Biochar caged zirconium ferrite nanocomposites for the adsorptive removal of Reactive Blue 19 dye in a batch and column reactors and conditions optimizaton

Shazia Perveen; Raziya Nadeem; Shaukat Ali; Yasir Jamil

doi:10.1515/zpch-2020-1749

Published by De Gruyter (O) March 26, 2021

Biochar caged zirconium ferrite nanocomposites for the adsorptive removal of Reactive Blue 19 dye in a batch and column reactors and conditions optimizaton

Shazia Perveen , Raziya Nadeem , Shaukat Ali and Yasir Jamil

From the journal Zeitschrift für Physikalische Chemie

https://doi.org/10.1515/zpch-2020-1749

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Abstract

Biochar caged zirconium ferrite (BC-ZrFe₂O₅) nanocomposites were fabricated and their adsorption capacity for Reactive Blue 19 (RB19) dye was evaluated in a fixed-bed column and batch sorption mode. The adsorption of dye onto BC-ZrFe₂O₅ NCs followed pseudo-second-order kinetics (R² = 0.998) and among isotherms, the experimental data was best fitted to Sips model as compared to Freundlich and Langmuir isotherms models. The influence of flow-rate (3–5 mL min⁻¹), inlet RB19 dye concentration (20–100 mg L⁻¹) and quantity of BC-ZrFe₂O₅ NCs (0.5–1.5 g) on fixed-bed sorption was elucidated by Box-Behnken experimental design. The saturation times (C_t/C_o = 0.95) and breakthrough (C_t/C_o = 0.05) were higher at lower flow-rates and higher dose of BC-ZrFe₂O₅ NCs. The saturation times decreased, but breakthrough was increased with the initial RB19 dye concentration. The treated volume was higher at low sorbent dose and influent concentration. Fractional bed utilization (FBU) increased with RB19 dye concentration and flow rates at low dose of BC-ZrFe₂O₅ NCs. Yan model was fitted best to breakthrough curves data as compared to Bohart-Adams and Thomas models. Results revealed that BC-ZrFe₂O₅ nanocomposite has promising adsorption efficiency and could be used for the adsorption of dyes from textile effluents.

Keywords: kinetic models; sorption isotherms; textile effluents; zirconium ferrite nanocomposites

Corresponding authors: Shazia Perveen and Raziya Nadeem, Department of Chemistry, University of Agriculture Faisalabad, Faisalabad, Pakistan, E-mail: shazia.fooz@gmail.com (S. Perveen), raziyaanalyst@uaf.edu.pk

Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: None declared.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2020-09-12

Accepted: 2021-03-05

Published Online: 2021-03-26

Published in Print: 2021-12-20

Biochar caged zirconium ferrite nanocomposites for the adsorptive removal of Reactive Blue 19 dye in a batch and column reactors and conditions optimizaton

Abstract

References

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