Change language
English Deutsch
Change currency
€ EUR £ GBP $ USD
BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Notizen: Zur Reaktion von [(η3-C4H7)PdCl]2 mit Se(SiMe3)2 Die Kristallstruktur von [(η3-C4H7)6Pd6Se3] / Reaction of [(η3-C4H7)PdCl]2 with Se(SiMe3)2 The Crystal Structure of [(η3-C4H7)6Pd6Se3]

  • Dieter Fenske , Achim Hollnagel and Kurt Merzweiler
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1988-0525
Download article (PDF)

[(η3-C4H7)PdCl]2 reacts with Se(SiMe3)2 to form [(η3-C4H7)6Pd6Se3] (1). 1 has been characterized by X-ray crystal structure analysis. It contains a distorted trigonal prismatic Pd6-cluster. Three faces of the Pd-prism are occupied by μ4-Se ligands. 1 crystallizes in the space group Pnma with 4 formula units per unit cell. The lattice constants at 200 K are: a = 1175.1(8), b = 1611.4(12), c = 1720.3(12) pm.

Keywords: Synthesis; X-Ray; Crystal Structure of [(η3-C4H7)6Pd6Se3]; Trigonal Prismatic Pd-Se Cluster
Received: 1988-1-25
Published Online: 2014-6-2
Published in Print: 1988-5-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Download article (PDF)
From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 43 Issue 5

Journal and Issue

Articles in the same Issue

Beiträge zur Chemie des Bors, 189 [1]. Die Kristall-und Molekülstruktur von Bis(1,3-dithiaborolan-2-yl)sulfid / Contributions to the Chemistry of Boron, 189 [1]. The Crystal and Molecular Structure of Bis(1,3-dithiaborolan-2-yl)sulfide
Stickstoffverbindungen von Elementen der dritten Hauptgruppe mit intra- und intermolekularen Donor-Akzeptor-Bindungen, V [1]. Spezielle Gallium- und Indiumamide mit Alkoxogruppen / Nitrogen Compounds of Elements of the Third Main Group with Intra- and Intermolecular Donor Acceptor Bonds, V [1]. Special Gallium and Indium Amides with Alkoxo Groups
ESCA Studies of N,N′-Thiobisamines and of Some of its Chromium Carbonyl Complexes
Synthese und Struktur des ersten dreigliedrigen Arsen—Phosphor—Platin-Ringes / Synthesis and Structure of the First Three-Membered Ring Containing Arsenic, Phosphorus and Platinum
Darstellung und Kristallstruktur von Cäsiumhydroxid mit Methanol CsOH · CH3OH / Properties and Crystal Structure of Cesium Hydroxide with Methanol CsOH · CH3OH
Synthese und Kristallstruktur von [l,3-Bis(4-ethoxyphenyl)triazenido]pyridino-silber(I), einem dimeren Komplex mit kurzem Silber-Silber-Kontakt / Synthesis and Crystal Structure of [1,3-Bis(4-ethoxyphenyl)triazenido]pyridino Silver(I), a Dimeric Complex with a Short Silver-Silver Contact
Synthese und Struktur von Cäsium-1,5-bis(p-tolyl)pentaazadienid, Cs+(tolN5tol)- / Synthesis and Structure of Cesium 1,5-Bis(p-tolyl)pentaazadienide, Cs+(tolN5tol)-
Synthese und Struktur von 1,5-Bis(tolyl)pentaazadienidokomplexen von Eisen(II) und Ruthenium(I): [Fe(tolN5tol)2]2 und [Ru(CO)3(tolN5tol)]2 / Synthesis and Structure of 1,5-Bis(tolyl)pentaazadienido Complexes of Iron(II) and Ruthenium(I): [Fe(tolN5tol)2]2 and [Ru(CO)3(tolN5tol)]2
Benzoatokomplexe des Eisens und Cobalts Synthese und Eigenschaften von Fe3(C6H5COO)4(acac)2, Fe(C6H5COO)2 und CO(C6H5COO)2 , Kristallstruktur von Fe3(C6H5COO)4(acac)2 und Co(C6H5COO)2 / Benzoato Complexes of Iron and Cobalt Synthesis and Properties of Fe3(C6H5COO)4(acac)2, Fe(C6H5COO)2 and Co(C6H5COO)2, Crystal Structure of Fe3(C6H5COO)4(acac)2 and Co(C6H5COO)2
Gemischte Borsäureester von Aminoalkoholen und Diolen / Mixed Esters of Boric Acid with Amino Alcohols and Diols
Über hexakoordinierte gemischte Halogeno-Anionen des Te(IV): Kristallographische und Raman-spektroskopische Untersuchungen an Rb2TeBr3,5Cl2,5 / On Hexacoordinated Mixed Halogeno Anions of Te(IV): Crystallographic and Raman Spectroscopic Investigation of Rb2TeBr3,5Cl2,5
Zur Chemie und Strukturchemie von Phosphiden und Polyphosphiden, 49 [1]. Bildung und Struktur des Henicosaphosphids [Li(12-Krone-4)2]3P21(THF)2 / Chemistry and Structural Chemistry of Phosphides and Polyphosphides, 49 [1]. Formation and Structure of the Henicosaphosphide [Li(12-Crown-4)2]3P21(THF)2
Komplexe des 1-Thia-4,7-diazacyclononans (L) mit Blei(II), Indium(III), Thallium(I) und (III) Kristallstruktur von [LPb][PbBr4] / Complexes of 1-Thia-4,7-diazacyclononane (L) with Lead(II), Indium(III), Thallium(I) and (III) Crystal Structure of [LPb][PbBr4]
1,1-Disilylethan, CH3CH(SiH3)2 / 1,1-Disilylethane, CH3CH(SiH3)2
Bindungsisomere Hexakis(selenocyanato(N)-selenocyanato(Se))-Osmate(III), [Os(NCSe)n(SeCN)6-n]3-, n = 0-3 / Bond Isomeric Hexakis(selenocyanato(N)-selenocyanato(Se)) Osmates(III), [Os(NCSe)n(SeCN)6-n]3-, n = 0-3
Detection of Reactive Sulfur Molecules (S6, S7, S9, S∞) in Commercial Sulfur, in Sulfur Minerals, and in Sulfur Melts Slowly Cooled to 20 °C [1].
Über die Reaktivität von [(CH3)2N]6W2 (W≡W) gegenüber CS2/S8 und CS2/Se8. Röntgenstrukturanalyse von [(CH3)2NCS2]2W(S)(S2) / Reactivity of [(CH3)2N]6W2 (W≡W) Towards CS2/S8 and CS2/Se8. X-Ray Structure Analysis of [(CH3)2NCS2]2W(S)(S2)
Elementorganische Verbindungen mit o-Phenylenresten, XV [1]. Hexamethoxy-tetrachalcogena-tetrahydropentacene / Organometallic Compounds with o-Phenylene Substituents, Part XV [1]. Hexamethoxy-tetrachaleogena-tetrahydropentacenes
NMR-spektroskopische Untersuchung des Problems der Valenzisomerie zwischen 1,2-Dithiin und (Z)-But-2-en-1,4-dithion / NMR Spectroscopic Investigation Concerning the Problem of Valence Isomerism between 1,2-Dithiine and (Z)-But-2-ene-1,4-dithione
The Electrochemical Synthesis of Neutral Zinc(II) Complexes of Schiff Base Ligands: The Crystal Structure of Bis[N-(4-methylphenyl)salicylaldiminato]zinc(II)
Synthese von 5-Alkyliden-2,3-pyrrolidindionen / Synthesis of 5-Alkylidene-2,3-pyrrolidinediones
Allo-Verbindungen mit ungewöhnlichem Verhalten bei der Gaschromatographie an chiraler stationärer Phase / Allo-Compounds with Unusual Behaviour in Gas Chromatography Using Chiral Stationary Phase
Evaluation of the 2 NH2A—T Pair in Hybridization, I Synthesis of the DNA/RNA Hybrid Oligomers Containing 2-Aminoadenosines
Nachweis von Corticosteroiden im Fett von Dachs und Murmeltier / Detection of Corticosteroids in Fat of Badger and of Alp-Marmot
Notizen: Zur Reaktion von [(η3-C4H7)PdCl]2 mit Se(SiMe3)2 Die Kristallstruktur von [(η3-C4H7)6Pd6Se3] / Reaction of [(η3-C4H7)PdCl]2 with Se(SiMe3)2 The Crystal Structure of [(η3-C4H7)6Pd6Se3]
Notizen: Preparation and ESR Spectra of Manganese(III) Complexes with 2-[Bis(benzimidazol-2-ylmethyl)- amino] ethanol
Notizen: Das Infrarotspektrum des Tetraselentetranitrids, Se4N4 / The Infrared Spectrum of Tetraseleniumtetranitride, Se4N4
Downloaded on 12.6.2024 from https://www.degruyter.com/document/doi/10.1515/znb-1988-0525/html
Scroll to top button