Сучасні методи отримання ендофуллеренів заліза
Анотація
В огляді проаналізовані експериментальні й теоретичні дослідження, присвячені методам отримання ендометалофуллеренів (ЕМФ) заліза, а також роботи, що ставлять під сумнів ці результати через вкрай низьку ефективність методик, які застосовували в синтезах. Розглянуто переваги та недоліки методів, а також вказано сфери можливого використання таких продуктів. Показано, що ЕМФ отримують переважно двома способами – дуговим розрядом у середовищі гелію або синтезом із застосуванням методів абляції та імплантації. Незважаючи на малу кількість робіт по залізоендофуллеренам, авторам статті вдалося досягти певного прогресу в аналізі ендоедральних фуллеренів заліза. Так, зафіксовано факт отримання Fe-ендофуллеренів з їх виділенням із суміші продуктів синтезу. Крім того, спрогнозовано вплив магнітного стану атомів металу на стабільність ендоедральних фуллеренів, встановлено зв'язок між виходом ЕМФ і температурою плазми, а також хімічною природою прекурсору атомів заліза. Зокрема, встановлено, що зі збільшенням атомної маси елементів вихід ЕМФ знижується по експоненційній залежності. Зроблено висновок, що магнітні властивості ЕМФ роблять їх перспективними матеріалами у галузі клінічної діагностики (контрастні речовини для Магнітно-резонансної томографії (МРТ)), а також медицини (для магнітокерованої доставки лікарських препаратів безпосередньо до хворих органів).
Посилання
Schur D.V., Lavrenko V.A.Studies of titanium-hydrogen plasma interaction. Vacuum. 1993. 4(9): 897. https://doi.org/10.1016/0042-207X(93)90247-8
Schur D.V., Veziroglu A., Zaginaychenko S.Y., Matysina Z.A., Veziroglu T.N., Gabdullin M.T., Ramazanov T.S., Zolotarenko An.D., Zolotarenko Al.D. Theoretical studies of lithium-aluminum amid and ammonium as perspective hydrogen storage. International Journal of Hydrogen Energy. 2019. 44(45): 24810. https://doi.org/10.1016/j.ijhydene.2019.07.205
Matysina Z.A., Zaginajchenko S.Y., Shhur D.V., Zolotarenko A.D., Zolotarenko Al.D., Gabdullin T.M. Alkali and potassium almates are perspective hydrogen substitutes. Alternativnaya Energetika i Ekologiya (ISJAEE). 2017. 13-15: 37. https://doi.org/10.15518/isjaee.2017.13-15.037-060
Matysina Z.A., Zaginaichenko S.Y., Schur D.V., Veziroglu T.N., Veziroglu A., Gabdullin M.T., Zolotarenko Al.D., Zolotarenko An.D. The mixed lithium-magnesium imide Li2Mg(NH)2 a promising and reliable hydrogen storage material. International Journal of Hydrogen Energy. 2018. 43(33): 16092. https://doi.org/10.1016/j.ijhydene.2018.06.168
Matysina Z.A., Zaginaichenko S.Y., Schur D.V., Zolotarenko Al.D., Zolotarenko An.D., Gabdullin M.T. Hydrogen Sorption Properties of Potassium Alanate. Russian Physics Journal. 2018. 61(2): 253. https://doi.org/10.1007/s11182-018-1395-5
Zolotarenko Al.D., Zolotarenko An.D., Veziroglu A., Veziroglu T.N., Shvachko N.A., Pomytkin A.P., Schur D.V., Gavrylyuk N.A., Ramazanov T.S., Akhanova N.Y., Gabdullin M.T. Methods of theoretical calculations and of experimental researches of the system atomic hydrogen - metal. International Journal of Hydrogen Energy. 2022. 47(11): 7310. https://doi.org/10.1016/j.ijhydene.2021.03.065
Matysina Z.A., Zaginaychenko S.Yu., Schur D.V. Solubility of Impurities in Metals, Alloys, Intermetallics, Fullerites.(Dnepropetrovsk: Science and education. 2006).
Schur D.V., Zaginaichenko S.Y., Savenko A.F., Bogolepov V.A., Anikina N.S., Zolotarenko A.D., Matysina Z.A., Veziroglu N., Scryabina N.E. Experimental evaluation of total hydrogen capacity for fullerite C60. International Journal of Hydrogen Energy. 2011. 36(1): 1143. https://doi.org/10.1016/j.ijhydene.2010.06.087
Schur D.V., Zolotarenko A.D., Zolotarenko A.D., Zolotarenko O.P., Chimbai M.V., Akhanova N.Y., Sultangazina M., Zolotarenko E.P. Analysis and identification of platinum-containing nanoproducts of plasma-chemical synthesis in a gaseous medium. Physical Sciences and Technology. 2019. 6(1-2): 46. https://doi.org/10.26577/phst-2019-1-p9
Volodin A.A., Zolotarenko A.D., Bel'mesov A.A., Gerasimova E.V., Sсhur D.V., Tarasov V.R., Zaginaichenko S.Yu., Doroshenko S.V., Zolotarenko An.D., Zolotarenko Al.D. Conductive Composite Materials Based on Metal Oxides and Carbon Nanostructures. Nanosistemi, Nanomateriali, Nanotehnologii. 2014. 12(4): 705.[in Russian]
Lavrenko V.A., Podchernyaeva I.A., Shchur D.V., Zolotarenko An.D., Zolotarenko Al.D. Features of Physical and Chemical Adsorption During Interaction of Polycrystalline and Nanocrystalline Materials with Gases. Powder Metallurgy and Metal Ceramics. 2018. 56(9-10): 504. https://doi.org/10.1007/s11106-018-9922-z
Akhanova N., Orazbayev S., Ualkhanova M., Perekos A.Y., Dubovoy A.G., Schur D.V., Zolotarenko Al.D., Zolotarenko An.D., Gavrylyuk N.A., Gabdullin M.T., Ramazanov T.S. The Influence of Magnetic Field on Synthesis of Iron Nanoparticles. Journal of Nanoscience and Nanotechnology Applications. 2019. 3(3): 1.
Dubovoj A.G., Perekos A.E., Lavrenko V.A., Rudenko Yu.M., Efimova T.V., Zalustkii V.P., Rushitskaya T.V., Kotko A.V., Zolotarenko Al.D., Zolotarenko An.D. Effect of a Magnetic Field on the Phase-Structural State and Magnetic Properties of Finely Dispersed Fe Powders Obtained by Electrospark Dispersion. Nanosistemi, Nanomateriali, Nanotehnologii. 2013. 11(1): 131. [in Russian].
Zaginajchenko S.Yu., Schur D.V., Gabdullin M.T., Dzhavadov N.F., Zolotarenko Al.D., Zolotarenko An.D., Zolotarenko A.D., Mamedova S.H., Omarova G.D., Mamedova Z.T. Features of pyrolytic synthesis and certification of carbon nanostructured materials. Alternativnaya Energetika i Ekologiya (ISJAEE). 2018. 19-21: 72. https://doi.org/10.15518/isjaee.2018.19-21.072-090
Akhanova N.Ye., Shchur D.V., Pomytkin A.P., Zolotarenko Al.D., Zolotarenko An.D., Gavrylyuk N.A., Ualkhanova M., Bo W., Ang D. Methods for the Synthesis of Endohedral Fullerenes. J. Nanosci. Nanotechnol. 2021.21(4):2446. https://doi.org/10.1166/jnn.2021.18971
Anikina N.S., Schur D.V., Zaginaichenko S.Y., Zolotarenko A.D. Regularity of C60 fullerene dissolving in methyl derivatives of benzene. In: Proc. of 10th International Conference "Hydrogen Materials Science and Chemistry of Carbon Nanomaterials" (Sept. 22 - 28, 2007, Sudak, Crimea, Ukraine). P. 672.
Schur D.V., Zaginaichenko S.Y., Zolotarenko A.D. Solubility and Transformation of Fullerene C60 Molecule. Carbon Nanomaterials in Clean Energy Hydrogen Systems. NATO Science Series. 2008: 85. https://doi.org/10.1007/978-1-4020-8898-8_7
Schur D.V., Zaginaichenko S.Yu., Lysenko E.A., Golovchenko T.N., Javadov N.F. The Forming Peculiarities of C60 Molecule. Carbon Nanomaterialsin Clean Energy Hydrogen Systems. 2008: 53. https://doi.org/10.1007/978-1-4020-8898-8_5
Akhanova N.Y., Shchur D.V., Pomytkin A.P., Zolotarenko Al.D., Zolotarenko An.D., Gavrylyuk N.A., Ualkhanova M., Bo W., Ang D. Gadolinium Endofullerenes. Journal of Nanoscience and Nanotechnology. 2021.21(4): 2435. https://doi.org/10.1166/jnn.2021.18970
Shul'ga Y.M., Baskakov S.A., Zolotarenko A.D., Kabachkov E.N., Muradjan V.E., Voilov D.N., Smirnov V.A., Martynenko V.M., Schur D.V., Pomytkin A.P., Coloring graphene oxide nanosheets and colored polymer compositions based on them. Nanosistemi, Nanomateriali, Nanotehnologii. 2013. 11(1): 161. [inRussian].
Sementsov Y.I., Gavriluk N.A., Prikhod'ko G.P., Aleksyeyeva T.A. Biocompatibility of Multiwall Cnt and Nanocomposites on the Base of Polymers. Carbon Nanomaterialsin Clean Energy Hydrogen Systems. 2008: 327. https://doi.org/10.1007/978-1-4020-8898-8_39
Sementsov Y.I., Gavrilyuk N.A., Prikhod'ko G.P., Melezhyk A.V. Properties of PTFE - MWNT composite materials. Hydrogen materials science and chemistry of carbon nanomaterials.2007: 757. https://doi.org/10.1007/978-1-4020-5514-0_95
Prihod'ko G.P., Gavriljuk N.A., Dijakon L.V., Kulish N.P., Melezhik A.V., Semencov Yu.I. Polypropylene composites filled with carbon nanotubes Nanosistemi, nanomateriali, nanotehnologii. 2006. 4: 1081.
Zolotarenko Ol.D., Rudakova E.P., Akhanova N.Y., Zolotarenko An.D., Shchur D.V., Gabdullin M.T., Ualkhanova M., Gavrylyuk N.A., Chymbai M.V., Tarasenko Yu.O., Zagorulko I.V., Zolotarenko A.D. Electric Conductive Composites Based on Metal Oxides and Carbon Nanostructures. Metallofiz. Noveishie Tekhnol. 2021.43(10): 1417.
Zolotarenko An.D., Zolotarenko Al.D., Veziroglu A., Veziroglu T.N., Shvachko N.A., Pomytkin A.P., Gavrylyuk N.A., Schur D.V., Ramazanov T.S., Gabdullin M.T. The use of ultrapure molecular hydrogen enriched with atomic hydrogen in apparatuses of artificial lung ventilation in the fight against virus COVID-19. International Journal of Hydrogen Energy. 2022. 47(11): 7281. https://doi.org/10.1016/j.ijhydene.2021.03.025
Sementsov Yu., Gavriluk N., Aleksyeyeva T. Lasarenko O. Polymer nanocomposites filled of multiwall carbon nanotubes for medical application. Nanosystems, nanomaterials, nanotechnologies. 2007. 5(2): 351.
Zolotarenko O.D., Rudakova O.P., Kartel M.T., Kaleniuk H.O., Zolotarenko A.D., Schur D.V. & Tarasenko Y.O. The mechanism of forming carbon nanostructures by electric arc-method. Surface. 2020. 12(27): 263-288. https://doi.org/10.15407/Surface.2020.12.263
Hebard A.F., Rosseinsky M.J., Haddon R.C., Murphy D.W., Glarum S.H., Palstra T.T.M., Ramirez A.P., Kortan A.R. Superconductivity at 18 K in potassium-doped C60. Nature. 1991. 350: 600. https://doi.org/10.1038/350600a0
Holczer K., Klein O., Huang Sh., Kaner R.B., Fu K., Whetten R.L., Diederich F. Alkali-Fulleride Superconductors: Synthesis, Composition, and Diamagnetic Shielding. Science. 1991. 252: 1154. https://doi.org/10.1126/science.252.5009.1154
Rosseinsky M.J., Ramirez A.P., Glarum S.H., Murphy D.W., Haddon R.C., Hebard A.F., Palstra T.M., Kortan A.R., Zahurak S.M., Makhija A.V. Superconductivityat 28 KinRbxC60. Phys. Rev. Lett. 1991. 66: 2830.
Haddon R.C., Hebard A.F., Rosseinsky M.J., Murphy D.W., Duclos S.J., LyonsK.B., Miller B., Rosamilia J.M., Fleming R.M., Kortan A.R., Glarum S.H., Makhija A.V., Muller A.J., Eick R.H., Zahurak S.M., Tycko R., Dabbagh G., Thiel F.A. Conducting films of C60 and C70 by alkali-metal doping. Nature. 1991. 350: 320. https://doi.org/10.1038/350320a0
Haddon R.C. Electronic structure, conductivity and superconductivity of alkali metal doped (C60). Acc. Chem. Res. 1992. 25: 127. https://doi.org/10.1021/ar00015a005
Wang H.H., Kini A.M., Savall B.M., Carlson K.D., Williams J.M., Lykke K.R., Wurz P., Parker D.H., Pellin M.J. First easily reproduced solution-phase synthesis and confirmation of superconductivity in the fullerene KxC60 (Tc = 18.0 .+-. 0.1 K). Inorg. Chem. 1991. 30(14): 2838. https://doi.org/10.1021/ic00014a005
Akhanova N.Y.,Schur D.V., Gavrylyuk N.A., Gabdullin M.T., Anikina N.S., Zolotarenko An. D., Krivushchenko O.Ya., Zolotarenko Ol.D., Gorelov B.M., Erlanuli E., Batrishev D.G. Use of absorption spectra for identification of endometallofullerenes. Himia, Fizika ta Tehnologia Poverhni. 2020.11 (3): 429. https://doi.org/10.15407/hftp11.03.429
Yeletskii A.V., Smirnov B.M. Fullerenes and carbon structures. Physics-Uspekhi. 1995. 38(9): 935. https://doi.org/10.1070/PU1995v038n09ABEH000103
Wang Y. Photoconductivity of fullerene-doped polymers. Nature.1992. 356: 585. https://doi.org/10.1038/356585a0
Hoshi H., Nakamura N., Maruyama Y., Nakagawa T., Suzuki Sh., Shiromar H., Achiba Y. Optical Second- and Third-Harmonic Generations in C60 Film. Jpn. J. Appl. Phys. 1991. 30(8A): L1397. https://doi.org/10.1143/JJAP.30.L1397
Kroto H.W., Heath J.R., O'Brien S.C., Curl R.F., Smalley R.E. C60: Buckminsterfullerene. Nature. 1985. 318: 162. https://doi.org/10.1038/318162a0
Chai Y., Guo T., Jin C., Haufler R.E., Chibante L.P.F., Fure J., Wang L., Alford J.M., Smalley R.E. Fullerenes with metals inside. J. Phys. Chem.1991. 95(20): 7564. https://doi.org/10.1021/j100173a002
Shinohara H., Tagmatarchis N. Endohedralmetallofullerenes. Fullerenes with Metal Inside (John Wiley & Sons, Ltd, 2015). https://doi.org/10.1002/9781118698006
Sueki K., Kikuchi K., Akiyama K., Sawa T., Katada M., Ambe S., Ambe F., Nakahara H. Formation of metallofullerenes with higher group elements. Chem. Phys. Lett. 1999. 300(1-2): 140. https://doi.org/10.1016/S0009-2614(98)01353-0
Patent: US 20090240042A1. Dorn H.C. Iezzi E.B. Endohedral metallofullerene derivatives. 2006.
Patent RF 2664133 №218.016.7C5D. Lebedev V.T., Sujasova M.V., Szhogina A.A., Sedov V.P.The Technology of 3d-metallic endofullerenes. 2017.
Chen Z., Ma L., Liu Y., Chen C. Applications of Functionalized Fullerenes in Tumor Theranostics. Theranostics. 2012. 2(3): 238. https://doi.org/10.7150/thno.3509
Pradeep T., Kulkarni G.U., Kannan K. R.,Guru Row T.N., Rao C.N. R. A novel iron fullerene (FeC60) adduct in the solid state. J. Am. Chem. Soc.1992. 11(46): 2272. https://doi.org/10.1021/ja00032a059
Roth L.M., Huang J., Schwedler J.T., Cassady C.J., Ben-Amots D., Kahr B., Freiser B.S. Evidence for an externally bound iron+-buckminsterfullerene complex, FeC60+, in the gas phase. J. Am. Chem. Soc. 1991. 113(16): 6298. https://doi.org/10.1021/ja00016a071
Yuang Y., Freiser B.S. Synthesis of bis(buckminsterfullerene)nickel cation, Ni(C60)2+, in the gas phase. J. Am. Chem. Soc. 1991. 113: 8186. https://doi.org/10.1021/ja00021a065
Churilov G.N.Preparation and study of iron-containing complexes of fullerenes // Zhurnal tehnicheskoj fiziki. 1997. 67(9):142. https://doi.org/10.1134/1.1258784
Uchida T., Minezaki H., Tanaka K., Muramatsu M., Asaji T., Kato Y., Kitagawa A., Biri S., Yoshida Y. Bio-Nano ECRIS: An electron cyclotron resonance ion source for new materials production. Review of Scientific Instruments.2010. 81: 02A306. https://doi.org/10.1063/1.3258027
Uchida T., Minezaki H., Yoshida Y., Biri S., Kitagawa A., Kato Y., Asaji T., Tanaka K. The bio-nano-ecris project: a new ecr ion source at toyo university to produce endohedral fullerenes. Proc. of ECRIS08 (Sept. 08 - 15), IL USA: Chicago. 2008. 27-32.
Minezaki H., Uchida T., Tanaka K., Muramatsu M., Asaji T., Kitagawa A., Kato Y., Racz R., Biri S., Yoshida Y. Synthesis of Endohedral Fullerene Using ECR Ion Source. AIP Conf. Proc.2011. 1321: 480. https://doi.org/10.1063/1.3548456
Uchida T., Minezaki H., Ishihara S., Muramatsu M., Rocz R., Asaji T., Kitagawa A., Kato Y., Biri S., Drentje A.G., Yoshida Y. Status of the Bio-Nano electron cyclotron resonance ion source at Toyo University. Review of Scientific Instruments. 2014. 85: 02C317. https://doi.org/10.1063/1.4862212
Minezaki H., Ishihara S., Uchida T., Muramatsu M., Rocz R., Asaji T., Kitagawa A., Kato Y., Biri S., Yoshida Y. Synthesis of endohedral iron-fullerenes by ion implantation. Review of Scientific Instruments. 2014. 85: 02A945. https://doi.org/10.1063/1.4850756
Minezaki H., Oshima K., Uchida T., Mizuki T., Racz R., Muramatsu M., Asaji T., Kitagawa A., Kato Y., Biri S., Yoshida Y. Synthesis of endohedral iron-fullerenes by ion implantation. Nucl. Instrum. Methods Phys. Res. B. 2013. 310: 18. https://doi.org/10.1016/j.nimb.2013.05.015
Minezaki H., Oshima K., Uchida T., Mizuki T., Racz R., Muramatsu M., Asaji T., Kitagawa A., Kato Y., Biri S., Yoshida Y. Synthesis of Fe-C60 complex by ion irradiation. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atom s.2013. 310(1): 18. https://doi.org/10.1016/j.nimb.2013.05.015
Asaji T., Ohba T., Uchida T., Minezaki H., Ishihara S., Racz R., Muramatsu M., Biri S., Kitagawa A., Kato Y., Yoshida Y. Fullerene-rare gas mixed plasmas in an electron cyclotron resonance ion source. Rev. Sci. Instrum. 2014. 85: 02A936-1. https://doi.org/10.1063/1.4847255
Biri S., Valek A., Kenez L., Janossy A., Kitagawa A. Production of multiply charged fullerene and carbon cluster beams by a 14.5 GHz ECR ion source. Review of Scientific Instruments. 2002. 73: 881. https://doi.org/10.1063/1.1429788
Kaneko T., Abe S., Ishida H., Hatakeyama R. An electron cyclotron resonance plasma configuration for increasing the efficiency in the yield of nitrogen endohedral fullerenes. Physics of Plasmas. 2007. 14: 110705. https://doi.org/10.1063/1.2814049
Deng Q., Heine T., Irle S., Popov A. Self-assembly of endohedral metallofullerenes: a decisive role of cooling gas and metal-carbon bonding. Nanoscale. 2016.8(6): 3796. https://doi.org/10.1039/C5NR08645K
Brunsman E.M., Sutton R., Bortz E., Kirkpatrick S., Midelfort K., Williams J., Smith P., McHenry M.E., Majetich S.A., Artman J.O., Graef M.De, Staley S.W. Magnetic properties of carbon-coated, ferromagnetic nanoparticles produced by a carbon-arc method. Journal of Applied Physics. 1994. 75(10): 5882. https://doi.org/10.1063/1.355548
Tang C.M., Deng K.M., Yang J.L., Wang X.Geometric and Electronic Properties of Metallofullerene Fe@C60. Chinese Journal of Chemistry. 2006. 24: 1133. https://doi.org/10.1002/cjoc.200690213
Estrada-Salas R.E., Valladares A.A. DFT calculations of the structure and electronic properties of late 3d transition metal atoms endohedrally doping C60. J. Mol. Struct.: THEOCHEM. 2008. 869(1-3): 1. https://doi.org/10.1016/j.theochem.2008.08.017
Gao G., Kang H.S. C60 as a chemical Faraday cage for three ferromagnetic Fe atoms. Chemical Physics Letters. 2008. 462(1-3): 72. https://doi.org/10.1016/j.cplett.2008.07.044
Javan M.B., Tajabor N., Behdani M., Rokn-Abadi M.R. Influence of 3d transition metals (Fe, Co) on the structural, electrical and magnetic properties of C60 nano-cage. Physica B: Condensed Matter. 2010: 405(24): 4937. https://doi.org/10.1016/j.physb.2010.09.035
Semenov S.G., Bedrina M.E., Makarova M.V., Titov A.V. Quantum chemical study of the Fe@C60 endocomplex. Journal of Structural Chemistry. 2017. 58(3): 475. https://doi.org/10.1134/S0022476617030040
Semenov S.G., Bedrina M.E. A Quantum Chemical Study of C60Cl30, C60(OH)30 Molecules and Fe@C60(OH)30 Endocomplex. Journal of Structural Chemistry. 2018. 59(3): 506. https://doi.org/10.1134/S0022476618030022
Ryzhkov M.V., Medvedeva N.I., Delley B. Electronic structures of endohedral fullerenes with scandium, titanium and iron atoms and metal-carbon clusters. Polyhedron. 2017. 134: 376. https://doi.org/10.1016/j.poly.2017.06.032
Gao H.T., Kou G., Will L., Du G. Endohedral metallofullerenes (M@C60) as efficient catalysts for highly active hydrogen evolution reaction. Journal of Catalysis. 2017. 354: 231. https://doi.org/10.1016/j.jcat.2017.08.025
Koltover V.K. Endohedral fullerenes: from chemical physics to nanotechnology and medicine. Vestn. RFFI (Journal RFBR). 2008. 59(3): 54.
Popov A. Yang S., Dunsch L. Endohedral Fullerenes. Chem. Rev. 2013. 113(8): 5989. https://doi.org/10.1021/cr300297r
Bezmel'nitsyn V.H., Eleckij A.V., Okun' M.V. Fullerenes in solutions. Uspehi fizicheskih nauk. 1998. 168(11): 1195 [in Russian]. https://doi.org/10.3367/UFNr.0168.199811b.1195
Zaulichnyy Ya. V., Petrovskaya S. S., Grayvoronskaya Ye. A., Solonin Yu. M. Carbon nanomaterials: electronic structure and structure formation processes. (K.:Naukova dumka, 2012) [in Russian].
