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Abstract
The review surveys the crystal chemistry of inorganic compounds belonging to the structure type of clathrate-I. The compounds of this family exhibit an unexpected variety of both chemical composition and features of the crystal structure. The basic crystal structure of clathrate-I and different variants of its modification, such as siting, position splitting, and superstructure formation including transformation to semiclathrates, are considered in terms of the group-subgroup relationship.
Published Online: 2013-04-29
Published in Print: 2013-05
© by Oldenbourg Wissenschaftsverlag, München, Germany