Volumetric, Viscosity and Conductance Studies of Solute–Solute and Solute–Solvent Interactions of Some Alkali Metal Chlorides in Aqueous Citric Acid at Different Temperatures

Manish Kumar; Shashi Kant; Deepika Kaushal

doi:10.1515/zpch-2018-1151

Published by De Gruyter (O) May 28, 2018

Volumetric, Viscosity and Conductance Studies of Solute–Solute and Solute–Solvent Interactions of Some Alkali Metal Chlorides in Aqueous Citric Acid at Different Temperatures

Manish Kumar , Shashi Kant and Deepika Kaushal

From the journal Zeitschrift für Physikalische Chemie

https://doi.org/10.1515/zpch-2018-1151

Showing a limited preview of this publication:

Abstract

The present study aims for the structure-making and structure-breaking behavior of some electrolytes in aqueous citric acid solution. The density, viscosity and conductance of some alkali metal chlorides lithium chloride (LiCl), sodium chloride (NaCl) and potassium chloride (KCl) in 0.01 m aqueous citric acid have been measured in the concentration range 0.01–0.12 m at 303.15, 308.15, 313.15 and 318.15 K. From these measurements, molar volume, viscosity parameters and molar conductance have been deliberated. Debye Hückel limiting law is used for the assessment of the contributions of various types of solute–solvent interactions. Jones–Dole viscosity equation is used to calculate viscosity B-coefficient for these salts in aqueous citric acid, which is known to provide information concerning the solvation of ions and their effects on the structure of the solvent in the near environment of the solute particles. The free energies of activation of viscous flow per mole of solvent, Δμ10‡ and solute, Δμ20‡, have also been evaluated by using viscosity data. Using molar volume, the transfer volume Ф_v^o_tr has also been computed. The structure making/ breaking behavior of LiCl, NaCl and KCl is inferred from the sign of second derivative of partial molar volume with respect to temperature at constant pressure (d²φ_v^o/dT²)_p, Temperature coefficient of B. dB/dT and temperature coefficient of Walden product i.e. d(Λ_m^oη_o)/dT values. It has been found from these studies that LiCl, NaCl and KCl behave as structure-breaker in 0.01 m aqueous citric acid solution. The results have been qualitatively used to explain the molecular interaction and structural changes between the components of these mixtures.

Keywords: conductance; lithium chloride; molar volume; potassium chloride; sodium chloride; viscosity

Acknowledgement

M. Kumar thanks CSIR New Delhi for his financial assistance.

References

1. R. Saeed, S. Masood, M. Ashfaq, A. Irfan, J. Chem. Eng. Data 54 (2009) 3125.10.1021/je900195zSearch in Google Scholar

2. D. Kaushal, D. S. Rana, M. S. Chauhan, S. Chauhan, Z. Phys. Chem. 228 (2014) 99.10.1515/zpch-2014-0436Search in Google Scholar

3. S. Kant, S. Kumar, J. Chem. Eng. Data 58 (2013) 1294.10.1021/je301362jSearch in Google Scholar

4. Y. Akhtar, S. F. Ibrahim, Arabian J. Chem. 4 (2011) 487.10.1016/j.arabjc.2010.07.009Search in Google Scholar

5. S. Kant, M. Kumar, J. Chem. Biol. Phys. Sci. 3 (2013) 2459.Search in Google Scholar

6. S. Chauhan, Seema, D. S. Rana, Rajni, M. S. Chauhan, A. Umar, Adv. Sci. Eng. Med. 4 (2012) 81.10.1166/asem.2012.1122Search in Google Scholar

7. D. S. Gill, D. S. Rana, S. P. Jauhar, J. Chem. Eng. Data. 55 (2010) 2066.10.1021/je900915pSearch in Google Scholar

8. Z. Hai-Lang, H. Shi-Jun, J. Chem. Eng. Data 41 (1996) 516.10.1021/je9501402Search in Google Scholar

9. K. Zhuo, Y. Chen, W. Wang, J. Wang, J. Chem. Eng. Data 53 (2008) 2022.10.1021/je700732uSearch in Google Scholar

10. V. R. Karanth, D. K. Bhat, Thermochim. Acta 572 (2013) 23.10.1016/j.tca.2013.08.002Search in Google Scholar

11. S. Thirumaran, K. J. Sabu, J. Appl. Sci. 11 (2011) 3258.10.3923/jas.2011.3258.3266Search in Google Scholar

12. S. K. Lomesh, D. Kumar, J. Mol. Liq. 241 (2017) 764.10.1016/j.molliq.2017.05.004Search in Google Scholar

13. G. Ayranci, M. Sahin, E. Ayranci, J. Chem. Thermodyn. 39 (2007) 1620.10.1016/j.jct.2007.04.009Search in Google Scholar

14. D. S. Rana, D. S. Gill, M. S. Chauhan, R. Gupta, Z. Phys. Chem. 225 (2011) 421.10.1524/zpch.2011.5533Search in Google Scholar

15. D. S. Rana, D. S. Gill and R. Gupta, Z. Phys. Chem. 222 (2008) 1039.10.1524/zpch.2008.5357Search in Google Scholar

16. B. Hribar, N. T. Southall, V. Vlachy, K. A. Dill, J. Am. Chem. Soc. 124 (2002) 12302.10.1021/ja026014hSearch in Google Scholar PubMed PubMed Central

17. E. Djamali, J. Cobble, J. Phys. Chem. B 113 (2009) 5200.10.1021/jp900723dSearch in Google Scholar PubMed

18. R. W. Gurney, Ionic Process in Solution, Chap. 10, McGrawHill, New York (1953).Search in Google Scholar

19. Y. Marcus, Chem. Rev. 109 (2009) 1346.10.1021/cr8003828Search in Google Scholar PubMed

20. L. Grande, E. Paillard, J. Hassoun, J. B. Park, Y. J. Lee, Y.K. Sun, S. Passerini, B. Scrosati, Adv. Mater. 27 (2015) 784.10.1002/adma.201403064Search in Google Scholar PubMed

21. Y. Lu, M. Tikekar, R. Mohanty, K. Hendrickson, L. Ma, L. A. Archer, Adv. Energy Mater. 5 (2015) 1402073.10.1002/aenm.201402073Search in Google Scholar

22. Q. Chen, K. Geng, K. Sieradzki, J. Electrochem. Soc. 162 (2015) A2004.10.1149/2.0261510jesSearch in Google Scholar

23. J. P. Castillo, H. Rui, D. Basilio, A. Das, B. Roux, R. Latorre, F. Bezanilla, M. Holmgren, Nat. Commun. 6 (2015) 7622.10.1038/ncomms8622Search in Google Scholar PubMed PubMed Central

24. G. K. Ward, F. J. Millero, J. Sol. Chem. 3 (1974) 417.10.1007/BF00651533Search in Google Scholar

25. S. Chauhan, M. S. Chauhan, D. Kaushal, V. K. Syal, J. Jyoti, J. Sol. Chem. 39 (2010) 622.10.1007/s10953-010-9534-9Search in Google Scholar

26. D. S. Gill, A. Kumari, R. Gupta, D. S. Rana, J. K. Puri, S. P. Jauhar, J. Mol. Liq. 133 (2007) 7.10.1016/j.molliq.2006.05.009Search in Google Scholar

27. S. Chauhan, K. Sharma, D. S. Rana, G. Kumar, A. Umar, J. Sol. Chem. 42 (2013) 634.10.1007/s10953-013-9981-1Search in Google Scholar

28. Z. Yan, X. Wen, Y. Kang, W. Chu, J. Chem. Thermodynamics 101 (2016) 300.10.1016/j.jct.2016.06.018Search in Google Scholar

29. D. Kumar, S. K. Sharma, Z. Phys. Chem. 232 (2018) 393.10.1515/zpch-2017-0977Search in Google Scholar

30. F. J. Millero, Structure, Thermodynamics and Transport processes in water and aqueous solutions, Chap. 15, R. A. Horne, Ed. Wiley Inter science, New York (1971).Search in Google Scholar

31. F. J. Millero, W. D. Hansen, J. Phys. Chem. 72 (1968) 1758.10.1021/j100851a064Search in Google Scholar

32. F. J. Millero, Chem. Rev. 71 (1971) 147.10.1021/cr60270a001Search in Google Scholar

33. L. G. Hepler, Can. J. Chem. 47 (1969) 4613.10.1139/v69-762Search in Google Scholar

34. M. F. Hossain, T. K. Biswas, M. N. Islam, M. E. Huque, Monatsh Chem. 141 (2010) 1297.10.1007/s00706-010-0402-5Search in Google Scholar PubMed

35. A. Pal, N. Chauhan, J. Chem. Eng. Data 56 (2011) 1687.10.1021/je100857sSearch in Google Scholar

36. D. Kumar, S. K. Lomesh, V. Nathan, J. Mol. Liq. 247 (2017) 75.10.1016/j.molliq.2017.08.057Search in Google Scholar

37. G. Jones, M. Dole, J. Am. Chem. Soc. 51 (1929) 2950.10.1021/ja01385a012Search in Google Scholar

38. A. M. Seuvre, M. Mathlouthi, Food Chem. 122 (2010) 455.10.1016/j.foodchem.2009.04.101Search in Google Scholar

39. H. Falkenhagen, E. L. Vernon, Z. Phys. Chem. 33 (1932) 140.Search in Google Scholar

40. Z. N. Yan, J. J. Wang, W. B. Liu, J. S. Lu, Thermochim. Acta 334 (1999) 17.10.1016/S0040-6031(99)00107-0Search in Google Scholar

41. M. N. Roy, V. K. Dakua, B. Sinha, Int. J. Thermophys. 28 (2007) 1275.10.1007/s10765-007-0220-0Search in Google Scholar

42. H. Li, X. S. Chen, F. Guo, L. Zhao, J. Zhu, Y. D. Zhang, J. Chem. Eng. Data 55 (2010) 1659.10.1021/je9007124Search in Google Scholar

43. D. S. Rana, D. S. Gill, S. P. Jauhar, Z. Phys. Chem. 225 (2011) 69.10.1524/zpch.2011.5527Search in Google Scholar

44. S. Glasstone, K. J. Laidler, H. Eyring, The Theory of Rate Processes, Mc Graw Hill, New York (1941), P. 477.Search in Google Scholar

45. A. Ali, S. Khan, S. Hyder, Md. Tariq, J. Chem. Thermodyn. 39 (2007) 613.10.1016/j.jct.2006.08.010Search in Google Scholar

46. A. Ali, P. Bidhuri, N. A. Malik, S. Uzair, Arab. J. Chem. (2014) (available online to 2014.08.27, http://dx.doi.org/10.1016/j.arabjc.2014.08.027).Search in Google Scholar

47. D. A. Maclness, The Principles of Electrochemistry, Dova Publications, Inc., New York (1967).Search in Google Scholar

48. R. L. Kay, D. F. Evans, J. Phys. Chem. 70 (1966) 2325.10.1021/j100879a040Search in Google Scholar

49. P. Bruno, M. D. Monica, J. Phys. Chem. 76 (1972) 1049.10.1021/j100651a018Search in Google Scholar

50. R. L. Blokhra, P. C. Verma, Electrochem Acta 22 (1977) 485.10.1016/0013-4686(77)85104-9Search in Google Scholar

Received: 2018-02-09

Accepted: 2018-04-29

Published Online: 2018-05-28

Published in Print: 2019-02-25

Volumetric, Viscosity and Conductance Studies of Solute–Solute and Solute–Solvent Interactions of Some Alkali Metal Chlorides in Aqueous Citric Acid at Different Temperatures

Abstract

Acknowledgement

References

Journal and Issue

Articles in the same Issue