Abstract
The last few years have seen an increasing interest in the study of lanthanide-silver (Ln-Ag) heterometallic coordination polymers due to their potential applications. It has led to intense activity of chemists to produce Ln-Ag heterometallic coordination polymers and investigate their properties. In this review, we summarize recent research development in the fascinating and challenging field of Ln-Ag heterometallic coordination polymers. This review covers 182 Ln-Ag heterometallic coordination polymers, which are categorized by the kind of ligand as N-heterocyclic carboxylate ligands and others. There are three categories of Ln-Ag coordination polymer based on N-heterocyclic carboxylate ligands: one dimensional (1D), 2D, and 3D. The 3D part was divided into Ln-Ag coordination polymers based on pyridine carboxylate ligands and other N-heterocyclic carboxylate ligands. This perspective illustrates the coordination features of compounds constructed by N-heterocyclic carboxylate ligands. Luminescent properties are also discussed.
About the authors
Ming Fang obtained her BS degree from Hebei Normal University in 2006, and received her PhD degree from Nankai University in 2012 under the supervision of Prof. Peng Cheng. She is currently a assistant researcher in the Department of Chemistry at Hebei Normal University of Science and Technology. Her research interest focuses on the development of functional materials of lanthanide based coordination polymers.
Bin Zhao obtained his B.S. degree in 1998 from Sichuan Normal College, China, and his Ph.D. degree in 2004 under the supervision of Prof. Peng Cheng from NKU. Then he joined the faculty at NKU and was appointed a professor in 2009. His interests focus upon the synthesis and functions of complicated cluster compounds, luminescent probes, multi-functional MOFs materials and molecule magnetic materials.
Acknowledgments
This work was supported by the 973 Program (2012CB821702 and 2011CB935902), NSFC (21421001 and 21473121), 111 project (B12015), MOE Innovation Team (IRT13022 and IRT-13R30) of China, and the Selected Overseas Scholar, Hebei Province (C2013001051).
References
Brouca-Cabarrecq, C.; Fava, O.; Mosset, A. Synthesis and crystal structure of a new bimetallic complex of diethylenetriamine pentaacetic acid: [YbAg2(dtpa)(H2O)]·3H2O. J. Chem. Crystallogr. 1999, 29, 81–86.Search in Google Scholar
Cai, Y. P.; Yu, Q. Y.; Zhou, Z. Y.; Hu, Z. J.; Fang, H. C.; Wang, N.; Zhan, Q. G.; Chen, L.; Su, C. Y. Metal-directed assembly of two 2-D 4d-4f coordination polymers based on elliptical triple-deck cylinders hinged by meso-double helical chains. CrystEngComm 2009a, 11, 1006–1013.10.1039/b823457dSearch in Google Scholar
Cai, Y. P.; Zhou, X. X.; Zhou, Z. Y.; Zhu, S. Z.; Thallapally, P. K.; Liu, J. Single-crystal-to-single-crystal transformation in a one-dimensional Ag-Eu helical system. Inorg. Chem. 2009b, 48, 6341–6343.Search in Google Scholar
Cai, S. L.; Zheng, S. R.; Wen, Z. Z.; Fan, J.; Wang, N.; Zhang, W. G. Two types of new three-dimensional d-f heterometallic coordination polymers based on 2-(pyridin-3-yl)-1H-imidazole-4,5-dicarboxylate and oxalate ligands: syntheses, structures, luminescence, and magnetic properties. Cryst. Growth Des. 2012, 12, 4441–4449.Search in Google Scholar
Chen, Y.; Ma, S. Microporous lanthanide metal-organic frameworks. Rev. Inorg. Chem. 2012, 32, 81–100.Search in Google Scholar
Chen, M. S.; Su, Z.; Chen, M.; Chen, S. S.; Li, Y. Z.; Sun, W. Y. Three-dimensional lanthanide-silver heterometallic coordination polymers: syntheses, structures and properties. CrystEngComm 2010, 12, 3267–3276.Search in Google Scholar
Chen, M.; Chen, M. S.; Okamura, T.; Lv, M. F.; Sun, W. Y.; Ueyama, N. A series of silver(I)-lanthanide(III) heterometallic coordination polymers: syntheses, structures and photoluminescent properties. CrystEngComm 2011, 13, 3801–3810.Search in Google Scholar
Cui, H. L.; Zhan, S. Z.; Li, M.; Ng, S. W.; Li, D. Luminescent isomeric Pr-Ag coordination polymers immobilized with organic sensitizer and Ag-S clusters. Dalton Trans. 2011, 40, 6490–6493.Search in Google Scholar
Cui, Y.; Yue, Y.; Qian, G.; Chen, B. Luminescent functional metal organic frameworks. Chem. Rev. 2012, 112, 1126–1162.Search in Google Scholar
Deng, H.; Li, Y. H.; Qiu, Y. C.; Liu, Z. H.; Zeller, M. Construction of isostructural Ln-Ag (Ln=Eu; Tb; Dy) nano-channel heterometallic coordination frameworks based on pyrazine-2-carboxylate and oxalate ligands. Inorg. Chem. Commun. 2008, 11, 1151–1154.Search in Google Scholar
Ding, F.; Song, X.; Jiang, B.; Smet, P. F.; Poelman, D.; Xiong, G.; Wu, Y. L.; Gao, E. J.; Verpoort, F.; Sun, Y. G. CrystEngComm 2012, 14, 1753–1759.10.1039/c1ce06012kSearch in Google Scholar
Fan, L. Q.; Chen, Y.; Wu, J. H.; Huang, Y. F. Synthesis, crystal structures and luminescent properties of two 4d-4f Ln-Ag heterometallic coordination polymers based on anion template. J. Solid State Chem. 2011, 184, 899–904.Search in Google Scholar
Gai, S.; Li, C.; Yang, P.; Lin, J. Recent progress in rare earth micro/nanocrystals: soft chemical synthesis, luminescent properties, and biomedical applications. Chem. Rev. 2014, 114, 2343–2389.Search in Google Scholar
Gerasko, O. A.; Mainicheva, E. A.; Naumova, M. I.; Neumaier, M.; Kappes, M. M.; Lebedkin, S.; Fenske, D.; Fedin, V. P. Sandwich-type tetranuclear lanthanide complexes with cucurbit[6]uril: from molecular compounds to coordination polymers. Inorg. Chem. 2008, 47, 8869–8880.Search in Google Scholar
Getman, R. B.; Bae, Y. S.; Wilmer, C. E.; Snurr, R. Q. Review and analysis of molecular simulations of methane, hydrogen, and acetylene storage in metal organic frameworks. Chem. Rev. 2012, 112, 703–723.Search in Google Scholar
Goodname, D. M. L.; Müller, T. E.; Williams, D. J. The first structurally characterized silver/lanthanide heterometallic complex; synthesis and crystal structure of Ag[Gd(dipic)2(H2O)3] ·3H2O (where H2dipic=2,6- pyridinedicarboxylic acid). Polyhedron 1992, 11, 1513–1516.Search in Google Scholar
Gu, X. J.; Xue, D. F. Selected controlled synthesis of three-dimensional 4d-4f heterometallic coordination frameworks by lanthanide carboxylate subunits and silver centers. Cryst. Growth Des. 2006a, 6, 2551–2557.Search in Google Scholar
Gu, X. J.; Xue, D. F. Spontaneously resolved homochiral 3D lanthanide-silver heterometallic coordination framework with extended helical Ln-O-Ag subunits. Inorg. Chem. 2006b, 45, 9257–9261.Search in Google Scholar
Gu, X. J.; Xue, D. F. Self-assembly of 3-D 4d-4f coordination frameworks based on 1-D inorganic heterometallic chains and linear organic linkers. CrystEngComm 2007, 9, 471–477.Search in Google Scholar
Gu, X. J.; Xue, D. F.; Ratajczak, H. Crystal engineering of lanthanide-transition-metal coordination polymers. J. Mol. Struct. 2008, 887, 56–66.Search in Google Scholar
Guo, D.; Duan, C.; Lu, F.; Hasegawa, Y.; Meng, Q.; Yanagida, S. Lanthanide heterometallic molecular squares Ru-2-Ln(2) exhibiting sensitized near-infrared emission. Chem. Commun. 2004, 1486–1487.10.1039/B403519DSearch in Google Scholar PubMed
Han, L. J.; Zhou, W. L.; Yang, Y. H.; Xu, Y. Synthesis, characterization and luminescence of two unusual 4d-4f Ln-Ag coordination compounds. Inorg. Chem. Commun. 2009, 12, 385–387.Search in Google Scholar
Han, L.; Ma, Y. R.; Chen, L. C.; Huo, S. M.; Qiu, T. R.; Zeng, R. H.; Meng, Q. H.; Luo, Y. F. Synthesis, structure and thermal behavior of a new coordination polymer based on mixed pyrazine-2-carboxylate and oxalate ligands. J. Chem. Crystallogr. 2011, 41, 596–600.Search in Google Scholar
Handa, S.; Gnanadesikan, V.; Matsunaga, S.; Shibasaki, M. Syn-selective catalytic asymmetric nitro-mannich reactions using a heterobimetallic Cu-Sm-Schiff base complex. J. Am. Chem. Soc. 2007, 129, 4900–4901.Search in Google Scholar
He, Y. K.; Han, Z. B. Hexanuclear 4d-4f complexes [Ln2Ag4(ina)8(H2O)10][NO3]2·4H2O(Ln=Sm, Eu, Dy): syntheses, structures and photoluminescent properties. Inorg. Chem. Commun. 2007, 10, 1523–1526.Search in Google Scholar
He, Y. K.; An, H. Y.; Han, H. B. 3D pillar-layered coordination polymers based on 4de4f heterometallic assembly. Solid State Sci. 2009, 11, 49–55.Search in Google Scholar
Huang, Y. G.; Jiang, F. L.; Hong, M. C. Magnetic lanthanide-transition-metal organic-inorganic hybrid materials: from discrete clusters to extended frameworks. Coord. Chem. Rev. 2009, 253, 2814–2834.Search in Google Scholar
Huang, L.; Mei, H.; Chen, L.; Xu, Y. A New 3D 4d-4f La-Ag coordination polymer constructed by interesting [Ag2]n and flat [La2(IN)6(CH3COO)]n layers. Z. Anorg. Allg. Chem. 2012, 638, 996–1000.Search in Google Scholar
Jin, J.; Niu, S. Y.; Han, Q.; Chi, Y. X. Synthesis and structure of a series of new luminescent Ag-Ln coordination polymers and the influence of the introduction of an Ag(I) ion on NIR luminescence from the Ln(III) centre. New J. Chem. 2010, 34, 1176–1183.Search in Google Scholar
Kurmoo, M. Magnetic metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1353–1379.Search in Google Scholar
Li, X. F.; Cao, R. Syntheses, structure and properties of three-dimensional pillared-layer Ag(I)-Ln (III) heterometallic coordination polymers based on mixed isonicotinate and hemimellitate ligands. J. Solid State Chem. 2012, 196, 182–186.Search in Google Scholar
Li, Z. Y.; Dai, J. W.; Wang, N.; Qiu, H. H.; Yue, S. T.; Liu, Y. L. A series of three-dimensional 4d-4f heterometallic coordination polymers with six-connected doubly interpenetrated pcu net topology: structural, photoluminescent, and magnetic properties. Cryst. Growth Des. 2010a, 10, 2746–2751.Search in Google Scholar
Li, Z. Y.; Dai, J. W.; Yue, S. T.; Liu, Y. L. Novel three-dimensional Ln-Ag 4d-4f heteropentametallic helix-based microporous metal-organic framework with unprecedented (3,4,5,6)-connected topology constructed from isonicotinate ligand. CrystEngComm 2010b, 12, 2014–2017.10.1039/c000058bSearch in Google Scholar
Li, X. F.; Huang, Y. B.; Zhao, H.; Zeng, Q. H. Three-dimensional Yb(III)-Ag(I) heterometallic coordination polymer showing dual photoluminescent emissions in the visible and near-infrared regions. Inorg. Chem. Commun. 2012a, 23, 132–136.10.7312/li--16274-024Search in Google Scholar
Li, X. F.; Huanga, Y. B.; Cao, R. A family of three-dimensional 3d-4f and 4d-4f heterometallic coordination polymers based on mixed isonicotinate and 2-sulfobenzoate ligands: syntheses, structures and photoluminescent properties. Dalton Trans. 2012b, 41, 6195–6205.Search in Google Scholar
Lian, Q. Y.; Huang, C. D.; Zeng, R. H.; Qiu, Y. C.; Mou, J. X.; Deng, H.; Zeller, M. Synthesis, characterization and thermal behavior of two 4d-4f coordination polymers based on N and O donor ligands. Z. Anorg. Allg. Chem. 2009, 635, 393–398.Search in Google Scholar
Liang, Y. C.; Cao, R.; Su, W. P.; Hong, M. C. A Gd-Ag Coordination polymer with porous structure via hydrothermal synthesis: [Gd2Ag2(pydc)4(H2O)4]n. Chem. Lett. 2000, 868–869.10.1246/cl.2000.868Search in Google Scholar
Lin, X. M.; Ying, Y.; Chen, L.; Fang, H. C.; Zhou, Z. Y.; Zhan, Q. G.; Cai, Y. P. 3D pillar-layered 4d-4f heterometallic coordination polymers based on pyridine-3,5-dicarboxylate and oxalate mixed ligands. Inorg. Chem. Commun. 2009, 12, 316–320.Search in Google Scholar
Liu, Z. H.; Qiu, Y. C.; Li, Y. H.; Deng, H.; Zeller, M. Synthesis, structures and luminescent properties of 4d-4f heterometallic coordination frameworks based on lanthanide oxalate substructures with nicotinate bridging ligands. Polyhedron 2008, 27, 3493–3499.Search in Google Scholar
Liu, Z. H.; Qiu, Y. C.; Li, Y. H.; Peng, G.; Liu, B.; Deng, H. Isostructural 3D Ln-Ag (Ln=Eu; Dy; Ho) coordination frameworks based on mixed nicotinate and oxalate ligands: synthesis, crystal structures and luminescence. Inorg. Chem. Commun. 2009a, 12, 204–207.Search in Google Scholar
Liu, G. X.; Ren, X. M.; Xu, H.; Nishihara, S.; Huang, R. Y. A 3D Gd-Ag coordination polymer constructed from pyridine-3,5-dicarboxylic acid: synthesis, crystal structure and magnetic properties. Inorg. Chem. Commun. 2009b, 12, 895–897.Search in Google Scholar
Liu, G. X.; Xu, Y. Y.; Ren, X. M.; Nishihara, S.; Huang, R. Y. Self-assembly of 3-D 4d-4f coordination frameworks based on pyridine-3,5-dicarboxylic acid: syntheses, crystal structures and luminescence. Inorg. Chim. Acta 2010, 363, 3727–3732.Search in Google Scholar
Liu, G. X.; Li, X. L.; Zha, X. C.; Zhang, C. Y.; Wang, Y.; Ren, X. M. A Porous 4d-4f heterometallic coordination polymer: synthesis, crystal structure and physical properties. Z. Anorg. Allg. Chem. 2011, 637, 1555–1559.Search in Google Scholar
Liu, Y.; Pan, M.; Yang, Q. Y.; Fu, L.; Li, K.; Wei, S. C.; Su, C. Y. Dual-emission from a single-phase Eu-Ag metal-organic framework: an alternative way to get white-light phosphor. Chem. Mater. 2012a, 24, 1954–1960.10.7312/li--16274-025Search in Google Scholar
Liu, G. X.; Zhou, H.; Zha, X. C.; Zhang, C. Y.; Wang, Y.; Nishihara, S.; Ren, X. M. Syntheses, crystal structures and physical properties of two unusual 4d-4f heterometallic coordination polymers. Inorg. Chim. Acta. 2012b, 387, 308–313.Search in Google Scholar
Ma, D. Y.; Liu, H. L.; Li, Y. W. 3D Ln-Ag (Ln=Nd; Eu) coordination polymers based on isonicotinate and oxalate ligands: synthesis, crystal structures and luminescence. Inorg. Chem. Commun. 2009, 12, 883–886.Search in Google Scholar
Ma, D. Y.; Wang, W. X.; Li, Y. W. 1-D Ln-Ag (Ln=Eu; Tb) heterometallic coordination polymers with pyridine-2,6-dicarboxylate as the single ligand: synthesis, crystal structures, and luminescence. J. Coord. Chem. 2010, 63, 448–456.Search in Google Scholar
Ma, L.; Qiu, Y. C.; Peng, G.; Cai, J. B.; Deng, H.; Zeller, M. Self-assembly of d-f coordination frameworks based on 1H-benzimidazole-5-carboxylic acid: synthesis, structure and luminescence. CrystEngComm 2011, 13, 3852–3861.Search in Google Scholar
Ma, J. X.; Huang, X. F.; Song, X. Q.; Liu, W.S. Assembly of framework-isomeric 4d-4f heterometallic metal-organic frameworks with neutral/anionic micropores and guest-tuned luminescence properties. Chem. Eur. J. 2013, 19, 3590–3595.Search in Google Scholar
Maspoch, D.; Ruiz-Molina, D.; Veciana, J. Old materials with new tricks: multifunctional open-framework materials. Chem. Soc. Rev. 2007, 36, 770–818.Search in Google Scholar
Merkens, C.; Englert, U. Ordered bimetallic coordination networks featuring rare earth and silver cations. Dalton Trans. 2012, 41, 4664–4673.Search in Google Scholar
Mou, J. X.; Zeng, R. H.; Qiu, Y. C.; Zhang, W. G.; Deng, H.; Zeller, M. Construction of three-dimensional Ln-Ag (Ln=Eu; Tm) coordination polymers based on isonicotinate and oxalate ligands. Inorg. Chem. Commun. 2008, 11, 1347–1351.Search in Google Scholar
Peng, G.; Qiu, Y. C.; Liu, Z. H.; Liu, B.; Deng, H. Spontaneous assembly of d-f coordination frameworks: syntheses, structures, and photoluminescence. Cryst. Growth Des. 2010, 10, 114–121.Search in Google Scholar
Qiu, Y. C.; Liu, H. G.; Ling, Y.; Deng, H.; Zeng, R. H.; Zhou, G. Y.; Zeller, M. 3D Ln-Ag (Ln=Nd; Eu) coordination polymers based on N- and O-donor ligands: synthesis, crystal structures and luminescence. Inorg. Chem. Commun. 2007, 10, 1399–1403.Search in Google Scholar
Qiu, Y. C.; Liu, Z. H.; Mou, J. X.; Deng, H.; Zeller, M. Rationally designed and controlled syntheses of different series of 4d-4f heterometallic coordination frameworks based on lanthanide carboxylate and Ag(IN)2 substructures. CrystEngComm 2010, 12, 277–290.Search in Google Scholar
Sharples, J. W.; Collison, D. The coordination chemistry and magnetism of some 3d-4f and 4f amino-polyalcohol compounds. Coord. Chem. Rev. 2014, 260, 1–20.Search in Google Scholar
Song, Y. J.; Chen, X.; Han, Z. B. Crystal structure of a new coordination polymer [LaAg(Pydc)(HPydc)(C2O4)0.5(H2O)2]n (H2Pydc=pyridine-3,5-dicarboxylic acid). Russ. J. Coord. Chem. 2009, 35, 746–750.Search in Google Scholar
Suh, M. P.; Park, H. J.; Prasad, T. K.; Lim, D. W. Hydrogen storage in metal organic frameworks. Chem. Rev. 2012, 112, 782–835.Search in Google Scholar
Sumida, K.; Rogow, D. L.; Mason, J. A.; McDonald, T. M.; Bloch, E. D.; Herm, Z. R.; Bae, T. H.; Long, J. R. Carbon dioxide capture in metal organic frameworks. Chem. Rev. 2012, 112, 724–781.Search in Google Scholar
Sun, Y. G.; Yan, X. M.; Ding, F.; Gao, E. J.; Zhang, W. Z.; Verpoort, F. A novel 3D 4d-4f heterometallic coordination polymer: synthesis, crystal structure and luminescence. Inorg. Chem. Commun. 2008, 11, 1117–1120.Search in Google Scholar
Sun, Y. G.; Wu, Y. G.; Xiong, G.; Smet, P. F.; Ding, F.; Guo, M. Y.; Zhu, M. C.; Gao, E. J.; Poelman, D.; Verpoort, F. Hydrothermal synthesis, crystal structure and properties of Ag(I)-4f compounds based on 1H-benzimidazole-5,6-dicarboxylic acid. Dalton Trans. 2010, 39, 11383–11395.Search in Google Scholar
Terazzi, E.; Guénée, L.; Varin, J.; Bocquet, B.; Lemonnier, J. F.; Emery, D.; Mareda, J.; Piguet, C. Silver baits for the “miraculous draught” of amphiphilic lanthanide helicates. Chem. Eur. J. 2011, 17, 184–195.Search in Google Scholar
Wang, C. C. Hydrothermal synthesis and crystal structure of a novel 3D heteronuclear cerium and silver coordination compound. Asian J. Chem. 2009, 21, 4711–4720.Search in Google Scholar
Ward, M. D. Transition-metal sensitised near-infrared luminescence from lanthanides in d-f heteronuclear arrays. Coord. Chem. Rev. 2007, 251, 1663–1677.Search in Google Scholar
Xiao, X. Y.; Wei, Y. Q.; Zheng, W. X.; Wu, K. C. Organic-inorganic hybrid lanthanide-silver heterometallic coordination frameworks constructed from oxalate and sulfate anion: syntheses, structures, and photoluminescent properties. Z. Anorg. Allg. Chem. 2011, 637, 741–747.Search in Google Scholar
Yan, C.; Li, K.; Wei, S. C.; Wang, H. P.; Fu, L.; Pan, M.; Su, C. Y. Lanthanide homometallic and d-f heterometallic MOFs from the same tripodal ligand: structural comparison, one photon (OP) vs. two photon (TP) luminescence and selective guest adsorption behavior. J. Mater. Chem. 2012, 22, 9846–9852.Search in Google Scholar
Yoon, M.; Srirambalaji, R.; Kim, K. Homochiral metal organic frameworks for asymmetric heterogeneous catalysis. Chem. Rev. 2012, 112, 1196–1231.Search in Google Scholar
Zeng, R. H.; Peng, G.; Qiu, Y. C.; Zheng, S. R.; Li, W. S.; Zhang, W. X.; Deng, H.; Cai, Y. P. Synthesis, crystal structures and properties of Ln(III)-Cu(I)-Na(I) and Ln(III)-Ag(I) heterometallic coordination polymers. CrystEngComm 2011, 13, 3910–3919.Search in Google Scholar
Zhang, Z. J.; Shi, W.; Huang, Y. Q.; Zhao, B.; Cheng, P.; Liao, D. Z.; Yan, S. P. The self-assembly of a heteronuclear complex monitored with ESI-MS and fluorescence spectrophotometry. CrystEngComm 2009, 11, 1811–1814.Search in Google Scholar
Zhao, B.; Chen, X. Y.; Wang, W. Z.; Cheng, P.; Ding, B.; Liao, D. Z.; Yan, S. P.; Jiang, Z. H. {[GdAg2(dtpa)(H2O)]·3H2O}n: the first 2D Gd-Ag coordination polymer with Ag-Ag interaction. Inorg. Chem. Commun. 2005, 8, 178–181.Search in Google Scholar
Zhao, B.; Zhao, X. Q.; Chen, Z.; Shi, W.; Cheng, P.; Yan, S. P.; Liao, D. Z. Structures and near-infrared luminescence of unique 4d-4f heterometal-organic frameworks (HMOF). CrystEngComm 2008, 10, 1144–1146.Search in Google Scholar
Zhao, X. Q.; Zhao, B.; Shi, W.; Cheng, P. Synthesis, structures, and luminescent and magnetic properties of Ln-Ag heterometal-organic frameworks. Inorg. Chem. 2009a, 48, 11048–11057.Search in Google Scholar
Zhao, X. Q.; Zhao, B.; Shi, W.; Cheng. P. Structures and luminescent properties of a series of Ln-Ag heterometallic coordination polymers. CrystEngComm 2009b, 11, 1261–1269.10.1039/b900430kSearch in Google Scholar
Zhou, X. P.; Xu, Z. T.; Zeller, M.; Hunter, A. D.; Chui, S. S. Y.; Che, C. M.; Lin, J. H. Reactions of H2S with AgCl within a porous coordination network. Inorg. Chem. 2010, 49, 7629–7631.Search in Google Scholar
Zou, J. P.; Chen, M. H.; Luo, S. L.; Tang, X. H.; Xiong, Z. Q.; Peng, Q. Two heterometal-organic coordination polymers with chelidamic acid: syntheses, structures andoptical properties. Inorg. Chim. Acta 2011, 373, 243–248.Search in Google Scholar
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