Chronology and geochemistry of Carboniferous-Permian intrusive rocks in Zhuanshanzi mining area, Chifeng, middle part of the northern margin of the North China Craton: Constraints on the tectonic evolution of the Paleo-Asian Ocean
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摘要:
本文对华北克拉通北缘中段赤峰撰山子矿区二长闪长岩、花岗(斑)岩等进行了岩相学、地球化学、锆石U-Pb定年以及Hf同位素研究,以期对古亚洲洋演化形成制约。锆石U-Pb定年显示,二长闪长岩和花岗岩形成于早石炭世(341.0±2.2Ma、324.1±4.3Ma),花岗斑岩形成于晚二叠世(252.8±3.2Ma、252.0±1.5Ma)。岩石地球化学及Hf同位素表明,二长闪长岩为高钾钙碱性I型花岗岩,形成于火山弧环境,其源区可能是俯冲板片脱水交代的地幔楔部分熔融产生玄武质岩浆上涌,导致新生地壳物质的部分熔融,并有部分玄武质岩浆加入形成的产物; 花岗岩及花岗斑岩均为高钾钙碱性A型花岗岩,花岗岩形成于火山弧环境,花岗斑岩形成于造山后伸展环境,二者皆为新生地壳部分熔融的产物。综合前人研究认为,早石炭世-晚二叠世,研究区经历了古亚洲洋俯冲、弧-陆碰撞以及造山后伸展等阶段。
Abstract:In this paper,the lithography,geochemistry,zircon U-Pb dating and Hf isotopes of monzodiorite and granite in Zhuanshanzi mining area,Chifeng,in the middle part of the northern margin of the North China Craton are studied in order to restrict the evolution of the Paleo-Asian Ocean. Zircon U-Pb dating shows that the monzodiorite and granite were formed in the Early Carboniferous (341.0±2.2Ma,324.1±4.3Ma) and the granitic porphyry in the Late Permian (252.8±3.2Ma,252.0±1.5Ma). Geochemistry and Hf isotopes indicate that the monzodiorite is a high-K calc-alkaline I-type granite. It was formed in a volcanic arc environment. The source may be basaltic magma upwelling caused by partial melting of mantle wedge metasomatized by dehydration of subduction plate,leading to partial melting of new crustal material. At the same time,some basaltic magma was added. The granite and granitic porphyry are high-K calc-alkaline A-type granites. Granite is formed in volcanic arc environment and granitic porphyry in post-orogenic extensional environment. They are products of partial melting of the new crust. Combining with previous studies,we concluded that the study area experienced subduction,arc-continent collision and post-orogenic extension of Paleo-Asian Ocean from the Early Carboniferous to the Late Permian.
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Key words:
- North China Craton /
- Chifeng area /
- Paleo-Asian Ocean /
- Zircon U-Pb /
- Geochemistry
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图 1
研究区大地构造位置图(a)和地质简图(b，据杨帆, 2019修改)
Figure 1.
The geotectonic map (a) and geological sketch map (b) of the study area (b, modified after Yang, 2019)
图 2
研究区石炭纪-二叠纪侵入岩镜下特征
Figure 2.
Microscopic characteristics of Carboniferous-Permian intrusive rocks of the study area
图 3
研究区石炭纪-二叠纪锆石阴极发光图像及年龄协和图
Figure 3.
Cathodoluminescence images of selected zircons and zircon U-Pb concordia diagrams from the Carboniferous-Permian of the study area
图 4
研究区石炭纪-二叠纪侵入岩SiO2-(Na2O+K2O)图解(a, 据Irvine and Baragar, 1971)、SiO2-K2O图解(b, 据Peccerillo and Taylor, 1976)、A/CNK-A/NK图解(c, 据Maniar and Piccoli, 1989)和Na2O-K2O图解(d)
Figure 4.
SiO2 vs. Na2O+K2O (a, after Irvine and Baragar, 1971), SiO2 vs. K2O (b, after Peccerillo and Taylor, 1976), A/CNK vs. A/NK (c, Maniar and Piccoli, 1989) and Na2O vs. K2O (d) diagrams for Carboniferous-Permian intrusive rocks of the study area
图 5
研究区石炭世-二叠世侵入岩球粒陨石标准化稀土元素配分图(a, 标准化值据Taylor and McLennan, 1985)和原始地幔标准化微量元素蛛网图(b, 标准化值据Sun and McDonough, 1989)
Figure 5.
Chondrite-normalized REE patterns (a, normalization values after Taylor and Mclennan) and primitive mantle-normalized trace element spider diagrams (b, normalization values after Sun and McDonough, 1989) for the Carboniferous-Permian intrusive rocks of the study area
图 6
研究区石炭纪-二叠纪侵入岩Hf同位素特征图(a, 底图据Yang et al., 2006)和εHf(t)-t图(b)
Figure 6.
Correlations between Hf isotopic compositions and the formation ages (a, base map after Yang et al., 2006) and εHf(t) vs. t (b) for the Carboniferous-Permian intrusive rocks of the study area
图 7
赤峰地区石炭纪-二叠纪侵入岩年龄图谱
Figure 7.
Age map of Carboniferous-Permian intrusive rocks in Chifeng area
图 8
研究区石炭纪-二叠纪侵入岩(Zr+Nb+Ce+Y)-10000Ga/Al (a)、(Zr+Nb+Ce+Y)-(K2O+Na2O)/CaO (b)、SiO2-P2O5 (c)和Y-Ce-Nb (d)图解(a、b, 据Whalen et al., 1987；d, 据Eby, 1992修改)
Figure 8.
Zr+Nb+Ce+Y vs. 10000Ga/Al (a), Zr+Nb+Ce+Y vs. K2O+Na2O/CaO (b), SiO2 vs. P2O5 (c) and Y-Ce vs. Nb (d) diagrams for Carboniferous-Permian intrusive rocks of the study area (a, b, after Whalen et al., 1987; d, after Eby, 1992)
图 9
研究区石炭纪-二叠纪侵入岩Sm-La/Sm图解(据Labanieh et al., 2012)
Figure 9.
Sm vs. La/Sm diagram for Carboniferous-Permian intrusive rocks of the study area (after Labanieh et al., 2012)
图 10
研究区石炭纪-二叠纪花岗岩Y+Nb-Rb(a)和Yb+Ta-Rb(b)图解(底图据Pearce et al., 1984)
Figure 10.
Y+Nb vs. Rb (a) and Yb+Ta vs. Rb (b) diagrams (base map after Pearce et al., 1984) for Carboniferous-Permian intrusive rocks of the study area
表 1
研究区石炭-二叠纪侵入岩锆石LA-ICP-MS U-Pb定年数据
Table 1.
Zriocon LA-ICP-MS U-Pb dating results for the Carboniferous-Permian intrusive rocks of the study area
测点号 Th U Th/U 207Pb/235U 206Pb/238U 207Pb/235U 206Pb/238U (×10-6) 比值 ±1σ 比值 ±1σ 年龄(Ma) ±1σ 年龄(Ma) ±1σ ZS-5-18二长闪长岩 -01 165.9 290.4 0.57 0.3886 0.0116 0.0538 0.0007 333 8 338 4 -02 227.6 281.6 0.81 0.3986 0.0241 0.0547 0.0010 341 17 344 6 -03 474.7 525.3 0.90 0.4012 0.0097 0.0547 0.0007 343 7 343 4 -04 131.0 198.5 0.66 0.4050 0.0187 0.0546 0.0008 345 13 343 5 -05 244.1 272.0 0.90 0.3992 0.0105 0.0546 0.0007 341 8 343 4 -06 123.5 228.0 0.54 0.4486 0.0134 0.0603 0.0008 376 9 377 5 -07 1261 1428 0.88 0.3939 0.0178 0.0535 0.0008 337 13 336 5 -08 310.4 504.8 0.61 0.3918 0.0141 0.0529 0.0007 336 10 332 4 -09 255.1 377.4 0.68 0.4026 0.0168 0.0546 0.0008 344 12 342 5 -10 250.7 346.3 0.72 0.4075 0.0242 0.0555 0.0010 347 17 348 6 -11 519.6 1303 0.40 0.3920 0.0485 0.0543 0.0017 336 35 341 10 -12 292.1 503.1 0.58 0.4032 0.0169 0.0539 0.0008 344 12 338 5 -13 142.3 242.6 0.59 0.4026 0.0333 0.0545 0.0012 344 24 342 7 -14 103.2 163.5 0.63 0.4082 0.0269 0.0550 0.0010 348 19 345 6 -15 202.1 312.1 0.65 0.4507 0.0102 0.0601 0.0007 378 7 376 4 -16 543.3 1105 0.49 0.3952 0.0167 0.0534 0.0008 338 12 335 5 -17 475.3 603.8 0.79 0.4080 0.0096 0.0547 0.0007 347 7 343 4 -18 124.4 208.0 0.60 0.3990 0.0179 0.0542 0.0008 341 13 340 5 -19 235.3 432.9 0.54 11.255 0.1312 0.4919 0.0054 2545 11 2579 23 -20 149.0 208.9 0.71 0.3929 0.0140 0.0545 0.0007 336 10 342 4 -21 111.9 202.8 0.55 0.4130 0.0148 0.0554 0.0008 351 11 348 5 ZS-5-17花岗岩 -01 127.8 244.4 0.52 0.3806 0.0234 0.0515 0.0013 327 17 324 8 -02 326.6 404.1 0.81 0.3804 0.0145 0.0521 0.0012 327 11 327 7 -03 625.8 638.9 0.98 0.3806 0.0160 0.0514 0.0012 327 12 323 7 -04 142.6 277.6 0.51 0.3842 0.0224 0.0514 0.0013 330 16 323 8 -05 447.0 599.5 0.75 0.3763 0.0130 0.0516 0.0012 324 10 324 7 -06 664.2 1303 0.51 0.3791 0.0139 0.0513 0.0012 326 10 322 7 -07 337.0 413.7 0.81 0.3772 0.0157 0.0517 0.0012 325 12 325 7 -08 129.4 241.1 0.54 0.3833 0.0402 0.0519 0.0017 329 30 326 10 -09 669.0 832.6 0.80 0.3799 0.0163 0.0516 0.0012 327 12 324 7 -10 1217 939.3 1.30 0.3855 0.0141 0.0513 0.0012 331 10 322 7 -11 241.9 322.5 0.75 0.5042 0.0141 0.0658 0.0015 415 10 411 9 -12 416.5 713.9 0.58 0.3769 0.0145 0.0519 0.0012 325 11 326 7 -13 143.9 233.7 0.62 0.5043 0.0198 0.0657 0.0015 415 13 410 9 ZS-5-16-1花岗斑岩 -01 169.6 228.2 0.74 0.2841 0.0107 0.0401 0.0009 254 8 254 6 -02 235.4 208.7 1.13 0.2805 0.0183 0.0393 0.0010 251 14 248 6 -03 83.0 76.1 1.09 0.2904 0.0208 0.0405 0.0010 259 16 256 6 -04 484.0 385.3 1.26 0.2872 0.0261 0.0403 0.0012 256 21 255 7 -05 109.9 78.4 1.40 0.2854 0.0354 0.0399 0.0014 255 28 252 8 -06 131.7 149.9 0.88 0.2807 0.0218 0.0400 0.0011 251 17 253 7 -07 414.5 481.1 0.86 0.2802 0.0142 0.0398 0.0010 251 11 251 6 -08 149.9 132.7 1.13 0.2811 0.0160 0.0398 0.0010 252 13 252 6 -09 85.4 61.9 1.38 0.2831 0.0191 0.0400 0.0010 253 15 253 6 -10 114.5 100.9 1.14 0.2831 0.0380 0.0401 0.0015 253 30 253 9 -11 121.6 185.9 0.65 0.2930 0.0377 0.0406 0.0015 261 30 256 9 -12 916.7 716.8 1.28 0.2967 0.0173 0.0406 0.0010 264 14 256 6 -13 141.6 150.0 0.94 0.2825 0.0263 0.0399 0.0012 253 21 252 7 -14 80.6 61.8 1.31 0.2792 0.0382 0.0400 0.0014 250 30 253 9 -15 416.5 360.5 1.16 0.2917 0.0259 0.0399 0.0012 260 20 252 7 -16 774.5 733.9 1.06 0.2792 0.0140 0.0389 0.0009 250 11 246 6 -17 650.9 468.4 1.39 0.2942 0.0125 0.0408 0.0010 262 10 258 6 ZS-5-16-2花岗斑岩 -01 214.0 287.9 0.74 0.2835 0.0078 0.0400 0.0005 253 6 253 3 -02 237.4 254.6 0.93 0.2844 0.0097 0.0400 0.0005 254 8 253 3 -03 827.8 575.4 1.44 0.2879 0.0141 0.0400 0.0006 257 11 253 4 -04 500.3 302.9 1.65 0.2805 0.0086 0.0403 0.0005 251 7 255 3 -05 280.6 222.3 1.26 0.2877 0.0116 0.0399 0.0006 257 9 252 3 -06 494.7 502.7 0.98 0.2699 0.0091 0.0392 0.0005 243 7 248 3 -07 187.9 134.2 1.40 0.2834 0.0110 0.0401 0.0005 253 9 254 3 -08 373.7 266.1 1.40 0.2807 0.0100 0.0398 0.0005 251 8 251 3 -09 233.8 284.8 0.82 0.2768 0.0247 0.0400 0.0009 248 20 253 6 -10 581.6 558.5 1.04 0.2841 0.0102 0.0403 0.0005 254 8 255 3 -11 347.6 366.6 0.95 0.2786 0.0264 0.0400 0.0010 250 21 253 6 -12 441.1 353.6 1.25 0.2746 0.0129 0.0386 0.0006 246 10 244 4 -13 315.6 353.0 0.89 0.2830 0.0089 0.0401 0.0005 253 7 253 3 -14 241.8 233.9 1.03 0.2820 0.0087 0.0400 0.0005 252 7 253 3 -15 208.1 351.7 0.59 0.2830 0.0105 0.0394 0.0005 253 8 249 3 -16 245.1 246.7 0.99 0.2834 0.0115 0.0396 0.0006 253 9 250 3 -17 249.2 153.7 1.62 0.2748 0.0106 0.0399 0.0005 247 8 252 3 -18 206.8 307.3 0.67 0.2878 0.0105 0.0400 0.0005 257 8 253 3 
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表 2
研究区石炭纪-二叠纪侵入岩主量元素(wt%)与微量元素(×10-6)分析结果
Table 2.
Major (wt%) and trace (×10-6) elements for these samples from the Carboniferous-Permian intrusive rocks of the studly area
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表 3
研究区石炭纪-二叠纪侵入岩锆石原位Hf同位素分析结果
Table 3.
Zircon in-situ Hf isotope data for the Carboniferous-Permian intrusive rocks of the study area
测点号 年龄
(Ma)$\frac{{ }^{176} \mathrm{Yb}}{{ }^{177} \mathrm{Hf}}$ ±2σ $\frac{{ }^{176} \mathrm{Lu}}{{ }^{177} \mathrm{Hf}}$ ±2σ $\frac{{ }^{176} \mathrm{Hf}}{{ }^{177} \mathrm{Hf}}$ ±2σ IHf εHf(0) εHf(t) tDM1
(Ma)tDM2
(Ma)fLu/Hf ZS-5-18二长闪长岩 -2 344 0.066678 0.000751 0.001873 0.000020 0.282688 0.000026 0.282676 -2.98 4.16 819 1392 -0.94 -3 343 0.063190 0.000645 0.001783 0.000012 0.282807 0.000024 0.282796 1.25 8.38 644 1010 -0.95 -4 343 0.049768 0.000184 0.001392 0.000002 0.282724 0.000024 0.282715 -1.70 5.52 757 1268 -0.96 -5 343 0.064944 0.000351 0.002230 0.000028 0.282563 0.000035 0.282548 -7.40 -0.37 1009 1799 -0.93 -6 377 0.088835 0.000969 0.003054 0.000076 0.282914 0.000039 0.282892 5.01 12.54 508 656 -0.91 -9 342 0.045227 0.000839 0.001276 0.000025 0.282731 0.000021 0.282723 -1.43 5.79 744 1243 -0.96 -10 348 0.042361 0.000308 0.001255 0.000009 0.282661 0.000023 0.282653 -3.93 3.43 844 1461 -0.96 -13 342 0.059251 0.000212 0.001645 0.000003 0.282642 0.000031 0.282631 -4.60 2.54 880 1537 -0.95 -17 343 0.049008 0.000628 0.001359 0.000016 0.282669 0.000028 0.282660 -3.64 3.59 834 1443 -0.96 -18 340 0.033045 0.000137 0.000954 0.000006 0.282595 0.000026 0.282589 -6.24 1.01 929 1673 -0.97 ZS-5-17花岗岩 -1 324 0.029130 0.000187 0.000860 0.000003 0.282638 0.000023 0.282632 -4.76 2.18 868 1557 -0.97 -2 327 0.076067 0.000730 0.002270 0.000025 0.282687 0.000027 0.282673 -3.01 3.68 829 1424 -0.93 -3 323 0.044176 0.001281 0.001276 0.000038 0.282695 0.000023 0.282687 -2.74 4.08 796 1385 -0.96 -4 323 0.046004 0.000222 0.001353 0.000007 0.282605 0.000023 0.282596 -5.92 0.88 926 1673 -0.96 -5 324 0.036649 0.000307 0.001110 0.000009 0.282630 0.000025 0.282623 -5.02 1.86 884 1586 -0.97 -6 322 0.036145 0.000454 0.001108 0.000011 0.282628 0.000030 0.282621 -5.10 1.73 887 1596 -0.97 -7 325 0.045117 0.000601 0.001345 0.000019 0.282685 0.000033 0.282677 -3.08 3.78 811 1414 -0.96 -9 324 0.055717 0.001752 0.001719 0.000051 0.282729 0.000026 0.282719 -1.51 5.24 756 1281 -0.95 -10 322 0.060582 0.001941 0.001808 0.000057 0.282666 0.000028 0.282655 -3.75 2.94 849 1488 -0.95 -12 326 0.063587 0.000760 0.001914 0.000020 0.282659 0.000030 0.282648 -3.98 2.77 861 1505 -0.94 ZS-5-16-1花岗斑岩 -1 253 0.016708 0.000234 0.000541 0.000006 0.282646 0.000026 0.282643 -4.47 0.99 849 1617 -0.98 -3 256 0.024653 0.000117 0.000811 0.000006 0.282722 0.000028 0.282718 -1.77 3.72 748 1373 -0.98 -4 254 0.033111 0.000093 0.001004 0.000003 0.282632 0.000026 0.282628 -4.94 0.47 878 1665 -0.97 -7 252 0.039437 0.001556 0.001272 0.000042 0.282715 0.000033 0.282709 -2.03 3.29 768 1409 -0.96 -8 253 0.038769 0.000598 0.001200 0.000017 0.282763 0.000035 0.282758 -0.30 5.05 697 1250 -0.96 -9 251 0.031081 0.000652 0.000947 0.000016 0.282674 0.000023 0.282670 -3.45 1.90 818 1534 -0.97 -12 252 0.032939 0.000582 0.001088 0.000017 0.282738 0.000033 0.282733 -1.21 4.14 731 1332 -0.97 -15 253 0.033806 0.000375 0.001111 0.000009 0.282674 0.000034 0.282669 -3.45 1.91 821 1534 -0.97 -17 252 0.027472 0.000363 0.000865 0.000007 0.282717 0.000027 0.282713 -1.96 3.43 757 1396 -0.97 ZS-5-16-2花岗斑岩 -1 253 0.034728 0.000633 0.001110 0.000019 0.282665 0.000025 0.282660 -3.79 1.58 835 1564 -0.97 -2 253 0.037207 0.000850 0.001133 0.000028 0.282547 0.000026 0.282542 -7.94 -2.58 1001 1938 -0.97 -7 254 0.025598 0.000583 0.000836 0.000015 0.282774 0.000035 0.282770 0.07 5.50 675 1210 -0.97 -9 251 0.034171 0.000086 0.001081 0.000002 0.282578 0.000036 0.282573 -6.88 -1.55 958 1844 -0.97 -10 255 0.030896 0.000290 0.000952 0.000007 0.282635 0.000029 0.282630 -4.86 0.58 874 1655 -0.97 -13 244 0.043363 0.000607 0.001381 0.000016 0.282749 0.000031 0.282742 -0.83 4.31 721 1312 -0.96 -14 253 0.048859 0.000775 0.001414 0.000025 0.282694 0.000028 0.282687 -2.77 2.55 800 1476 -0.96 -16 253 0.035030 0.000840 0.001131 0.000030 0.282610 0.000035 0.282605 -5.72 -0.36 913 1738 -0.97 -17 249 0.039069 0.000958 0.001208 0.000031 0.282638 0.000027 0.282632 -4.75 0.52 876 1657 -0.96 -18 250 0.070937 0.000521 0.002025 0.000011 0.282763 0.000037 0.282753 -0.33 4.83 714 1269 -0.94
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