日本レオロジー学会誌
Online ISSN : 2186-4586
Print ISSN : 0387-1533
ISSN-L : 0387-1533
高度架橋ポリマーの構造と弾性について
村上 謙吉高杉 純生
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ジャーナル フリー

1975 年 3 巻 2 号 p. 82-86

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For measuring the density of crosslinks in rubber vulcanizates, there are two kinds of methods. The mechanical method leads to a value νM(0), whereas the swelling method gives a value νS (0). In the ranges of lower crosslink density, the relation νM (0)>νS(0) is obtained for reasons which are well understood, whereas the inverse relation νM(0)<νS(0) is established in the range of higher crosslink density for reasons which have not yet been clarified. By introducing improved equations for such vulcanizates at higher crosslink densities, the relationνM(0)>νS(0) was obtained even for the higher crosslink density.

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