Skip to content
BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Formation of Cyanopolyynes in Gas Discharges

  • G. Winnewisser , R. A. Creswell , M. Winnewisser and M. Winnewisser

Abstract

Cyanodiacetylene, H(C ≡ C)2 CN has been produced by a radiofrequency discharge in a mixture of acetylene, HCCH, and hydrogen cyanide, HCN. This reaction is of astrophysical importance, since it lends support to the possibility of the ion-molecule formation scheme of producing long carbon chain molecules in interstellar sources. From a measurement of the J = 4←3 transition of HC5N the nuclear quadrupole coupling constant eqQ = - 4.242 (30) MHz was determined.

Received: 1978-7-26
Published Online: 2014-6-2
Published in Print: 1978-10-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Downloaded on 24.5.2024 from https://www.degruyter.com/document/doi/10.1515/zna-1978-1008/html
Scroll to top button