Metallorganische Lewis-Säuren, XXXV. Bildung und Struktur chalkogenverbrückter Metallkomplexe: [{(μ5-C5H5)(OC)2Fe}2SeSe{Fe(CO)2(μ5-C5H5)}]+BF4- und [(μ5-C5H5)(OC)2FeS(R)Re(CO)5]+BF4- (R = Me, Ph) / Organometallic Lewis Acids, XXXV. Formation and Stucture of Chalcogen Bridged Metal Complexes:  [{(μ5-C5H5)(OC)2Fe}2SeSe{Fe(CO)2(μ5-C5H5)}]+BF4- and [(μ5-C5H5)(OC)2FeS(R)Re(CO)5]+BF4- (R = Me, Ph)

Peter M. Fritz; Wolfgang Beck; Ulrich Nagel; Kurt Polborn; Wolfgang A. Herrmann; Christian Hecht; Jürgen Rohrmann

doi:10.1515/znb-1988-0605

Open Access Published by De Gruyter June 2, 2014

Metallorganische Lewis-Säuren, XXXV. Bildung und Struktur chalkogenverbrückter Metallkomplexe: [{(μ⁵-C₅H₅)(OC)₂Fe}₂SeSe{Fe(CO)₂(μ⁵-C₅H₅)}]⁺BF₄^- und [(μ⁵-C₅H₅)(OC)₂FeS(R)Re(CO)₅]⁺BF₄^- (R = Me, Ph) / Organometallic Lewis Acids, XXXV. Formation and Stucture of Chalcogen Bridged Metal Complexes: [{(μ⁵-C₅H₅)(OC)₂Fe}₂SeSe{Fe(CO)₂(μ⁵-C₅H₅)}]⁺BF₄^- and [(μ⁵-C₅H₅)(OC)₂FeS(R)Re(CO)₅]⁺BF₄^- (R = Me, Ph)

Peter M. Fritz , Wolfgang Beck , Ulrich Nagel , Kurt Polborn , Wolfgang A. Herrmann , Christian Hecht and Jürgen Rohrmann

From the journal Zeitschrift für Naturforschung B

https://doi.org/10.1515/znb-1988-0605

The cationic diselenium bridged title compound 2 and [{(μ⁵-C5H5)(CO)₂Fe}₃Se]⁺BF₄^- have been isolated from the reaction of (OC)₅ReFBF₃ with (μ²-Se_n)[(μ⁵-C₅H₅)(CO)₂Fe]₂ (n = 1, 2). The heterometallic μ-thiolato title complex has been prepared from (OC)₅ReFBF₃ and (μ⁵-C₅H₅)(OC)₂FeSR (R = Me. Ph; 4). The structures of 2 and 4a have been determined by X-ray diffraction analyses.

: Diselenium; Thiolato Bridged Carbonyl Iron and Rhenium Complexes

Received: 1988-1-18

Revised: 1988-3-3

Published Online: 2014-6-2

Published in Print: 1988-6-1

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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