Devonian extension of the eastern section of the northern margin of the North China Plate: Evidence from post-collision magmatic rocks in Changtu area, northern Liaoning Province
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摘要:
华北板块北缘是研究古亚洲洋演化及其与华北克拉通北缘相互作用过程的关键地带，但其晚古生代特别是泥盆纪时期的构造演化一直存在争议，辽北地区出露的泥盆纪岩浆岩为解决这一科学问题提供了新的证据。本文以昌图地区新发现的祥子岭和夏家沟花岗质岩体以及红花店变流纹岩为研究对象，开展了岩相学、地球化学、年代学以及Lu-Hf同位素等研究，并对其岩石成因及构造环境进行了探讨。LA-ICP-MS锆石U-Pb测年结果显示，祥子岭黑云母二长花岗岩侵位年龄为389±2Ma，夏家沟二长花岗岩侵位年龄为377±7Ma，红花店变流纹岩年龄为385±2Ma，是泥盆纪岩浆活动的产物。这些岩石具有高硅(SiO2=71.23%~77.39%)、富碱(K2O+Na2O=8.23%~10.25%)，贫铁(FeOT=1.17%~2.68%)、镁(MgO=0.01%~0.24%)、钙(CaO=0.40%~1.27%)，以及准铝质-弱过铝质(A/CNK=0.84~1.03)的地球化学特征，并且富集Rb、Th、Pb和亏损Ba、P、Ti。结合较低的Zr+Nb+Ce+Y含量(109.4×10-6~329.4×10-6)、10000×Ga/Al比值(0.57~3.59)和锆饱和温度(716~778℃)，昌图泥盆纪岩浆岩表现出高分异I型花岗岩的特征。此外，样品的锆石εHf(t)值皆为正值(6.4~14.6)且随着结晶年龄的年轻而显著升高，表明研究区泥盆纪岩浆岩是幔源基性岩浆与新生地壳再融熔体发生岩浆混合作用的产物，在岩浆演化过程中经历了结晶分离作用。结合区域资料分析，辽北昌图泥盆纪岩浆岩形成于伸展环境，与晚志留世末白乃庙弧与华北克拉通北缘发生弧-陆碰撞后的地壳伸展作用有关。
Abstract:The northern margin of the North China Plate is a key area for studying the evolution of the Paleo-Asian Ocean and its interaction with the northern margin of the North China Craton. However, the tectonic evolution of the North China Plate in the Late Paleozoic, especially in the Devonian Period, has been controversial. The Devonian magmatic rocks exposed in the northern Liaoning provide a new evidence for solving this scientific problem. In this paper, the petrography, geochemistry, chronology and Lu-Hf isotopes of the Xiangziling and Xiajiagou granitic bodies and the Honghuadian meta-rhyolite, which are all newly discovered in the Changtu area, are studied, and their petrogenesis and tectonic environment are also discussed. LA-ICP-MS zircon U-Pb dating results show that the Xiangziling biotite monzogranite is 389±2Ma, the Xiajiagou monzogranite is 377±7Ma, and the Honghuadian metamorphic rhyolite is 385±2Ma, which were the products of Devonian magmatic activity. These rocks are high in silicon (SiO2=71.23%~77.39%), rich in alkali (K2O+Na2O=8.23%~10.25%), poor in iron (FeOT=1.17%~2.68%), magnesium (MgO=0.01%~0.24%), and calcium (CaO=0.40%~1.27%). They also show geochemical characteristics of peraluminous to weakly peraluminous (A/CNK=0.84~1.03), with enrichment of Rb, Th, Pb and depletion of Ba, P, Ti. Given the aforesaid characteristics and low Zr+Nb+Ce+Y content (109.4×10-6~329.4×10-6), 10000×Ga/Al ratio (0.57~3.59) and zirconium saturation temperature (716~778℃), the Changtu Devonian magmatic rocks exhibit the characteristics of highly fractionated I-type granites. In addition, the zircon εHf(t) values of the samples (6.4~14.6) are positive and increase significantly with the age of crystallization, indicating that the Devonian magmatic rocks in the study area were the product of the magmatic mixing between mantle-derived basaltic magma and the remelting of new crust, and experienced crystallization separation during the magmatic evolution. Based on the regional data analysis, the Changtu Devonian magmatic rocks were formed in an extensional environment, which is related to the crustal extension caused by the arc-continent collision between the Bainaimiao arc and the northern margin of the North China Craton at the end of Late Silurian Period.
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图 1
中亚造山带构造简图(a, 据Jahn et al., 2000)和华北板块北缘构造纲要图(b, 据Zhang et al., 2014; Wang et al., 2016; Shi et al., 2022)
Figure 1.
Simplified tectonic map of the Central Asian Orogenic Belt (a, modified after Jahn et al., 2000) and sketch tectonic map of the northern margin of the North China Plate (b, modified after Zhang et al., 2014; Wang et al., 2016; Shi et al., 2022)
图 2
昌图地区地质简图及样品采集位置
Figure 2.
Simplified geological map of Changtu area with the sample locations
图 3
昌图泥盆纪岩浆岩野外和显微照片
Figure 3.
Field and microscopic photos for the Devonian magmatic rocks in the Changtu area
图 4
昌图泥盆纪岩浆岩锆石的代表性阴极发光图像(a、d、g)、协和年龄(b、e、h)和稀土元素特征(c、f、i，标准化值据McDonough and Sun, 1995)
Figure 4.
Cathodoluminescence images of representative zircon grains (a, d, g), concordia diagrams zircon measuring point (b, e, h) and chondrite-normalized REE patterns (c, f, i, normalization values after McDonough and Sun, 1995) from the Devonian magmatic rocks in the Changtu area
图 5
昌图泥盆纪岩浆岩TAS图解(a, 据Irvine and Baragar, 1971)、K2O-SiO2图解(b, 据Peccerillo and Taylor, 1976)和A/CNK-A/NK图解(c, 据Maniar and Piccoli, 1989)
Figure 5.
TAS (a, after Irvine and Baragar, 1971), K2O vs. SiO2 (b, after Peccerillo and Taylor, 1976) and A/CNK vs. A/NK (c, after Maniar and Piccoli, 1989) diagram of the Devonian magmatic rocks in the Changtu area
图 6
昌图泥盆纪岩浆岩球粒陨石标准化稀土元素配分模式(a, 标准化值据Boynton, 1984)和原始地幔标准化微量元素蛛网图(b, 标准化值据McDonough and Sun, 1995)
Figure 6.
Chondrite-normalized REE patterns (a, normalization values after Boynton, 1984) and primitive mantle-normalized trace element spider diagram (b, normalization values after McDonough and Sun, 1995) for the Devonian magmatic rocks in the Changtu area
图 7
昌图泥盆纪岩浆岩的Hf同位素特征(底图据张琪琪, 2021)
Figure 7.
Zircon Hf isotopic compositions of the Devonian magmatic rocks in the Changtu area (base map after Zhang, 2021)
图 8
昌图泥盆纪岩浆岩的成因类型判别图(据Whalen et al., 1987)
Figure 8.
Genetic type discrimination diagrams for the Devonian magmatic rocks in the Changtu area (after Whalen et al., 1987)
图 9
昌图泥盆纪岩浆岩SiO2-P2O5图解(a)、Rb-Y图解(b)和Rb-Th图解(c)(据Chappell, 1999)
Figure 9.
SiO2 vs. P2O5 diagram (a), Rb vs. Y diagram (b) and Rb vs. Th diagram (c) of the Devonian magmatic rocks in the Changtu area (after Chappell, 1999)
图 10
昌图泥盆纪岩浆岩结晶分异作用过程判别图解(底图据Geng et al., 2011; Blundy and Shimizu, 1991; Ewart and Griffin, 1994; Zhang et al., 2015)
Figure 10.
Discrimination diagrams showing the fractional crystallization process of the Devonian magmatic rocks in the Changtu area (base map after Geng et al., 2011; Blundy and Shimizu, 1991; Ewart and Griffin, 1994; Zhang et al., 2015)
图 11
昌图泥盆纪花岗岩构造环境判别图(据Pearce et al., 1984)
Figure 11.
Discrimination diagram of tectonic setting for the Devonian granites in the Changtu area (after Pearce et al., 1984)
表 1
昌图泥盆纪岩浆岩LA-ICP-MS锆石U-Pb分析结果
Table 1.
LA-ICP-MS zircon U-Pb data of the Devonian magmatic rocks in the Changtu area
测点号 含量(×10-6) Th/U 同位素比值 年龄(Ma) Th U 
1σ 
1σ 
1σ 
1σ 
1σ 
1σ 样品235-20黑云母二长花岗岩，206Pb/238U加权平均年龄为389±2Ma(MSWD=0.32，n=23) -01 1099 991 1.11 0.0538 0.0009 0.4641 0.0081 0.0623 0.0006 361 37 387 6 389 4 -02 729 1038 0.70 0.0547 0.0010 0.4723 0.0091 0.0623 0.0007 467 39 393 6 390 4 -03 897 1211 0.74 0.0563 0.0009 0.481 7 0.0090 0.0617 0.0007 465 37 399 6 386 4 -04 794 1131 0.70 0.0542 0.0008 0.4723 0.0083 0.0628 0.0007 389 33 393 6 393 4 -05 1066 1274 0.84 0.0556 0.0009 0.4834 0.0084 0.0627 0.0006 439 3 400 6 392 4 -06 1142 1239 0.92 0.0546 0.0010 0.4724 0.0089 0.0625 0.0007 394 34 393 6 391 4 -07 930 473 1.97 0.0573 0.0014 0.4947 0.0119 0.0624 0.0007 506 58 408 8 390 4 -08 658 927 0.71 0.0525 0.0010 0.4525 0.0089 0.0622 0.0007 306 43 379 6 389 4 -09 1373 1554 0.88 0.0524 0.0008 0.4499 0.0079 0.0619 0.0006 302 3 377 6 387 4 -10 1355 1221 1.11 0.0537 0.0009 0.4661 0.0080 0.0627 0.0006 367 37 388 6 392 3 -11 684 1073 0.64 0.0541 0.0010 0.4694 0.0093 0.0627 0.0008 376 43 391 6 392 5 -12 821 1031 0.80 0.0536 0.0010 0.4647 0.0090 0.0627 0.0007 354 43 388 6 392 4 -13 910 1242 0.73 0.0534 0.0010 0.4586 0.0088 0.0621 0.0008 346 41 383 6 389 5 -14 601 871 0.69 0.0534 0.0011 0.4592 0.0091 0.0623 0.0007 346 46 384 6 390 4 -15 1149 1486 0.77 0.0530 0.0011 0.4501 0.0094 0.0614 0.0007 328 46 377 7 384 4 -16 1281 1690 0.76 0.0550 0.0008 0.4704 0.0070 0.0619 0.0005 413 27 391 5 387 3 -17 1131 1449 0.78 0.0562 0.0009 0.4801 0.0081 0.0618 0.0006 461 31 398 6 387 4 -19 722 921 0.78 0.0562 0.0010 0.4834 0.0098 0.0623 0.0007 457 41 400 7 389 4 -20 898 1291 0.70 0.0559 0.0011 0.4776 0.0093 0.0620 0.0007 456 10 396 6 388 4 -21 934 1372 0.68 0.0550 0.0009 0.4728 0.0082 0.0623 0.0006 409 42 393 6 390 4 -22 1216 1492 0.82 0.0557 0.0008 0.4816 0.0078 0.0625 0.0007 443 31 399 5 391 4 -23 435 848 0.51 0.0558 0.0011 0.4757 0.0090 0.0617 0.0006 456 10 395 6 386 4 -25 1147 1299 0.88 0.0560 0.0012 0.4800 0.0108 0.0620 0.0007 450 16 398 7 388 4 样品235-9二长花岗岩，206Pb/238U加权平均年龄为377±2Ma(MSWD=0.44，n=18) -01 532 794 0.67 0.0536 0.0011 0.4400 0.0091 0.0595 0.0007 354 44 370 6 372 4 -02 1611 2202 0.73 0.0540 0.0007 0.4512 0.0069 0.0604 0.0007 372 62 378 5 378 4 -03 621 1180 0.53 0.0539 0.0009 0.4499 0.0077 0.0605 0.0006 365 69 377 5 378 4 -05 1066 995 1.07 0.0558 0.0011 0.4633 0.0101 0.0601 0.0008 443 44 387 7 376 5 -06 315 576 0.55 0.0538 0.0013 0.4511 0.0111 0.0607 0.0006 361 54 378 8 380 4 -08 1844 2354 0.78 0.0540 0.0010 0.4518 0.0110 0.0603 0.0009 372 43 379 8 377 5 -09 369 615 0.60 0.0542 0.0012 0.4448 0.0095 0.0594 0.0006 389 50 374 7 372 4 -10 781 969 0.81 0.0534 0.0009 0.4415 0.0082 0.0597 0.0006 346 39 371 6 374 4 -11 933 1130 0.83 0.0537 0.0008 0.4455 0.0076 0.0599 0.0006 367 35 374 5 375 3 -12 780 907 0.86 0.0532 0.0009 0.4409 0.0083 0.0598 0.0006 345 37 371 6 374 4 -13 509 758 0.67 0.0539 0.0011 0.4520 0.0091 0.0607 0.0007 365 44 379 6 380 4 -14 445 635 0.70 0.0524 0.0014 0.4317 0.0113 0.0596 0.0008 302 61 364 8 373 5 -15 589 828 0.71 0.0517 0.0010 0.4331 0.0080 0.0606 0.0006 333 47 365 6 379 4 -16 1072 1552 0.69 0.0520 0.0009 0.4355 0.0081 0.0604 0.0006 287 36 367 6 378 4 -17 784 1389 0.56 0.0541 0.0011 0.4535 0.0094 0.0604 0.0006 376 44 380 7 378 3 -18 1901 2361 0.81 0.0528 0.0010 0.4421 0.0085 0.0606 0.0007 320 44 372 6 379 4 -19 870 1012 0.86 0.0521 0.0012 0.4353 0.0103 0.0603 0.0006 300 52 367 7 377 4 -20 422 742 0.57 0.0536 0.0015 0.4506 0.0124 0.0607 0.0007 367 58 378 9 380 4 样品GZ05-1变流纹岩，206Pb/238U加权平均年龄为385±2Ma(MSWD=0.32，n=36) -1 688 990 0.69 0.0546 0.0010 0.4663 0.0083 0.0618 0.0006 394 41 389 6 387 4 -2 209 330 0.63 0.0556 0.0012 0.4750 0.0110 0.0617 0.0007 435 48 395 8 386 4 -5 177 312 0.57 0.0549 0.0014 0.4629 0.0126 0.0610 0.0008 406 59 386 9 382 5 -7 210 300 0.70 0.0565 0.0016 0.4814 0.0138 0.0616 0.0008 472 95 399 9 385 5 -8 117 173 0.68 0.0519 0.0018 0.4415 0.0156 0.0614 0.0008 280 84 371 11 384 5 -9 536 493 1.09 0.0574 0.0020 0.4913 0.0170 0.0618 0.0010 506 81 406 12 387 6 -10 187 346 0.54 0.0539 0.0015 0.4610 0.0134 0.0614 0.0008 365 64 385 9 384 5 -11 321 447 0.72 0.0553 0.0012 0.4646 0.0104 0.0606 0.0007 433 48 387 7 379 4 -12 619 1124 0.55 0.0546 0.0009 0.4639 0.0079 0.0612 0.0007 398 35 387 5 383 4 -13 789 1206 0.65 0.0541 0.0011 0.4651 0.0096 0.0619 0.0007 376 44 388 7 387 4 -14 346 515 0.67 0.0541 0.0011 0.4588 0.0094 0.0610 0.0006 376 44 383 7 382 4 -15 375 296 1.27 0.0568 0.0020 0.4843 0.0163 0.0617 0.0009 483 78 401 11 386 6 -16 294 350 0.84 0.0549 0.0015 0.4748 0.0142 0.0621 0.0007 409 68 394 10 389 4 -17 121 199 0.61 0.0563 0.0023 0.4815 0.0193 0.0619 0.0012 465 89 399 13 387 7 -19 254 412 0.62 0.0572 0.0012 0.4879 0.0110 0.0615 0.0008 502 46 403 8 385 5 -20 210 249 0.85 0.0558 0.0013 0.4793 0.0119 0.0619 0.0008 456 54 398 8 387 5 -21 439 563 0.78 0.0577 0.0012 0.4931 0.0105 0.0616 0.0006 520 46 407 7 385 4 -22 318 370 0.86 0.0534 0.0014 0.4572 0.0114 0.0619 0.0007 343 90 382 8 387 4 -23 162 222 0.73 0.0557 0.0016 0.4739 0.0139 0.0615 0.0007 439 67 394 10 384 4 -24 474 791 0.60 0.0554 0.0012 0.4714 0.0102 0.0614 0.0007 428 44 392 7 384 4 -25 288 375 0.77 0.0551 0.0014 0.4736 0.0120 0.0621 0.0008 417 56 394 8 388 5 -26 166 190 0.87 0.0586 0.0019 0.4987 0.0151 0.0621 0.0009 554 77 411 10 388 6 -27 243 350 0.69 0.0561 0.0014 0.4722 0.0116 0.0610 0.0008 457 28 393 8 382 5 -28 583 809 0.72 0.0546 0.0011 0.4622 0.0100 0.0613 0.0008 394 46 386 7 383 5 -29 756 1123 0.67 0.0550 0.0010 0.4708 0.0091 0.0619 0.0007 409 39 392 6 387 4 -30 176 235 0.75 0.0598 0.0017 0.4972 0.0133 0.0606 0.0008 594 27 410 9 379 5 -31 200 254 0.79 0.0582 0.0019 0.4852 0.0156 0.0605 0.0008 539 70 402 11 379 5 -32 959 1084 0.88 0.0556 0.0013 0.4746 0.0117 0.0618 0.0008 439 50 394 8 387 5 -33 167 257 0.65 0.0556 0.0016 0.4719 0.0137 0.0618 0.0008 439 65 392 9 387 5 -34 382 389 0.98 0.0553 0.0014 0.4721 0.0133 0.0617 0.0008 433 57 393 9 386 5 -35 233 287 0.81 0.0566 0.0015 0.4799 0.0123 0.0619 0.0008 476 92 398 8 387 5 -36 637 946 0.67 0.0563 0.0013 0.4764 0.0132 0.0610 0.0009 465 55 396 9 382 5 -37 308 347 0.89 0.0537 0.0013 0.4546 0.0116 0.0614 0.0007 367 56 380 8 384 4 -38 160 234 0.68 0.0544 0.0015 0.4623 0.0140 0.0615 0.0007 387 65 386 10 385 4 -39 195 225 0.87 0.0546 0.0018 0.4615 0.0158 0.0613 0.0009 394 81 385 11 384 6 -40 268 358 0.75 0.0536 0.0015 0.4570 0.0134 0.0616 0.0008 367 58 382 9 386 5 
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表 2
昌图区泥盆纪岩浆岩的主量元素(wt%)、稀土和微量元素(×10-6)分析结果
Table 2.
Major element (wt%) and trace element (×10-6) compositions of the Devonian magmatic rocks in the Changtu area
样品号 235-20 CT12 CT13 CT14 235-5 235-9 235-11 235-19 GZ05-1 GZ05-2 GZ05-4 GZ05-14 岩性 黑云母二长花岗岩 二长花岗岩 变流纹岩 岩体 祥子岭岩体 夏家沟岩体 泥盆纪变质火山-沉积岩 SiO2 74.71 76.83 75.48 77.39 75.66 76.21 74.51 72.84 74.75 74.51 75.71 71.23 TiO2 0.22 0.14 0.23 0.12 0.18 0.13 0.15 0.21 0.13 0.16 0.12 0.21 Al2O3 12.57 12.21 12.97 12.05 11.54 12.48 12.69 12.99 13.64 13.86 12.98 13.78 Fe2O3 1.37 0.95 1.08 0.68 1.61 1.18 1.37 1.56 0.88 1.06 0.86 2.12 FeO 0.46 0.54 0.60 0.56 0.54 0.58 0.42 0.50 0.62 0.66 0.67 0.77 MnO 0.04 0.02 0.04 0.03 0.08 0.06 0.06 0.08 0.07 0.05 0.05 0.1 MgO 0.10 0.04 0.10 0.06 0.01 0.01 0.07 0.24 0.04 0.07 0.08 0.02 CaO 0.74 0.57 0.85 0.58 0.55 0.74 0.93 1.27 0.40 0.71 0.42 1.18 Na2O 2.95 3.32 3.73 3.55 3.68 3.38 3.56 3.01 4.72 4.74 3.98 5.02 K2O 6.26 4.96 4.51 4.84 6.13 4.85 5.88 7.04 4.52 3.72 4.77 5.23 P2O5 0.02 0.02 0.03 0.01 0.02 0.01 0.02 0.03 0.01 0.03 0.01 0.01 LOI 0.54 0.37 0.33 0.23 0.18 0.34 0.33 0.23 0.17 0.36 0.28 0.27 Total 99.99 99.96 99.93 100.11 100.17 99.99 99.99 100.01 99.94 99.93 99.94 99.95 Na2O+K2O 9.21 8.28 8.24 8.39 9.81 8.23 9.44 10.05 9.24 8.46 8.75 10.25 A/CNK 0.97 1.03 1.03 0.99 0.84 1.03 0.91 0.87 1.02 1.06 1.04 0.86 DI 94 95 93 95 93 94 95 94 96 94 95 94 σ 2.68 2.03 2.09 2.05 2.95 2.04 2.83 3.39 2.69 2.27 2.34 3.72 La 25.50 18.41 13.98 28.47 23.59 22.31 30.64 41.58 26.60 33.40 21.09 33.57 Ce 48.04 46.72 26.91 47.72 51.46 44.35 39.88 64.32 99.57 98.37 92.91 93.99 Pr 4.74 2.32 1.77 3.22 6.93 5.16 6.19 7.46 6.48 7.54 5.32 7.69 Nd 15.39 12.68 10.34 16.88 26.49 17.79 21.09 24.21 22.98 26.17 17.87 27.00 Sm 2.59 2.53 2.00 3.25 7.60 4.12 4.52 4.50 4.68 4.55 3.53 4.89 Eu 0.46 0.52 0.68 0.37 0.44 0.21 0.25 0.50 0.84 1.00 0.78 0.80 Gd 2.37 2.38 1.77 2.98 6.47 3.71 3.81 4.04 4.54 4.11 3.61 4.35 Tb 0.22 0.46 0.35 0.56 1.98 1.06 0.92 0.84 0.85 0.68 0.68 0.79 Dy 1.27 2.70 2.08 3.48 8.99 5.44 4.93 4.92 5.37 3.97 4.43 4.70 Ho 0.24 0.57 0.44 0.76 1.92 1.19 1.05 1.06 1.13 0.83 0.95 1.04 Er 0.68 1.77 1.35 2.41 5.58 3.73 3.24 3.26 3.53 2.60 3.01 3.23 Tm 0.11 0.34 0.25 0.48 1.02 0.72 0.61 0.65 0.67 0.48 0.56 0.52 Yb 0.75 2.38 1.7 3.25 7.08 4.96 4.41 4.65 4.48 3.29 3.75 4.09 Lu 0.13 0.37 0.26 0.50 1.11 0.76 0.71 0.71 0.67 0.48 0.55 0.63 ∑REE 102.5 94.15 63.88 114.3 150.6 115.5 122.3 162.7 182.4 187.4 159.0 187.3 LREE 96.72 83.18 55.68 99.92 116.5 93.94 102.6 142.6 161.2 171.0 141.5 167.9 HREE 5.76 10.97 8.20 14.41 34.13 21.57 19.69 20.14 21.24 16.42 17.54 19.33 LREE/HREE 16.78 7.59 6.79 6.93 3.41 4.36 5.21 7.08 7.59 10.42 8.07 8.69 (La/Sm)N 6.19 4.57 4.39 5.51 1.95 3.41 4.26 5.81 3.58 4.62 3.76 4.32 (Gd/Lu)N 2.30 0.79 0.84 0.73 0.73 0.61 0.66 0.71 0.84 1.07 0.82 0.86 (La/Yb)N 22.86 5.21 5.55 5.91 2.25 3.03 4.68 6.02 4.00 6.85 3.80 5.53 δEu 0.56 0.64 1.08 0.36 0.19 0.16 0.18 0.35 0.55 0.69 0.66 0.52 Rb 103.9 190.4 83.73 184.9 171.3 194.1 136.0 196.9 118.9 94.69 98.50 66.29 Sr 78.70 69.26 84.69 107.6 15.11 25.42 18.97 85.10 92.72 166.4 80.12 77.24 Y 6.04 15.29 11.14 19.99 49.68 35.41 22.69 22.82 28.77 21.20 24.30 27.15 Ba 226.7 359.2 665.8 299.9 18.77 21.73 69.00 77.20 594.0 673.0 588.2 405.9 Cs 1.10 1.41 0.94 0.97 0.70 0.91 0.89 1.27 0.99 1.00 0.86 0.96 Th 15.92 25.75 14.08 30.10 14.51 25.53 16.62 20.40 18.98 19.25 17.81 13.02 U 0.66 1.65 0.73 2.83 3.38 3.63 2.18 4.49 2.06 3.05 2.34 1.95 Nb 9.94 8.91 5.59 17.41 44.63 30.74 23.66 40.50 20.01 15.08 16.58 24.89 Ta 0.54 1.03 0.52 1.53 2.91 2.53 2.21 4.10 1.50 1.02 1.05 2.39 Ga 23.88 13.30 9.06 12.75 9.00 6.76 3.82 15.52 17.61 18.60 15.61 21.60 Zr 108.2 99.89 65.76 75.32 183.3 128.7 106.5 123.5 111.8 127.1 98.59 183.4 Hf 3.66 1.98 0.81 1.23 10.71 7.71 5.04 4.43 1.96 2.31 1.60 7.15 Sn 1.22 2.26 1.82 1.91 3.97 1.67 2.23 1.81 2.21 1.85 1.93 2.66 Cu 2.13 3.89 2.83 7.64 5.37 4.78 2.16 2.27 5.91 5.34 4.84 3.29 Pb 10.52 21.75 20.07 15.40 14.59 9.97 7.02 9.12 33.23 34.37 51.19 12.20 Zn 5.59 23.55 31.24 12.96 61.31 12.57 2.93 4.49 41.70 55.24 42.46 44.36 Cr 5.08 4.62 1.48 2.72 1.90 2.33 2.44 0.71 2.99 3.11 6.51 5.19 V 6.31 3.89 3.98 4.51 0.57 0.33 0.14 4.75 4.50 11.45 2.30 7.03 B 1.97 5.49 4.61 5.70 1.08 1.01 1.62 1.97 4.44 6.34 4.46 5.80 Li 3.24 5.80 9.27 3.59 1.60 4.51 5.00 3.65 9.63 4.89 3.71 4.46 Be 1.12 2.80 1.77 3.41 6.10 5.03 3.62 3.30 2.47 2.60 2.44 2.55 Sc 1.24 2.22 1.65 1.88 1.86 1.24 1.07 2.21 4.26 3.37 3.40 5.65 Co 3.52 0.70 0.70 0.97 2.92 3.55 2.36 2.75 0.73 1.43 0.49 3.18 Ni 2.85 3.42 1.23 1.68 0.59 0.38 0.10 0.68 2.62 2.47 3.79 0.45 10000×Ga/Al 3.59 2.06 1.32 2.03 1.47 1.02 0.57 2.26 2.44 2.53 2.27 2.96 Zr+Nb+Ce+Y 172.2 170.8 109.4 160.4 329.1 239.2 192.7 251.2 260.2 261.7 232.4 329.4 TZr (℃) 749 751 716 725 778 771 740 745 755 769 749 722
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表 3
昌图泥盆纪岩浆岩锆石Hf同位素分析结果
Table 3.
Zircon Hf isotopic compositions of the Devonian magmatic rocks in the Changtu area
测点号 Age (Ma) 
2σ εHf(0) εHf(t) 2σ tDM1 (Ma) tDM2 (Ma) fLu/Hf 235-20黑云母二长花岗岩 -01 389 0.069670 0.002095 0.282760 0.000025 -0.4 7.6 0.9 718 897 -0.94 -02 390 0.070345 0.002109 0.282789 0.000027 0.6 8.6 1.0 677 833 -0.94 -03 390 0.054194 0.001645 0.282783 0.000019 0.4 8.5 0.7 677 839 -0.95 -04 389 0.090101 0.002727 0.282729 0.000025 -1.5 6.4 0.9 776 977 -0.92 -05 389 0.067989 0.002127 0.282799 0.000020 1.0 9.0 0.8 661 809 -0.94 -06 390 0.058467 0.001802 0.282837 0.000024 2.3 10.4 0.9 600 718 -0.95 -07 389 0.083402 0.002472 0.282803 0.000024 1.1 9.0 0.9 663 808 -0.93 -08 388 0.071929 0.002195 0.282815 0.000021 1.5 9.5 0.8 640 776 -0.93 -09 390 0.070785 0.002081 0.282842 0.000025 2.5 10.5 0.9 599 713 -0.94 -10 388 0.054770 0.001667 0.282865 0.000024 3.3 11.4 0.9 558 654 -0.95 235-9二长花岗岩 -01 378 0.111469 0.003115 0.282931 0.000023 5.6 13.2 0.8 483 535 -0.91 -02 378 0.080668 0.002310 0.282889 0.000026 4.1 11.9 0.9 534 617 -0.93 -03 376 0.114160 0.003449 0.282846 0.000031 2.6 10.0 1.1 616 733 -0.90 -04 377 0.086580 0.002556 0.282859 0.000023 3.1 10.7 0.8 582 689 -0.92 -05 375 0.091398 0.002644 0.282958 0.000026 6.6 14.2 0.9 435 467 -0.92 -06 374 0.105823 0.003066 0.282866 0.000027 3.3 10.8 1.0 579 682 -0.91 -07 378 0.090058 0.002625 0.282888 0.000023 4.1 11.8 0.8 539 623 -0.92 -08 378 0.106900 0.002987 0.282859 0.000020 3.1 10.7 0.7 588 694 -0.91 -09 379 0.096520 0.002539 0.282921 0.000023 5.3 13.0 0.8 489 546 -0.92 -10 377 0.068330 0.001955 0.282964 0.000022 6.8 14.6 0.8 419 442 -0.94
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