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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Heterogeneous Catalysis, VI Direct Reduction of Alcohols to Hydro- carbons [1]

  • Wilhelm F. Maier , Irina Thies and Paul von Ragué Schleyer
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1982-0323
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Abstract

Secondary and tertiary alcohols are converted cleanly to the parent hydrocarbons in the gas phase with H2 in the presence of a Ni/Al2O3 catalyst at 190 °C. Primary alcohols are de-hydroxymethylated; e.g., 1-hydroxymethylada-mantane (4) gives adamantane (1). Alumina alone, in the absence of Ni, results in the formation of homoadamantane (5) from 4.

Keywords: Gas Phase Hydrogenolysis; Homoadamantane Preparation
Received: 1981-8-13
Published Online: 2014-6-2
Published in Print: 1982-3-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 37 Issue 3

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