Change language
English Deutsch
Change currency
€ EUR £ GBP $ USD
BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Synthese und Molekülstruktur der dreikernigen Cluster-Verbindung (η5C5Me5)IrFe2(CO)9 / Synthesis and Molecular Structure of the Trinuclear Cluster Compound (η5-C5Me5)IrFe2(CO)9

  • Ernst Guggolz , Manfred L. Ziegler , Willibald Kalcher , Johann Plank , Doris Riedel and Wolfgang A. Herrmann
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1981-0901
Download article (PDF)

Abstract

Reaction of triirondodecacarbonyl (1) with the dinuclear chloroiridium complex [(η5 -C5Me5)Ir(μ-Cl)Cl]2 (2) in benzene at 50 °C yields the novel mixed iron iridium cluster of composition (η5 -C5Me5)IrFe2(CO)9 (8) the molecular structure of which has been established by X-ray diffraction methods. The mononuclear half-sandwich complex (η5 -C5Me5)Ir(CO)2 (4) present in the reaction mixture was found to represent the immediate precursor of the cluster compound 8.

Keywords: Iron; Iridium; Carbonyl Complexes; Pentamethylcyclopentadienyl
Received: 1981-4-8
Published Online: 2014-6-2
Published in Print: 1981-9-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Download article (PDF)
From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 36 Issue 9

Journal and Issue

Articles in the same Issue

Synthese und Molekülstruktur der dreikernigen Cluster-Verbindung (η5C5Me5)IrFe2(CO)9 / Synthesis and Molecular Structure of the Trinuclear Cluster Compound (η5-C5Me5)IrFe2(CO)9
Photochemische Reaktionen von Re2(CO)10 in Gegenwart von Cyclooctatetraen und 1.3-Butadien / Photochemical Reactions of Re2(CO)10 in the Presence of Cyclooctatriene and 1,3-Butadiene
Darstellung und Charakterisierung von Cyclotri(silaselan) (H2Si-Se)3 / Preparation and Characterisation of Cyclotri(silaselane) (H2Si-Se)3
Darstellung von 2-Amino-1.3.2λ3(λ5)-dioxaphospholanen / Synthesis of 2-Amino-1,3,2λ3 (λ5)-dioxaphospholanes
Acyl-und Alkylidenarsane, V [1] (Dimethylaminomethyliden)-phenylar8an, ein acyclisches Alkylidenarsan / Acyl-and Alkylidenearsines, V [1] (Dimethylaminomethylidene)-phenylarsine, an Acyclic Alkylidenearsine
Nachweis von Se6, Se7 und Se8 in Lösungen yon Selen mittels Hochdruckflüssigkeitschromatographie / Detection, of Se6, Se7 and Se8 in Selenium Solutions by High-Pressure Liquid Chromatography
Über die inhibierende Wirkung grenzflächenaktiver Stoffe auf die polarographische Reduktion von Cd2+ -, Zn 2+ -und Co 2+ -Ionen in wasser-methanolischen und methanolischen Lösungen / On the Inhibition Effect of Surfactants on the Polarographic Reduction of Cd 2+ , Zn 2+ and Co 2+ Ions in Aqueous Methanolic and Methanolic Solutions
Schwefel(VI)-oxid-chlorid-imide und Schwefel(VI)-oxid-fluorid-imide [1] / Sulfur(VI)-oxide-chloride-imides and Sulfur(VI)-oxide-fluoride-imides [1]
Neue Verbindungen mit der Ca9Mi4Bi9-Struktur: Zur Kenntnis von Ca9Cd4Bi9, Sr9Cd4Bi9 und Ca9Zn4Sb9 / New Compounds with the Ca9Mn4Bi9 Structure: Ca9Cd4Bi9, Sr9Cd4Bi9, and Ca9Zn4Sb9
Anhydride und Thioanhydride von tert-Butylstibinig-und -stibonigsäuren / Anhydrides and Thioanhydrides of tert-Butylstibinous-and Stibonous Acids
Koordinationschemie reduzierter N-Heterozyklen. Komplexe des Pyrazin-Radikalanions mit Phenylmetallkationen +MPh von Beryllium, Magnesium und Zink / Coordination Chemistry of Reduced N-Heterocycles. Complexes of Pyrazine Anion Radical with Phenyl Metal Cations +MPh of Beryllium, Magnesium and Zinc
Phosphinsubstituierte Chelatliganden, II [1] Thiocarbamoylphosphinsulfid-und -oxid-Komplexe des Mangans und Rheniums / Phosphine Substituted Chelate Ligands, II [1] Thiocarbamoylphosphine Sulfide and Oxide Complexes of Manganese and Rhenium
cis-Dichloro-(1 ,5-bisdiphenylphosphanopentane)platinum(II). Synthese, Krystall– und Molekülstruktur / cis-Dichloro-(1 ,5-bisdiphenylphosphanopentane)platinum(II). Synthesis, Crystal and Molecular Structure
Darstellung und Eigenschaften der ferf-ButyHminovanadin(V)-Verbindungen tC4H9N =VX3 (X = Cl, RCOO) / Synthesis and Properties of Jerf -Butylimino vanadium (V) Compounds tC4H9N = VX3 (X = Cl, RCOO)
Electron Spin Resonance Studies on Conformational Changes of the Sarcoplasmic Reticulum Ca2+ – ATPase Induced by Synergistic Action of Calcium and ATP
Über die Struktur des Tris-[norbornyl-2] methanols / On the Structure of Tris-[norbornyl-2]methanol
Condensation of 3-Aryl-2,4-dicarboethoxy-5-hydroxy-5-methylcyclohexanones with o-Phenylenediamine, Thiourea, α,β-Unsaturated Ketones and Hydrazines
Polymergebundenes Sulfonylazid zur entformylierenden Diazogruppen-Übertragung und zur Diazo -cyclopolyen -Synthese / Polymer Anchored Sulfonylazide for Deformylating Diazo Group Transfer and the Synthesis of Diazo-cyclopolyenes
Alkaloide aus Catharanthus roseus-Zellkulturen, II [1] / Alkaloids from Catharanthus roseus Tissue Cultures, II [1]
Isolierung und Strukturuntersuchungen an der Ribonuclease T2 aus Aspergillus oryzae, I. / Isolation and Structure Investigations on the Ribonuclease T2 from Aspergillus oryzae, I
Taifine, a New Alkaloid from Ruta chalepensis L
3.5-Dihydroxy-6.7.8-trimethoxyflavon aus Heiichrysum graveolens: Bestätigung der Konstitution / Confirmation of the Structure of an Extractive from Helichrysum graveolens as 3,5-Dihydroxy-6,7,8-trimethoxyflavone
Die 2.2.2-Trichlor -tert-butyloxycarbonyl -Gruppe als N-Schutzgruppe bei Oligonukleotidsynthesen / The 2,2,2-Trichloro-tert-butoxycarbonyl Group, an N-Protecting Group in Oligonucleotide Synthesis
Eine einfache Darstellung von Khaplofolin, Dihydroflindersin und verwandten Alkaloiden [1] / Synthesis of Khaplofoline, Dihydroflindersine and Related Alkaloids [1]
New Anthraquinones and Anthraquinone Glycosides from Morinda lucida
Umsetzungen von N-Brom-N-Natriumcarbamidaten mit Organometallverbindungen. Synthesen von N-Brom-N-Metallverbindungen des Zinns und Bleis / Reactions of N-Bromo-N-sodiocarbamidates with Metalorganic Compounds. Syntheses of N-Bromo-N-metallo Compounds of Tin and Lead
Crystal and Molecular Structure of 4-Oxo-6-iodoqwnolinium(OIQn)-2,2'- (2,5-cyclohexadiene-1,4-diylidene)- bispropanedinitrile (TCNQ)
Untersuchung der symmetrischen Phosphat-Valenzschwingung in gemischten Calcium-Strontium-Apatiten / Investigation on the Symmetric Phosphate Stretching Vibration in Mixed Calcium -Strontium -Apatites
ABX-Verbindungen mit modifizierter Ni2In-Struktur / ABX-Compounds with a Modified Ni2In Structure
Magnetische Eigenschaften von AB2X2-Verbindungen im CaAl2Si2-Typ / Magnetic Properties of AB2X2 Compounds with the CaAl2Si2 Structure
η1,η3-Octadienediyl-palladium Complexes
The Tetrabutylammonium Salt of 2-Thioxo-1,3-dithiol-4,5-dithiolate as a Starting Material for Preparation of Organometallic Conductors
Solid Phase Peptide Synthesis by Four Component Condensation: Peptide Formation on an Isocyano Polymer Support
BERICHTIGUNG
Downloaded on 1.5.2024 from https://www.degruyter.com/document/doi/10.1515/znb-1981-0901/html
Scroll to top button