The EPR zero-field splitting D (= b02 ) and its pressure and temperature dependence for trigonal Mn2+ centers in low and room temperature phases in [Zn(H2O)6](BF4)2 :Mn2+ crystal are studied by a high-order perturbation formula based on the dominant spin-orbit coupling mechanism. From the studies, the local trigonal distortion angles, the local angular compressibilities and the local angular thermal expansion coefficients for Mn2+ centers in both phases of the [Zn(H2O)6](BF4)2 crystal are estimated. The results are discussed
Keywords : Electron Paramagnetic Resonance; Crystal- and Ligand-Field Theory; Defect Structure and Properties; Mn2+; [Zn(H2O)6](BF4)2
Received: 2006-2-21
Published Online: 2014-6-2
Published in Print: 2006-6-1
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