Abstract
A composite material based dual-emission probe for Fe3+ was prepared by the hybridization of a three-dimensional framework with CdSe/ZnS quantum dots (QDs)-doped silica nanoparticles. The obtained probe showed characteristic fluorescence emissions of CdSe/ZnS QDs (red) and Cd-metal-organic framework (MOF, blue) under a single exciation wavelength. Upon the detection of Fe3+, only the fluorescence of Cd-MOF was quenched, whereas the red fluorescence of CdSe/ZnS QDs particles was mostly reserved. Consequently, the variation of the two fluorescence intensity ratios displays a continuous color change from blue to red upon exposure to different amounts of Fe3+ ions, which can be easily observed under a UV lamp.
Acknowledgements
This work was supported by the National Natural Science Foundation of China (Nos. 21601050), NSFC-Henan region mutual funds (U1604124), the key scientific research project of Henan higher education (16A150010), Science and technology research project of Henan province (152102210314).
References
[1] L.-Y. Wang, Y. Tian, L.-M. Ding, B. Zhao, X.-Y. He, B. Song, S.-F. Liu, RSC Adv.2017, 7, 16916.10.1039/C7RA00846ESearch in Google Scholar
[2] X. Luo, X. Zhang, Y.-L. Duan, X.-L. Wang, J.-M. Zhao, Dalton Trans.2017, 46, 6303.10.1039/C7DT00715ASearch in Google Scholar
[3] X.-Y. Dong, R. Wang, J.-Z. Wang, S.-Q. Zang, T. C. W. Mark, J. Mater. Chem. A2015, 3, 641.10.1039/C4TA04421ESearch in Google Scholar
[4] J. Wang, M. Jiang, L. Yan, R. Peng, J. Meng, F. Huang, Y. Li, P.-Y. Wu, Inorg. Chem.2016, 55, 12660.10.1021/acs.inorgchem.6b01815Search in Google Scholar PubMed
[5] B.-D. Wang, J.-N. Hai, Z.-C. Liu, Q. Wang, Z.-Y. Yang, S.-H. Sun, Angew. Int. Ed. Chem.2010, 49, 4576.10.1002/anie.201001373Search in Google Scholar PubMed
[6] L.-W. He, X.-L. Yang, K.-X. Xu, W.-Y. Lin, Chem. Commun.2017, 53, 4080.10.1039/C7CC00512ASearch in Google Scholar PubMed
[7] J. L. Bricks, A. Kovalchuk, C. Trieflinger, M. Nofz, M. Buschel, A.-L. Tolmachev, J. Daub, K. Rurack, J. Am. Chem. Soc.2005, 127, 13522.10.1021/ja050652tSearch in Google Scholar PubMed
[8] S.-C. Zhou, M. Zhang, F.-Y. Yang, F. Wang, C. Y. Wang, J. Mater. Chem. C2017, 5, 2466.10.1039/C6TC05253CSearch in Google Scholar
[9] M. Zheng, H.-Q. Tan, Z.-G. Xie, L.-G. Zhang, X.-B. Jing, Z.-C. Sun, ACS Appl. Mater. Interfaces.2013, 5, 1078.10.1021/am302862kSearch in Google Scholar PubMed
[10] H.-J. Zhang, R.-Q. Fan, W. Chen, J.-Z. Fan, Y.-W. Dong, Y. Song, X. Du, P. Wang, Y.-L. Yang, Cryst. Growth Des.2016, 16, 5429.10.1021/acs.cgd.6b00903Search in Google Scholar
[11] R.-F. Bogale, Y.-Z. Chen, J.-W. Ye, Y.-Y. Yang, A. Rauf, L.-Y. Duan, P. Tian, G.-L. Ning, Sens. Actuators B2017, 245, 171.10.1016/j.snb.2017.01.177Search in Google Scholar
[12] B.-L. Hou, D. Tian, J. Liu, L.-Z. Dong, S.-L. Li, D.-S. Li, Y.-Q. Lan, Inorg. Chem.2016, 55, 10580.10.1021/acs.inorgchem.6b01809Search in Google Scholar PubMed
[13] G.-F. Ji, J.-J. Liu, X.-C. Gao, W. Sun, J.-Z. Wang, S.-L. Zhao, Z.-L. Liu, J. Mater. Chem. A2017, 5, 10200.10.1039/C7TA02439HSearch in Google Scholar
[14] G.-X. Wen, Y.-P. Wu, W.-W. Dong, J. Zhao, D.-S. Li, J. Zhang, Inorg. Chem.2016, 55, 10114.10.1021/acs.inorgchem.6b01876Search in Google Scholar PubMed
[15] Y. Zhou, H.-H. Chen, B. Yan, J. Mater. Chem. A2014, 2, 13691.10.1039/C4TA01297FSearch in Google Scholar
[16] R.-W. Huang, Y.-S. Wei, X.-Y. Dong, X.-H. Wu, C.-X. Du, S.-Q. Zang, T. C. W. Mak, Nat. Chem.2017, 9, 689.10.1038/nchem.2718Search in Google Scholar PubMed
[17] K. Zhang, H.-B. Zhou, Q.-S. Mei, S.-H. Wang, G.-J. Guan, R.-Y. Liu, J. Zhang, Z.-P. Zhang, J. Am. Chem. Soc.2011, 133, 8424.10.1021/ja2015873Search in Google Scholar PubMed
[18] M. Royzen, Z.-H. Dai, J. W. Canary, J. Am. Chem. Soc.2005, 127, 1612.10.1021/ja0431051Search in Google Scholar PubMed
[19] F.-M. Ye, C.-F. Wu, Y.-H. Jin, Y.-H. Chan, X.-J. Zhang, D.-T. Chu, J. Am. Chem. Soc.2011, 133, 8146.10.1021/ja202945gSearch in Google Scholar PubMed PubMed Central
[20] K. Komatsu, Y. Urano, H. Kojima, T. Nagano, J. Am. Chem. Soc.2007, 129, 13447.10.1021/ja072432gSearch in Google Scholar PubMed
[21] X.-J. Liu, N. Zhang, T. Bing, D.-H. Shangguan, Anal. Chem.2014, 86, 2289.10.1021/ac404236ySearch in Google Scholar PubMed
[22] A. Zhu, Q. Qu, X.-L. Shao, B. Kong, Y. Tian, Angew. Chem. Int. Ed.2012, 51, 7185.10.1002/anie.201109089Search in Google Scholar PubMed
[23] S.-J. Zhu, Q.-N. Meng, L. Wang, J.-H. Zhang, Y.-B. Song, H. Jin, K. Zhang, H.-C. Sun, H.-Y. Wang, B. Yang, Angew. Chem. Int. Ed.2013, 52, 3953.10.1002/anie.201300519Search in Google Scholar PubMed
[24] X.-L. Wang, Y. Xiong, X.-T. Sha, G.-C. Liu, H.-Y. Lin, Cryst. Growth Des.2017, 17, 483.10.1021/acs.cgd.6b01299Search in Google Scholar
[25] H.-J. Li, Q.-Q. Li, Y.-L. He, Z.-Q. Xu, Q. J. Tang, New J. Chem.2017, 41, 15204.10.1039/C7NJ02904GSearch in Google Scholar
[26] H.-J. Li, Q.-Q. Li, Z.-Q. Xu, N. Zhang, Z.-Q. Xu, Y. Wang, Y. Wang, Cryst. Growth Des.2018, 18, 6248.10.1021/acs.cgd.8b01053Search in Google Scholar
[27] H.-J. Li, Q.-Q. Li, Y.-L. He, N. Zhang, Z.-Q. Xu, Y. Wang, Materials2018, 11, 744.10.3390/ma11050744Search in Google Scholar PubMed PubMed Central
[28] G.-M. Sheldrick, Acta Crystallogr.2008, A64, 112.10.1107/S0108767307043930Search in Google Scholar PubMed
[29] W.-J. Gong, Z.-G. Ren, H.-X. Li, J.-G. Zhang, J.-P. Lang, Cryst. Growth Des.2017, 17, 870.10.1021/acs.cgd.6b01728Search in Google Scholar
[30] M. Zheng, H.-Q. Xie, Z.-G. Zhang, L.-G. Jing, Z.-C. Sun, Inorg. Chem.2017, 56, 2936.10.1021/acs.inorgchem.6b03075Search in Google Scholar PubMed
[31] S.-S. Nagarkar, A.-V. Desai, S.-K. Ghosh, Chem. Commun.2014, 50, 8915.10.1039/C4CC03053BSearch in Google Scholar
[32] T.-D. Gauthier, E.-C. Shane, W.-F. Guerin, W.-R. Seitz, C.-L. Grant, Sci. Technol.1986, 20, 1162.10.1021/es00153a012Search in Google Scholar
[33] J. Keizer, J. Am. Chem. Soc.1983, 105, 1494.10.1021/ja00344a013Search in Google Scholar
[34] Q. Tang, S.-X. Liu, Y.-W. Liu, J. Miao, S.-J. Li, L. Zhang, Z. Shi, Z.-P. Zheng, Inorg. Chem.2013, 52, 2799.10.1021/ic400029pSearch in Google Scholar PubMed
[35] Q. Freeman, I. Willner, Chem. Soc. Rev.2012, 41, 4067.10.1039/c2cs15357bSearch in Google Scholar PubMed
Supplementary Material
The online version of this article offers supplementary material (https://doi.org/10.1515/zkri-2018-2130).
©2019 Walter de Gruyter GmbH, Berlin/Boston
