Change language
English Deutsch
Change currency
€ EUR £ GBP $ USD
BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Chemie polyfunktioneller Moleküle, 80 [1]. Kristall- und Molekülstrukturen der Heteronoradamantane 5-Methyl-2.2.8.8-tetra-ethoxycarbonyl-1.3.7-triarsa-tricyclo[3.3.1.03,7]nonan und 5-Methyl-1.3.7-triarsa-2.8-diselena-tricyclo[3.3.1.03,7]nonan / Chemistry of Polyfunctional Molecules, 80 [1]. Crystal and Molecular Structures of the Heteronoradam antanes 5-Methyl-2.2.8.8-tetra-ethoxycarbonyl-1.3.7-triarsa-tricyclo[3.3.1.03,7]nonane and 5-M ethyl-1.3.7-triarsa-2.8-diselena-[3.3.1.03,7]nonane

  • Gerhard Thiele , Heinz W. Rotter , Martin Lietz and Jochen Ellermann
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1984-1008
Download article (PDF)

The molecular and crystal structures of the nor-heteroadam antanes CH3C(CH2As)3[C(COOCH2CH3)2]2 (1) and CH3C(CH2As)3Se2 (2) have been investigated in order to obtain confirmation of the rare structures deduced earlier from mass, 1H NMR and vibrational spectroscopy. Crystals of 1 are triclinic, space group P1̄-C1i with a - 769.27(30), b = 1036.09(14), c = 1599.18(17) pm, α = 98.236(10)°, β = 97.987(18)°, γ = 103.633(20)° and Z = 2. On the basis of 1821 unique reflections the structure was refined to a weighted R value of 5.28%. The crystals of 2 are monoclinic, space group P 21/c-C52h with a = 1102.73(23), b - 727.49(14), c = 1281.27(42) pm. β = 98.803(21)° and Z = 4. On the basis of 1065 unique reflections the structure was refined to a weighted R value of 5.93%.

Several attempts to synthesize CH3C(CH2As)3Te2 failed.

: Crystal Structures; Heteronoradamantanes; Arsenic; Selenium
Received: 1984-3-23
Published Online: 2014-6-2
Published in Print: 1984-10-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Download article (PDF)
From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 39 Issue 10

Journal and Issue

Articles in the same Issue

Fluoride und Fluorosäuren, VIII [1]. Über eine fehlgeordnete feste Phase des SF4 sowie die Kristallstrukturen von Produkten seiner unbeabsichtigten Hydrolyse in Glasapparaturen, SiF4 (Neubestimmung) und SOF2 / Fluorides and Fluoro Acids, VIII [1]. On a Disordered Solid Phase of SF4 and the Crystal Structures of Products of its Unintentional Hydrolysis in Glass Apparatus, SiF4 (Redetermination) and SOF2
Fluoride und Fluorosäuren, IX [1]. Verbindungsbildung im System NOF–HF sowie Kristallstrukturen von NOF·3 HF und NOF·4 HF / Fluorides and Fluoro Acids, IX [1]. Compound Formation in the System NOF–HF and Crystal Structures of NOF·3HF and NOF·4HF
Beiträge zur Chemie des Phosphors, 145 [1]. Neue Lithium-hydrogenpolyphosphide durch Metallierung von Diphosphan / Contributions to the Chemistry of Phosphorus, 145 [1]. Novel Lithium Hydrogen Polyphosphides Through Metalation of Diphosphane
Cyclisierung von Bis(2,2,2-trifluorethoxy)-1,2-diiminoethan mit Schwefel-, Selen-, Phosphor- und Arsenchloriden / Cyclisation of Bis(2,2,2-trifluoroethoxy)-1,2-diiminoethane with Sulfur, Selenium, Phosphorus, and Arsenic Chlorides
The Electronic Structures of the Group V Series ER3 (E = N→Sb; R=H, Hal). An Intercomparison of Photoelectron Spectra and SCC–Xα Calculations [1]
Polymere Methylphosphono-vanadate: Struktur von K[CH3PVO5]·H2O / Polymeric M ethylphosphono Vanadates: Structure of K[CH3PVO5]·H2O
Synthesis, Crystal Structure and Electrochemistry of μ-Acetatodi-μ-hydroxo-bis[(1,4,7-triazacyclononane)ruthenium(III)]-tris-iodide. Characterization of Some Ru(II)—Ru(III) Mixed Valence Species
Chemie polyfunktioneller Moleküle, 80 [1]. Kristall- und Molekülstrukturen der Heteronoradamantane 5-Methyl-2.2.8.8-tetra-ethoxycarbonyl-1.3.7-triarsa-tricyclo[3.3.1.03,7]nonan und 5-Methyl-1.3.7-triarsa-2.8-diselena-tricyclo[3.3.1.03,7]nonan / Chemistry of Polyfunctional Molecules, 80 [1]. Crystal and Molecular Structures of the Heteronoradam antanes 5-Methyl-2.2.8.8-tetra-ethoxycarbonyl-1.3.7-triarsa-tricyclo[3.3.1.03,7]nonane and 5-M ethyl-1.3.7-triarsa-2.8-diselena-[3.3.1.03,7]nonane
Synthese und Reaktivität von [5-exo-Phosphino-η4-cyclopentadien]- tricarbonyleisenkomplexen / Synthesis and Reactivity of [5-exo-Phosphino-η4-cyclopentadiene] Tricarbonyliron Complexes
Difluor-bis(methylamino)-t-butyl-phosphoran Darstellung und NMR-Daten / Difluoro-bis(methylamino)-t-butyl-phosphorane Preparation and NMR Data
Structural Studies of Benzene Derivatives, XII [1]. The Molecular Structure of 3,5-Dimethylbenzoic Acid in the Crystal, and a Comparison with the Gas Phase Structure of Related Molecules
Zur Reaktion von 1-Sila-2,4-cyclohexadien mit tert-Butyllithium/Trimethylchlorsilan / On the Reaction of 1-Sila-2,4-cyclohexadiene with tert-Butyllithium/Trimethylchlorosilane
1H and 13C NMR Spectroscopic Studies of the Complexation of Phenylenedioxydiacetamides with Calcium and Potassium Cations in Solution
Formaldehydkomplexe / Formaldehyde Complexes
1.3-Dichlor-5-trifluormethyl-1,3-dithia-2,4,6-triazin / 1.3-Dichloro-5-trifluoromethyl-1,3-dithia-2,4,6-triazine
Mesosubstituierte Porphyrine und mesosubstituierte Eisenporphyrine, 2 [1] / meso-Substituted Porphyrins and meso-Substituted Iron Porphyrins, 2 [1]
Dikationether, 3 [1]. Substitutionen an Bis(acridinium)ethern und 9-Trifloxyacridinium-Salzen mit Halogeniden, Pseudohalogeniden und Schwefel-Nucleophilen / Dication Ethers, 3 [1]. Substitution Reactions on Bis(acridinium) Ethers and 9-Trifloxyacridinium Salts by Halides, Pseudohalides and Sulfur Nucleophiles
The Effect of Substituents on the Photochemical Reaction between Naphthalenedicarbonitrile and Methylbenzenes
ESR- und ENDOR-Untersuchungen von p-Benzosemichinon-Diarylthallium-Ionenpaaren / ESR- and ENDO R-Investigations of p-Benzosemiquinone-Diarylthallium Ion Pairs
Chemical Examination of the Seeds of Cassia spectablis
The Chlorination of Di-tert-butyl-2-naphthol+
On the Involvement of Singlet Oxygen in the Biosynthesis of Oxygenation Products of the Furocoumarin Imperatorine
Heterocyclen-Synthesen mit 4.4-Bis(trifluormethyl)-1,3-diazabuta-1,3-dienen, III [1]. Synthese trifluormethyl-substituierter Sechsring-Heterocyclen durch Umsetzung mit Enolethern, Enaminen und Heterokumulenen / Synthesis of Heterocyclic Compounds from 4.4-Bis(trifluorom ethyl)-1,3-diazabuta-1,3-dienes, III [1]. Synthesis of Trifluoromethyl Substituted Six Membered Ring Systems by Reaction with Enolethers, Enamines, and Heterocumulenes
Downloaded on 27.4.2024 from https://www.degruyter.com/document/doi/10.1515/znb-1984-1008/html
Scroll to top button