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Licensed Unlicensed Requires Authentication Published by De Gruyter June 2, 2014

Isolierte trigonale SrO6 – Prismen verknüpfen Kagome-Netze im Strontium-Manganat(IV)-Tellurat(VI): SrMnTeO6 / Kagomé Layers Connected by Isolated Trigonal SrO6 Prisms in the Strontium Manganate(IV) Tellurate(VI): SrMnTeO6 L

  • L. Wulff and Hk. Müller-Buschbaum
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1998-0305

Abstract

Single crystals of the hitherto unknown compound SrMnTeO6 have been prepared from Sr(OH)2 ·8H2O , MnCO3(aq) and TeO2 in air by crystallization below the melt range. X-ray investigations showed hexagonal symmetry, space group D33h -P6̅2m, lattice constants a = 5.143( 1), c = 5.384(2) A, Z = 1. SrMnTeO6 is characterized by staggered [(Mn/Te)6O18] Kagome layers along [001]. These layers are connected by Sr2+ ions, resulting in SrO6 prisms isolated from each other. The structure is discussed with respect to the connection of Kagome nets in the quaternary oxides of the Ba3Ln4O9 type.

Keywords: Strontium; Manganese; Tellurate; Crystal Structure
Received: 1997-11-7
Published Online: 2014-6-2
Published in Print: 1998-3-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 53 Issue 3

Journal and Issue

Articles in the same Issue

Enantioselective Catalysis, XVII [1]. Enantioselective Catalytic Hydrogenation of Unfunctionalized Ketones
Isoselenocyanatoborate -Kristallstrukturen von (n-Bu4N)[BH(NCSe)3] und (Ph4P)[B3H7(NCSe)] / Isoselenocyanatoborates -Crystal Structures of (n-Bu4N)[BH(NCSe)3] and (Ph4P)[B3H7(NCSe)]
Redoxreaktionen von Molybdänverbindungen mit Bis(2-salicyliden- aniinophenvl Klisulfid. Kristallstruktur von Salicylaldehyd-2-mercapto- anilato(2-)-triphenylphosphanoxid-dioxomolybdän(VI) Redox / Reactions of Molybdenum Compounds with Bis(2-salicylidene-aminophenyl)disulfide. Crystal Structure of Salicylaldehyde-2-mercaptoanilato(2-)– triphenylphosphaneoxide-dioxo- molybdenum(VI)
Ag+ als Substituent eines Alkalimetalls in Ag2SrMnV2O8 / Ag+ As Substituent Of An Alkaline Metal In Ag2SrMnV2O8
Isolierte trigonale SrO6 – Prismen verknüpfen Kagome-Netze im Strontium-Manganat(IV)-Tellurat(VI): SrMnTeO6 / Kagomé Layers Connected by Isolated Trigonal SrO6 Prisms in the Strontium Manganate(IV) Tellurate(VI): SrMnTeO6 L
Isolierte 1∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5
Zur Kristallchemie der Silber-Mangan-Oxovanadate Ag2BaMnV2O8 und (AgCa2)Mn2(VO4)3 / On the Crystal Chemistry of the Silver Manganese Oxovanadates Ag2BaMnV2O8 and (AgCa2)Mn2(VO4)3
Zur Synthese fluororganischer O-(Trimethylsilyl)-cyanhydrine / Synthesis of Fluoroorganic O-(Trimethylsilyl)Cyanhydrines
Synthesis and Reactions with CO and C2H4 of Cobalt(I) Complexes Containing Trimethylphosphine and Chelating o-Diphenylphosphanyl- phenolate Ligands
Spectrometric pK Determination of Daphnetin, Chlorogenic Acid and Quercetin
Bonding in an Unusual Nickel Carbide
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Solventothermal Synthesis of the Lamellar Selenidostannates(IV) A2Sn4Se9 · H2O (A = Rb, Cs) and Cs2Sn2Se6
Cyclodisilazane in cis-Konformation -eine einfache Synthese / Cyclodisilazanes in cis Conformation -a Facile Synthesis
Untersuchungen zum chemischen Transport von YX3 mit AlX3 und zur Existenz von gasförmigen und festen Komplexen YAl3 X12 (X = Br, I) / Investigations on the Chemical Transport Reaction of YX3 with AlX3 and on the Existence of Gaseous and Solid Complexes YAl3 X12 (X = Br, I) H
Synthesis and Mesomorphic Properties of Polymethylene-α,ω–bis [2-thio- 5-(4',4"n-alcoxybenzoyIoxy)phenyl]-1,3,4-oxadiazole
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Kristallstruktur von [Mo(Co)3(Ncme)(Srbu)]2 / Crystal Structure of [Mo(CO)3(NCMe)(S'Bu)]2
The Molecular Structures and Conformational Preferences of Bis(dimethylstibyl)-Sulfane and -Tellurane, E(SbMe2)2, E = S or Te, Me = CH3, by Density Functional Theory Calculations and Gas Electron Diffraction
Experimental and Computational Studies on Aminoguanidine Free Base, Monocation and Dication. Part III: Proton Affinities of Guanidine, Aminoguanidine and Glyoxal Bis(amidinohydrazone)
Reaction of 9-Borabicyclo[3.3.1]nonane with N-Trimethylsilylamines – Cleavage of the N–Si or N–H Bond
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