：^*对于δ²⁶Mg，为加权平均值

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