Abstract
Searching for natural materials exhibiting larger electron-electron interactions constitutes a traditional approach to high-temperature superconductivity research. Very recently, we pointed out that the newly developed field of electromagnetic metamaterials deals with the somewhat related task of dielectric response engineering on a sub-100-nm scale. Considerable enhancement of the electron-electron interaction may be expected in such metamaterial scenarios as in epsilon near-zero (ENZ) and hyperbolic metamaterials. In both cases, dielectric function may become small and negative in substantial portions of the relevant four-momentum space, leading to enhancement of the electron pairing interaction. This approach has been verified in experiments with aluminum-based metamaterials. Metamaterial superconductor with Tc=3.9 K have been fabricated, which is three times that of pure aluminum (Tc=1.2 K), which opens up new possibilities to improve the Tc of other simple superconductors considerably. Taking advantage of the demonstrated success of this approach, the critical temperature of hypothetical niobium, MgB2- and H2S-based metamaterial superconductors is evaluated. The MgB2-based metamaterial superconductors are projected to reach the liquid nitrogen temperature range. In the case of an H2S-based metamaterial, the projected Tc appears to reach ~250 K.
1 Introduction
One of the most important goals of condensed matter physics is reliably designing new materials with enhanced superconducting properties. Recently, an electromagnetic metamaterial strategy, consisting of deliberately engineering the dielectric properties of a nanostructured “metamaterial superconductor” that results in an enhanced electron pairing interaction that increases the value of the superconducting energy gap and the critical temperature, Tc, was suggested to achieve this goal [1], [2]. Our recent experimental work [3], [4], [5] has conclusively demonstrated that this approach can indeed be used to increase the critical temperature of a composite superconductor-dielectric metamaterial. For example, we have demonstrated the use of Al2O3-coated aluminum nanoparticles to form epsilon near-zero (ENZ) core-shell metamaterial superconductors with a Tc that is three times that of pure aluminum [4]. This deep and non-trivial connection between the fields of electromagnetic metamaterials and superconductivity research stems from the fact that superconducting properties of a material, such as electron-electron pairing interaction, the superconducting critical temperature Tc, etc. may be expressed via the effective dielectric response function εeff(q, ω) of the material [6]. For example, considerable enhancement of attractive electron-electron interaction may be expected in such actively studied metamaterial scenarios as ENZ [7] and hyperbolic metamaterials [8], since in both cases, εeff(q, ω) may become small and negative in substantial portions or the four-momentum (q, ω) space. Such an effective dielectric response-based macroscopic electrodynamics description is valid if the material may be considered as a homogeneous medium on the spatial scales below the superconducting coherence length. Since this length (the size of the Cooper pair) equals ~100 nm in a typical BCS superconductor, the metamaterial unit size must fall within the window between the ~0.3-nm (given by the atomic scale) and the ~100-nm scale of a typical Cooper pair for the metamaterial approach to remain valid.
The metamaterial superconductor approach takes advantage of the recent progress in plasmonics [9] and electromagnetic metamaterials [10] to engineer an artificial medium or “metamaterial”, so that its effective dielectric response function εeff(q, ω) conforms to almost any desired behavior. It appears natural to use this newly found freedom to engineer and maximize the electron pairing interaction in such an artificial superconductor via engineering its dielectric response function εeff(q, ω). In this article, we will review the comparative advantages and shortcomings of various electromagnetic metamaterial strategies to achieve this goal. For example, the ENZ approach based on the plasmonic core-shell nanostructures [4] seems to be the most efficient way to achieve the highest Tc values. However, the core-shell metamaterial superconductor geometry exhibits poorer transport properties compared to its parent (aluminum) superconductor. A natural way to overcome this issue is the implementation of the layered hyperbolic metamaterial geometry, which is based on parallel periodic layers of metal separated by layers of dielectric. This geometry ensures excellent transport properties in the plane of the layers. As noted in [11], typical high-Tc superconductors (such as BSCCO) exhibit hyperbolic behavior in a substantial portion of the far infrared and terahertz frequency ranges. Indeed, it was demonstrated that the artificial hyperbolic metamaterial geometry may also lead to a considerable enhancement of superconducting properties [5].
We should also mention that very recently, other approaches to artificial metamaterial superconductor engineering have been proposed by several groups, such as suggestions to create better superconductors by phonon spectrum modification via periodic nanostructuring of thin film [12] and bulk [13] superconductors. It was also proposed to modify natural hyperbolic superconductors (such as HgBa2CuO4+y) via inhomogeneous charge density waves (CDWs) [14]. Together with our electromagnetic metamaterial approach these strategies open up new areas in superconductivity research at the unconventional intersection of nanophotonics and solid-state physics, which may potentially reach the scientific dream of achieving room temperature superconductivity [15].
2 Macroscopic electrodynamic description of superconductivity
Electromagnetic properties are known to play a very important role in the pairing mechanism of superconductors [6]. According to the BCS theory, a Cooper pair is formed from two electrons with opposite spins and momenta that are loosely bound. This mechanism may be described as an attractive interaction of electrons that results from the polarization of the ionic lattice which these electrons create as they move through the lattice. Based on this interpretation, Kirzhnits et al. [6] formulated their description of superconductivity in terms of the dielectric response function of the superconductor. They demonstrated that the electron-electron interaction in a superconductor may be expressed in the form of an effective Coulomb potential,
where VC is the Fourier-transformed Coulomb potential in vacuum and εeff(q, ω) is the linear dielectric response function of the superconductor treated as an effective medium. While the thermodynamic stability condition implies that εeff(0, 0)>0, the dielectric response function at higher frequencies and momenta may become large and negative, which accounts for the weak net attraction and pairing of electrons in the superconducting condensate. Based on this approach, Kirzhnits et al. derived explicit expressions for the superconducting gap Δ and critical temperature, Tc, of the superconducting transition as a function of the dielectric response function, and demonstrated that their expressions agree with the BCS result.
The key observation made in Refs. [1], [2] was that the “homogeneous medium” approximation may remain valid even if the basic structural elements of the material are not simple atoms or molecules. It was suggested that artificial “metamaterials” may be created from much bigger building blocks, and the electromagnetic properties of these fundamental building blocks may be engineered in such a way that the attractive pairing interaction described by Eq. (1) is maximized. The two potential solutions described in [1], [2] require minimization of εeff(q, ω) within a substantial portion of the relevant four-momentum spectrum
where εxx=εyy=ε1 and εzz=ε2 have opposite signs. As a result, the effective Coulomb interaction of two electrons may become attractive and very strong along spatial directions where
which indicates that the superconducting order parameter must be strongly anisotropic. This situation resembles the hyperbolic character of such high-Tc superconductors as BSCCO [11]. However, engineering such ENZ or hyperbolic metamaterials constitutes a much more challenging task compared to typical applications of superconducting metamaterials suggested so far [16], which only deal with metamaterial engineering on scales which are much smaller than the microwave or RF wavelengths. Since the superconducting coherence length (the size of the Cooper pair) is ξ~100 nm in a typical BCS superconductor [17], the metamaterial unit size must fall within the window between ~0.3 nm (given by the atomic scale) and ξ~100-nm scale of a typical Cooper pair. Moreover, the coherence length of the metamaterial superconductor must be determined in a self-consistent manner. The coherence length will decrease with increasing Tc of the metamaterial superconductor since the approach of Kirzhnits et al. gives rise to the same BCS-like relationship between the superconducting gap Δ and the coherence length ξ [17]:
where VF is the Fermi velocity. Therefore, the metamaterial structural parameter (such as the interlayer or interparticle distance, etc.), which must remain smaller than the coherence length, defines the limit of critical temperature enhancement. Demonstration of the superconductivity enhancement in electromagnetic metamaterials opens up numerous new possisbilities for metamaterial enhancement of Tc in such practically important simple superconductors as niobium and MgB2.
3 Epsilon near-zero superconductors: theory and experiment
Let us demonstrate that tuning electron-electron interaction is indeed possible using the epsilon-near-zero (ENZ) metamaterial approach, which is based on intermixing metal and dielectric components in the right proportions. Following [18], a simplified dielectric response function of a metal may be written as
where ωp is the plasma frequency, k is the inverse Thomas-Fermi radius, Ωn(q) are dispersion laws of various phonon modes, and Γn are the corresponding damping rates. Zeroes of the dielectric response function of the bulk metal (which correspond to various bosonic modes) maximize electron-electron pairing interaction given by Eq. (1). In the discussion below we will limit our consideration to the behavior of εm(q, ω) near ω=Ω1(q) in the vicinity of the Fermi surface, so that a more complicated representation of εm(q, ω) by the Lindhard function, which accurately represents εm(q, ω) in the q→0 and ω→0 limit [18], does not need to be used. We are going to use only the fact that εm changes sign near ω=Ω1(q) by passing through zero. Expression for εm(q, ω) given by Eq. (5) does exhibit this behavior.
As summarized in [19], the critical temperature of a superconductor in the weak coupling limit is typically calculated as
where θ is the characteristic temperature for a bosonic mode mediating electron pairing (such as the Debye temperature θD in the standard BCS theory, or θex=ħωex/k or θpl=ħωpl/k in the theoretical proposals which suggest excitonic or plasmonic mediation of the electron pairing interaction), and λeff is the dimensionless coupling constant defined by V(q, ω)=VC(q) ε−1(q, ω) and the density of states ν (see for example [20]):
where VC is the unscreened Coulomb repulsion and the angle brackets denote average over the Fermi surface.
Compared to the bulk metal, zeroes of the effective dielectric response function εeff(q, ω) of the metal-dielectric metamaterial are observed at shifted positions compared to the zeroes of εm(q, ω) [2], and additional zeros may also appear. According to the Maxwell-Garnett approximation [21], mixing of nanoparticles of a superconducting “matrix” with dielectric “inclusions” (described by the dielectric constants εm and εd, respectively) results in the effective medium with a dielectric constant εeff, which may be obtained as
where n is the volume fraction of metal (0≤n≤1). The explicit expression for εeff may be written as
and it is easy to verify that
For a given value of the metal volume fraction n, the ENZ conditions (εeff ≈ 0) may be obtained around εm ≈ 0 and around
Since the absolute value of εm is limited by some value εm,max [see Eq. (5)], the latter zero of εeff disappears at small n as n→0 at some critical value of the volume fraction n=ncr=1.5εd/εm,max. Let us evaluate Im(ε−1eff(q, ω)) near this zero of εeff at n>ncr. Based on Eq. (10),
where
where λm is also determined by Eq. (7) in the limit ε→εm, and we have assumed the same magnitudes of
Therefore, near this pole
Let us apply the obtained simple estimates to the case of Al-Al2O3 core-shell metamaterial studied in [4]. Assuming the known values Tcbulk=1.2 K and θD=428 K of bulk aluminum [8], Eq. (6) results in λm=0.17, which corresponds to the weak coupling limit. In order to make the mechanism behind the enhancement of Tc in the Al-Al2O3 core-shell metamaterial superconductor abundantly clear, we have plotted the hypothetical values of Tc as a function of metal volume fraction n, which would originate from either Eq. (13) or Eq. (15) in the absence of each other. The corresponding values calculated as
are shown in Figure 1B. The vertical dashed line corresponds to the assumed value of ncr.
The experimentally measured data points from Ref. [4] are shown for comparison on the same plot. The match between the experimentally measured values of enhanced Tc and the theoretical curve obtained based on Eq. (13) is quite impressive, given the fact that Eqs. (13) and (16) do not contain any free parameters. Such a good match unambiguously identifies metamaterial enhancement as the physical mechanism of critical temperature tripling in the Al-Al2O3 core-shell metamaterial superconductor. It is impressive that such simple and well-known nanophotonics tools as the effective medium theory may be used to considerably enhance the critical temperature of simple superconductors.
The proof of principle experiments conducted with both random [3] and core-shell [4] ENZ metal-dielectric metamaterials indeed validates the effective medium-based theory outlined above. Our initial superconducting metamaterial samples [3] were prepared using commercially available tin and barium titanate nanoparticles obtained from the US Research Nanomaterials, Inc. The nominal diameter of the BaTiO3 nanoparticles was 50 nm, while tin nanoparticle size was specified as 60–80 nm. Both nanoparticle sizes fall substantially below the superconducting coherence length in pure tin ξSn~230 nm [17]. Our choice of materials was based on results of numerical calculations of the real part of the dielectric constant of the Sn/BaTiO3 mixture shown in Figure 2. These calculations were based on the measured dielectric properties of Sn [22] and BaTiO3 [23], respectively, and on the Maxwell-Garnett expression, Eq. (9), for the dielectric permittivity of the mixture. These calculations indicated that it was possible to achieve broadband ENZ conditions in the 30–50% range of the volume fraction of BaTiO3 in the frequency range of relevance around hν~kTc of pure tin.
The Sn/BaTiO3 superconducting metamaterials were fabricated by combining the given amounts of Sn and BaTiO3 nanoparticle powders by volume into a single test tube filled with de-ionized water. The resulting suspensions were sonicated and magnetically stirred for 30 min, followed by water evaporation. The remaining mixtures of Sn and BaTiO3 nanoparticles were compressed into test pellets using a hydraulic press. A typical scanning electron microscopy (SEM) image of the resulting Sn/BaTiO3 composite metamaterial is shown in Figure 3. The original compressed nanoparticles are clearly visible in the image. The resulting average metamaterial composition has been verified after fabrication using an SEM with energy-dispersive X-ray spectroscopy (EDS). The compositional analysis of an area of the samples of about 1 μm in diameter is consistent with this nominal composition. Such EDX spectra were used to establish the homogeneous character of the fabricated composite metamaterials.
The superconducting critical temperature Tc of various Sn/BaTiO3 metamaterials was measured via the onset of diamagnetism for samples with different volume fractions of BaTiO3 using a MPMS SQUID magnetometer. The zero-field-cooled (ZFC) magnetization per unit mass for several samples with varying concentrations of BaTiO3 is plotted in Figure 4A. The temperatures of the onset of the superconducting transition and the temperatures of the midpoint of the transition are plotted in Figure 5. The Tc increased from the pure Sn value of 3.68 K with increasing BaTiO3 concentration to a maximum ΔTc~0.15 K or 4% compared to the pure tin sample for the 40% sample followed by Tc decreasing at higher volume fractions. A pure tin sample was prepared from pressed tin nanoparticles of the same diameter using the same method of preparation. The value of Tc agreed with expected value of pure Sn. The magnetization of the composite samples in the superconducting state is comparable in magnitude with the pure tin sample. The increase of Tc and its dependence on effective dielectric constant determined by the concentration of BaTiO3 agrees qualitatively with the Maxwell-Garnett theory-based calculations described above (see Figure 2). Moreover, the decrease in Tc at higher volume fraction of BaTiO3, which is apparent from Figure 5 also agrees well with the Maxwell-Garnett theory, since εeff(q, ω) changes sign to positive for higher BaTiO3 concentrations.
To verify the reproducibility of these results, our measurements were repeated for several sets of nanocomposite samples fabricated using strontium titanate nanoparticles (instead of barium titanate) using the same fabrication technique described above. The superconducting critical temperature Tc of the Sn/SrTiO3 metamaterial samples was measured for samples with different volume fractions of SrTiO3 nanoparticles as shown in Figure 4B producing volume fraction dependencies, which are similar to those obtained for Sn/BaTiO3 samples. These results established that the metamaterial approach to dielectric response engineering can indeed increase the critical temperature of a composite superconductor-dielectric metamaterial. However, despite this initial success, the observed critical temperature increase was modest. It was argued in [2] that the random nanoparticle mixture geometry may not be ideal because simple mixing of superconductor and dielectric nanoparticles results in substantial spatial variations of εeff(q, ω) throughout a metamaterial sample. Such variations lead to considerable broadening and suppression of the superconducting transition.
To overcome this issue, it was suggested that an ENZ plasmonic core-shell metamaterial geometry, which has been developed to achieve partial cloaking of macroscopic objects [24], should be implemented [2]. The cloaking effect relies on mutual cancellation of scattering by the dielectric core (having εd>0) and plasmonic shell (with εm<0) of the nanoparticle, so that the effective dielectric constant of the nanoparticle becomes very small and close to that of vacuum (a plasmonic core with a dielectric shell may also be used). This approach may be naturally extended to the core-shell nanoparticles having negative ENZ behavior, as required in the superconducting application. Synthesis of such individual ENZ core-shell nanostructures followed by nanoparticle self-assembly into a bulk ENZ metamaterial (as shown in Figure 6) appears to be a viable way to fabricate an extremely homogeneous metamaterial superconductor.
The design of an individual core-shell nanoparticle is based on the fact that scattering of an electromagnetic field by a sub-wavelength object is dominated by its electric dipolar contribution, which is defined by the integral sum of its volume polarization [24]. A material with ε>1 has a positive electric polarizability, while a material with ε<1 has a negative electric polarizability (since the local electric polarization vector, P=(ε−1)E/4π, is opposite to E). As a result, the presence of a plasmonic shell (core) cancels the scattering produced by the dielectric core (shell), thus providing a cloaking effect. Similar consideration for the negative ENZ case leads to the following condition for the core-shell geometry:
where rc and rs are the radii, and εc and εs are the dielectric permittivities of the core and shell, respectively. Eq. (17) corresponds to the average dielectric permittivity of the core-shell nanoparticle being approximately equal to zero. Working on the negative side of this equality will ensure negative ENZ character of each core-shell nanoparticle. A dense assembly of such core-shell nanoparticles will form a medium that will have small negative dielectric permittivity. Moreover, in addition to obvious advantage in homogeneity, a core-shell based metamaterial superconductor design enables tuning of the spatial dispersion of the effective dielectric permittivity εeff(q, ω) of the metamaterial, which would further enhance its Tc [2]. Spatial dispersion of a metamaterial is indeed well known to originate from plasmonic effects in its metallic constituents. In a periodic core-shell nanoparticle-based ENZ metamaterial spatial dispersion is defined by the coupling of plasmonic modes of its individual nanoparticles. This coupling enables propagating plasmonic Bloch modes and hence nonlocal effects.
The successful realization of such an ENZ core-shell metamaterial superconductor using compressed Al2O3-coated aluminum nanoparticles has been reported in [4], leading to tripling of the metamaterial critical temperature compared to the bulk aluminum. This material is ideal for the proof of principle experiments because the critical temperature of aluminum is quite low (Tc Al=1.2 K [17]), leading to a very large superconducting coherence length ξ=1600 nm [17]. Such a large value of ξ facilitates the metamaterial fabrication requirements while Al2O3 exhibits very large positive values of dielectric permittivity up to
The 18-nm-diameter Al nanoparticles for these experiments were acquired from the US Research Nanomaterials, Inc. Upon exposure to the ambient conditions, a ~2-nm-thick Al2O3 shell is known to form on the aluminum nanoparticle surface [28], which is comparable to the 9-nm radius of the original Al nanoparticle. Further aluminum oxidation may also be achieved by heating the nanoparticles in air. The resulting core-shell Al2O3-Al nanoparticles were compressed into macroscopic, ~1-cm diameter, ~0.5-mm-thick test pellets using a hydraulic press, as illustrated in the inset in Figure 6.
The IR reflectivity of such core-shell metamaterial samples was measured in the long-wavelength IR (LWIR) (2.5–22.5 μm) range using an FTIR spectrometer, and compared with reflectivity spectra of Al and Al2O3, as shown in Figure 7. While the reflectivity spectrum of Al is almost flat, the spectrum of Al2O3 exhibits a very sharp step-like behavior around 11 μm that is related to the phonon-polariton resonance, which results from coupling of an infrared photon with an optic phonon of Al2O3 [29]. The step in reflectivity is due to the negative sign of
The Kramers-Kronig analysis of the FTIR reflectivity spectra of the Al-Al2O3 sample also allows us to evaluate εeff(0, ω) for the metamaterial in the LWIR spectral range. Plots of the real part of ε for pure Al and for the Al-Al2O3 core-shell metamaterial based on the Kramers-Kronig analysis of the data in Figure 7 are plotted in Figure 8. The plot in Figure 8A clearly demonstrates that
The Tc of various Al-Al2O3 core-shell metamaterials was determined via the onset of diamagnetism for samples with different degrees of oxidation using a MPMS SQUID magnetometer. The ZFC magnetization per unit mass versus temperature for several samples with various volume fractions of Al2O3 is plotted in Figure 10A, whereas the corresponding reflectivity data are shown in Figure 10B. Even though the lowest achievable temperature with our MPMS SQUID magnetometer was 1.7 K, we were able to observe a gradual increase of Tc that correlated with an increase of the Al2O3 volume fraction as determined by the drop in reflectivity shown in Figure 10B. The reliability of the MPMS SQUID magnetometer at T>1.7 K was checked by measurements of the Tc of bulk tin at Tc=3.7 K, as described in Ref. [3], in excellent agreement with the textbook data [17].
The observed increase in Tc also showed good correlation with the results of the Kramers-Kronig analysis shown in Figure 8B: samples exhibiting smaller negative ε demonstrated higher Tc increase. The highest onset temperature of the superconducting transition reached 3.9 K, which is more than three times as high as the critical temperature of bulk aluminum, Tc Al=1.2 K [17]. All of the samples exhibited a small positive susceptibility that increased with decreasing temperature, consistent with the presence of small amounts of paramagnetic impurities. The discussed Tc values were determined by the beginning of the downturn of M(T), where the diamagnetic superconducting contribution starts to overcome paramagnetic contribution, making this temperature the lower limit of the onset of superconductivity. Further oxidation of aluminum nanoparticles by annealing for 2 h at 600°C resulted in a Tc less than 1.7 K, our lowest achievable temperature. Based on the reflectivity step near 11 μm (see Figure 10B), the volume fraction of Al2O3 in this sample may be estimated as ~50%, which corresponds to (rs–rc)~0.26rc. For rc~9 nm, the corresponding thickness of Al2O3 was (rs–rc)~2.4 nm.
Thus, the theoretical prediction of a large increase of Tc in ENZ core-shell metamaterials shown in Figure 1 has been confirmed by direct measurements of εeff(0, ω) of the fabricated metamaterials and the corresponding measurements of the increase of Tc. These results strongly suggest that increased aluminum Tc’s that were previously observed in very thin (<50-nm thickness) granular aluminum films [26], [27] and disappeared at larger film thicknesses were due to changes in the dielectric response function rather than quantum size effects and soft surface phonon modes [27]. As clearly demonstrated by the experimental data and the discussion above, the individual Al nanoparticle size is practically unaffected by oxidation, thus excluding the size effects as an explanation of giant Tc increase in our bulk core-shell metamaterial samples. The developed technology enables efficient nanofabrication of bulk aluminum-based metamaterial superconductors with a Tc that is three times that of pure aluminum and with virtually unlimited shapes and dimensions. These results open up numerous new possibilities of considerable Tc increase in other simple superconductors.
4 Hyperbolic metamaterial superconductors: theory and experiment
While the Tc increase observed in ENZ metamaterial superconductors is impressive, the core-shell metamaterial superconductor geometry exhibits poor transport properties compared to its parent (aluminum) superconductor. A natural way to overcome this issue is the implementation of the hyperbolic metamaterial geometry (Figure 11A), which has been suggested in [1], [2]. Hyperbolic metamaterials are extremely anisotropic uniaxial materials, which behave like a metal (Reεxx=Reεyy<0) in one direction and like a dielectric (Reεzz>0) in the orthogonal direction. Originally introduced to overcome the diffraction limit of optical imaging [8], hyperbolic metamaterials demonstrate a number of novel phenomena resulting from the broadband singular behavior of their density of photonic states. The “layered” hyperbolic metamaterial geometry shown in Figure 11A is based on parallel periodic layers of metal separated by layers of dielectric. This geometry ensures excellent transport properties in the plane of the layers. Let us demonstrate that the artificial hyperbolic metamaterial geometry may also lead to a considerable enhancement of superconducting properties.
The first successful realization of an artificial hyperbolic metamaterial superconductor has been reported in [5]. The metamaterial was made of aluminum films separated by thin layers of Al2O3. This combination of materials is ideal for the proof of principle experiments because it is easy to controllably grow Al2O3 on the surface of Al, and because the critical temperature of aluminum is quite low (Tc Al=1.2 K [17]), leading to a very large superconducting coherence length ξ=1600 nm [17]. Such a large value of ξ facilitates the metamaterial fabrication requirements since the validity of macroscopic electrodynamic description of the metamaterial superconductor requires that its spatial structural parameters must be much smaller than ξ. It appears that the Al/Al2O3 hyperbolic metamaterial geometry is capable of superconductivity enhancement, which is similar to that observed for a core-shell metamaterial geometry [4], while having much better transport and magnetic properties compared to the core-shell superconductors. The multilayer Al/Al2O3 hyperbolic metamaterial samples for these experiments (Figure 12) were prepared using sequential thermal evaporation of thin aluminum films followed by oxidation of the top layer for 1 h in air at room temperature. The first layer of aluminum was evaporated onto a glass slide surface. Upon exposure to ambient conditions a ~2-nm-thick Al2O3 layer is known to form on the aluminum film surface [28]. Further aluminum oxidation may also be achieved by heating the sample in air. The oxidized aluminum film surface was used as a substrate for the next aluminum layer. This iterative process was used to fabricate thick multilayer (up to 16 metamaterial layers) Al/Al2O3 hyperbolic metamaterial samples. A transmission electron microscopy (TEM) image of the multilayer metamaterial sample is shown in Figure 12. During TEM experiments samples were coated with gold and platinum to ensure conductivity of the surface during sample preparation. A focused ion beam (FIB) microscope was used to prepare a sample for transmission electron microscopy (TEM). Samples were analyzed using a JEOL 2200 FS TEM, acquiring bright-field and high-resolution images. Figure 12 shows an image from the hyperbolic stack, showing polycrystalline Al grains, with 1- to 2-nm-thick amorphous Al2O3 spacing layers, corresponding with the designed structure. Some Al2O3 layers are difficult to discern due to slight sample warping from the preparation process. The inset shows that the interfacial layers are indeed amorphous, between polycrystalline grains of Al, which, in cross-section, exhibit Moire cross-hatching.
To demonstrate that these multilayer samples exhibit hyperbolic behavior, we studied their transport and optical properties (Figures 13–15
). The temperature dependence of the sheet resistance of a 16-layer 10-nm/layer Al/Al2O3 hyperbolic metamaterial and a 100-nm-thick Al film are shown in Figure 13A. As illustrated in the logarithmic plot in the inset, the electronic conductivity of the metamaterial approaches conductivity values of bulk aluminum (indicated by the arrow) and is far removed from the parameter space characteristic for granular Al films [27], which is indicated by the gray area in the inset. These results were corroborated by measurements of IR reflectivity of these samples, shown in Figure 13B. The IR reflectivity of the hyperbolic metamaterial samples was measured in the long wavelength IR (LWIR) (2.5–22.5 μm) range using an FTIR spectrometer, and compared with reflectivity spectra of Al and Al2O3. While the reflectivity spectrum of bulk Al is almost flat, the spectrum of Al2O3 exhibits a very sharp step-like behavior around 11 μm that is related to the phonon-polariton resonance, which results from coupling of an infrared photon with an optical phonon of Al2O3 [29]. The step in reflectivity is due to the negative sign of
The Kramers-Kronig analysis of the FTIR reflectivity spectra of Al and Al2O3 measured in [4] also allowed us to calculate the ε1 and ε2 components of the Al/Al2O3 layered films in the LWIR spectral range using the Maxwell-Garnett approximation as follows:
where n is the volume fraction of metal, and εm and εd are the dielectric permittivities of the metal and dielectric, respectively [31]. Results of these calculations for a multilayer metamaterial consisting of 13-nm-thick Al layers separated by 2 nm of Al2O3 are shown in Figure 14. The metamaterial appears to be hyperbolic except for a narrow LWIR spectral band between 11 and 18 μm. A good match between the Maxwell-Garnett approximation [Eqs. (18) and (19)] and the measured optical properties of the metamaterial is demonstrated by ellipsometry (Figure 15A) and polarization reflectometry (Figure 15B) of the samples.
Variable angle spectroscopic ellipsometry with photon energies between 0.6 and 6.5 eV on the Al/Al2O3 metamaterial have been performed using a Woollam variable angle spectroscopic ellipsometer (W-VASE). For a uniaxial material with optic axis perpendicular to the sample surface and in plane of incidence, ellipsometry provides the pseudo-dielectric function which, in general, depends both on ε1 and ε2. However, as demonstrated by Jellison and Baba [32], the pseudo-dielectric function in this measurement geometry is dominated by the in-plane dielectric function ε1 and is independent of the angle of incidence. The measured results for the real and imaginary parts of the pseudo-dielectric function in Figure 15A show good agreement with the model for the in-plane dielectric function [Eq. (18)]. The calculated data points are based on the real and imaginary parts of εAl tabulated in [30]. The measured sign of the real part of the pseudo-dielectric function is negative, which suggests metallic in-plane transport. The sign of the real part of ε2 (and therefore, the hyperbolic character of our samples) was determined by polarization reflectometry, since ellipsometry data are less sensitive to ε2 [32]. Polarization reflectometry also confirmed the negative sign of the real part of ε1 consistent with ellipsometry data. The metamaterial parameters were extracted from the polarization reflectometry data as described in detail in [33]. Reflectivity for s-polarization is given in terms of the incident angle θ by
where
Reflectivity for p-polarization is given as
where
We measured the p- and s-polarized absolute reflectance on the metamaterial sample using the reflectance mode of the ellipsometer. The reflectance was measured at two photon energies, 2.07 (600 nm) and 2.88 eV (430 nm), as shown in Figure 15B, and was normalized to the measured reflectance of a 150-nm gold film. The absolute reflectance of the gold film was obtained from ellipsometry measurements. The estimated uncertainty in the absolute reflectance of the Al/Al2O3 metamaterial is one percent. In order to obtain the dielectric permittivity ε1 and ε2 values, we fit the s-polarized reflectance first and get the in-plane dielectric function ε1. We then use the in-plane dielectric function to fit the p-polarized reflectance to obtain the out-of-plane dielectric function, ε2. The data analysis was done using W-VASE software. At 2.07 eV (600 nm), ε1=−7.17+1.86i and ε2=1.56+0.21i, and at 2.88 eV (430 nm), ε1=−2.15+0.50i and ε2=1.30+0.09i. It is clear that the real part of the out-of-plane dielectric function is positive while the real part of the in-plane dielectric function is negative, which confirms the dielectric nature along z-axis and metallic nature in the xy-plane, i.e. a hyperbolic metamaterial.
The Tc and critical magnetic field, Hc, of various samples (Figures 16 and 17 ) were determined via four-point resistivity measurements as a function of temperature and magnetic field, H, using a Physical Property Measurement System (PPMS) by Quantum Design. Even though the lowest achievable temperature with our PPMS system was 1.75 K, which is higher than the critical temperature Tc Al=1.2 K of bulk aluminum, we were able to observe a pronounced effect of the number of layers on Tc of the hyperbolic metamaterial samples. Figure 16A shows measured resistivity as a function of temperature for the 1-, 3- and 8-layer samples each having the same 8.5-nm layer thickness. While the superconducting transition in the 1-layer sample was below 1.75 K and could not be observed, the 3- and 8-layer metamaterial samples exhibited progressively higher critical temperature, which strongly indicates the role of hyperbolic geometry in Tc enhancement. A similar set of measurements performed for several samples having 13-nm layer thickness is shown in Figure 16B.
The measurements of Hc in parallel and perpendicular fields are shown in Figure 17. Figure 17A shows measured resistivity as a function of temperature for a 16-layer 13.2 nm layer thickness hyperbolic metamaterial sample. The critical temperature of this sample appears to be Tc=2.3 K, which is about two times higher than the Tc of bulk aluminum (another transition at Tc=2.0 K probably arise from one or two decoupled layers or edge shadowing effects where the thickness of the films is not uniform). The inset in Figure 17A illustrates the measurements of
Measurements of the perpendicular critical field
Assuming
We have also studied changes in Tc as a function of Al layer thickness in a set of several 8-layer Al/Al2O3 metamaterial samples, as shown in Figure 18A. The quantitative behavior of Tc as a function of n may be predicted based on the hyperbolic enhancement of the electron-electron interaction [Eq. (2)] and the density of electronic states, ν, on the Fermi surface which experience this hyperbolic enhancement. Using Eqs. (18) and (19), the effective Coulomb potential from Eq. (2) may be rewritten as
Let us assume once again (see Ref. [15] and the theoretical discussion in the previous section) that the dielectric response function of the metal used to fabricate the hyperbolic metamaterial shown in Figure 11 may be described by Eq. (5), and the critical temperature of a metamaterial superconductor may be found using Eq. (6) via the density of states in Eq. (7).
Let us consider the region of four-momentum (q, ω) space, where ω>Ω1(q). While εm=0 at ω=Ω1(q), εm(q, ω) is large in a good metal and negative just above Ω1(q). Based on Eq. (25), the differential of the product νV may be written as
where x=cosθ, and θ varies from 0 to π. The latter expression has two poles at
As the volume fraction, n, of metal is varied, one of these poles remains close to εm=0, while the other is observed at larger negative values of εm:
This situation is similar to calculations of Tc for ENZ metamaterials. Since the absolute value of εm is limited [see Eq. (5)], the second pole disappears near n=0 and near n=1. Due to the complicated angular dependence in Eq. (27), it is convenient to reverse the order of integration in Eq. (7) and perform the integration over dω first, followed by angular averaging. Following the commonly accepted approach, while integrating over dω we take into account only the contributions from the poles given by Eq. (27), and assume the value of
Near n=0 and n=1, these expression may be approximated as
and
respectively. Note that at the ω=Ω1(q) zero of the dielectric response function of the bulk metal the effective Coulomb potential inside the metal may be approximated as
so that the coupling constant λeff of the hyperbolic metamaterial obtained by angular integration of the sum of Eqs. (31) and (32) may be expressed via the coupling constant λm of the bulk metal:
where α is a constant of the order of 1 and x0 is defined by the maximum negative value of εm, which determines if the second pole [Eq. (29)] exists at a given n. Based on Eq. (29),
If the second pole does not exist, then x0=0 may be assumed. Based on Eq. (6), the theoretically predicted value of Tc for the hyperbolic metamaterial is calculated as
assuming the known values Tcbulk=1.2 K and λm=0.17 for bulk aluminum [15]. The predicted behavior of Tc as a function of n is plotted in Figure 18B. This figure demonstrates that the experimentally measured behavior of Tc as a function of n (which is defined by the Al layer thickness) correlates well with the theoretical fit, which was obtained using Eq. (36) based on the hyperbolic mechanism of Tc enhancement.
The observed combination of transport and critical properties of the Al/Al2O3 hyperbolic metamaterials is very far removed from the parameter space typical of the granular aluminum films [27], [34]. Together with the number of layer and layer thickness dependence of Tc and Hc shown in Figures 16–18, these observations strongly support the hyperbolic metamaterial mechanism of superconductivity enhancement. The developed technology enables efficient nanofabrication of thick film aluminum-based hyperbolic metamaterial superconductors with a Tc that is two times that of pure aluminum and with excellent transport and magnetic properties. While the observed Tc increase is slightly smaller than the one observed in ENZ metamaterials [4], the hyperbolic metamaterial geometry exhibits superior transport and magnetic properties compared to the ENZ core-shell metamaterial superconductors. In addition, our theoretical model is applicable to previous experiments performed in NbN/AlN [35] and Al/Si [36] multilayer geometries. We should also note that unlike recent pioneering work on quantum metamaterials [37], which are based on superconducting split-ring resonators and quantum circuits, our work aims at engineering of metamaterials with enhanced superconducting properties.
5 What next? How to further increase critical temperature in a metamaterial superconductor
While theoretical plots in Figure 1B unambiguously identify the physical mechanism of Tc enhancement in the Al-Al2O3 core-shell metamaterial superconductor, it must be understood that a complete theory should take into account simultaneous contributions of both poles of Eq. (10) to λeff of the metamaterial. It is also clear that according to Eq. (5) the metamaterial pole occurs at a slightly different frequency compared to the εm ≈ 0 pole, and therefore it must have slightly different value of
let us assume that near ω=Ω1(q) Eq. (5) may be approximated as
where Em is a positive constant. Based on Eq. (11), the corresponding frequency of the “metamaterial” pole is
which is slightly higher than Ω1, and therefore, a slightly larger value of
where
which now has a single fitting parameter α. We will consider it as a free parameter of the model, since we are not aware of any experimental measurements of dispersion of Imεm for aluminum. Note that Eq. (41) depends on εd only via ncr and α. The calculated behavior of Tc as a function of n is presented in Figure 19A. The agreement appears to be very good. The best fit to experimental metamaterial data is obtained at α=0.89. We must emphasize that this model is quite insensitive to the particular choice of functional form of εm(q, ω) in the broad (q, ω) range. In our derivations, we are only using the fact that εm changes sign near ω=Ω1(q) by passing through zero, which is described by Eq. (38).
The apparent success of such a simple theoretical description in the case of Al-Al2O3 core-shell and hyperbolic metamaterial superconductors prompted us to apply the same theory to the tin-based ENZ metamaterials studied in [3]. Assuming the known values Tcbulk=3.7 K and θD=200 K of bulk tin [17], [18], Eq. (6) results in λm=0.25, which also corresponds to the weak coupling limit. The calculated behavior of Tc as a function of n is presented in Figure 19B, which also shows experimental data points measured in [3]. The agreement also appears to be very good, given the spatial inhomogeneity of the fabricated metamaterials [3] (note also the difference in temperature scales in Figure 19A and B). The best fit to experimental metamaterial data is obtained at α=0.83. It appears that a smaller increase in metamaterial Tc in this case is due to larger value of permittivity εd of the dielectric component of the metamaterial, which according to Eq. (11) limits the range ncr<n<0.6 where the metamaterial Tc enhancement may occur. Larger value of εd also leads to smaller value of α [see Eq. (39)], which also reduces the metamaterial pole contribution to λeff.
We should also note that the appearance of an additional “metamaterial” pole in the Maxwell-Garnett expression [Eq. (9)] for a metal-dielectric mixture does not rely on any particular spatial scale, as long as it is smaller than the coherence length. In fact, the Maxwell-Garnett approximation may be considered as a particular case of the Clausius-Mossotti relation [21], which traces the dielectric constant of a mixture to the dielectric constants of its constituents, and it is only sensitive to the volume fractions of the constituents. Therefore, the same concept is supposed to be applicable at much smaller spatial scales compared to the two metamaterial cases studied in Refs. [3] and [4]. We anticipate that similar Tc enhancements may be observed in metamaterials based on other higher temperature superconductors, which have smaller coherence length, such as niobium and MgB2.
First, let us consider the case of niobium, which has Tcbulk=9.2 K and θD=275 K in the bulk form [17], [18]. Enhancing the superconducting properties of niobium is a very important task, since niobium alloys, such as Nb3Sn and NbTi are widely used in superconducting cables and magnets. Based on Eq. (6), niobium has λm=0.29, which also corresponds to the weak coupling limit. The coherence length of niobium is ξ=38 nm [17], [18], which would complicate nanofabrication requirements for a niobium-based metamaterial. However, given the current state of nanolithography, which operates on a 14 nm node [38], these requirements still look quite realistic. Alternatively, smaller than 38-nm-diameter nanoparticles would need to be used in nanoparticle-based ENZ metamaterial geometries.
The calculated behavior of Tc of a niobium-based ENZ metamaterial as a function of n is presented in Figure 20A for different values of the α ratio in Eq. (41). The vertical dashed line in the plot corresponds to the same value of ncr as in the Al-Al2O3 core-shell metamaterial superconductor. It is interesting to note that the general range of predicted Tc enhancement matches well with the observed enhancement of Tc in various niobium alloys [17]. The corresponding experimental data point for Nb3Sn is shown in the same plot for comparison (it is assumed that n=0.75 for Nb3Sn). As we have mentioned above, our model is based on the Maxwell-Garnett approximation, which traces the dielectric constant of a mixture to the dielectric constants of its constituents. The spatial scale of mixing is not important within the scope of this model. Therefore, our model may be applicable to some alloys. We should note that the additional “metamaterial” pole described by Eq. (11) may also be present in the case of a mixture of a normal metal with the superconductor. However, unlike the previously considered case of a dielectric mixed with a superconductor, the additional “metamaterial” pole is observed at ω<Ω1, where the dielectric constant of the superconductor εs is positive [see Eq. (38)], while the dielectric constant of the normal metal εm is negative (it is assumed that the critical temperature of the normal metal is lower than the critical temperature of the superconductor). Indeed, under these conditions, an additional pole in the inverse effective dielectric response function of the metamaterial does appear in [Eq. (10)], and similar to Eq. (11), it is defined as
This pole will result in the enhanced Tc of the metamaterial (or alloy), which may be calculated using the same Eq. (41). However, since this additional pole occurs at ω<Ω1, it is expected that Imεs will be smaller at this frequency, resulting in factor α being slightly larger than one. This conclusion agrees well with the position of Nb3Sn data point on Figure 20A.
Next, let us consider the case of MgB2, which has Tcbulk=39 K and θD=920 K in the bulk form [39]. The coherence length of MgB2 remains relatively large: the π and σ bands of electrons have been found to have two different coherence lengths, 51 and 13 nm [40]. Both values are large enough to allow metamaterial fabrication, at least in principle. Based on Eq. (6), MgB2 has λm=0.32, which still remains within the scope of the weak coupling limit. The calculated behavior of Tc of a MgB2-based ENZ metamaterial as a function of n is presented in Figure 4B for different values of the α ratio in Eq. (41). Similar to Figure 20A, the vertical dashed line in the plot corresponds to the same value of ncr as in the Al-Al2O3 core-shell metamaterial superconductor. It appears that the critical temperature of MgB2-based ENZ metamaterial would probably fall in the liquid nitrogen temperature range. A good choice of the dielectric component of such a metamaterial could be diamond: 5-nm-diameter diamond nanoparticles are available commercially, see for example Ref. [3].
Unfortunately, superconductors having progressively higher Tc are not well described by Eq. (6), which is valid in the weak coupling limit only. Thus, it is interesting to evaluate what kind of metamaterial enhancement may be expected in such system as H2S, which superconducts at 203 K at very high pressure [41]. While simple theoretical description developed in our work may not be directly applicable to this case as far as Tc calculations are concerned (because of the very large values of θD~1200 K and λ~2 in this material [42]), adding a suitable dielectric or normal metal to H2S will still result in an additional “metamaterial” pole in its inverse dielectric response function. Eqs. (8–12) will remain perfectly applicable in this case. Therefore, adding such a pole will enhance superconducting properties of H2S. Based on Eq. (10), we may predict that the enhancement of superconducting properties will be observed at n~0.6, as it also happened in the cases of aluminum and tin-based metamaterials considered in this paper. As far as the choice of a dielectric is concerned, based on Eqs. (8–12), it appears that readily available nanoparticles of diamond (off the shelf 5-nm-diameter diamond nanoparticles were used in [3]) could be quite suitable, since diamond has rather low dielectric constant εdia~5.6, which stays almost constant from the visible to RF frequency range. Low permittivity of the dielectric component ensures smaller value of ncr defined by Eq. (11), and hence larger metamaterial enhancement. It is not inconceivable that 5-nm-diameter diamond nanoparticles could be added to H2S in the experimental chamber used in [41].
Unfortunately, in the strong coupling limit, the expected Tc enhancement may not be as drastic as in the weak coupling limit described by Eq. (6). In the λ>>1 limit of the Eliashberg theory, the critical temperature of the superconductor may be obtained as [43]
Therefore, enhancement of λ by the largest possible factor of 1.5 calculated based on the Maxwell-Garnett theory for the effective dielectric response function of the metamaterial (see Figure 1A) will lead to Tc enhancement by factor of (1.5)1/2, which means that a critical temperature range ~250 K (or ~−20°C) may potentially be achieved in a H2S-based metamaterial superconductor. Such a development would still be of sufficient interest, since this would constitute an almost room temperature superconductivity.
Considerable increase of Tc of the metamaterial superconductors may also be achieved by optimizing the metamaterial geometry. Historically, the suggestion to use highly polarizable dielectric side chains or layers in order to increase Tc of a 1D or 2D electronic system can be traced back to the pioneering papers by Little [44] and Ginzburg [45]. Using modern language, the superconducting systems proposed in these works could be called “superconducting metamaterials”. While these proposals never led to hypothesized room temperature superconductivity, experimental attempts to realize such superconductors were limited by modest polarizability of natural materials. Recent development of high-ε metamaterials gives these proposals another chance [2]. An example of the high-index metamaterial, which may be used in the modern day versions of either 1D or 2D superconducting geometries proposed by Little and Ginzburg is shown in Figure 21 [2].
In another recent development, fractal metamaterial superconductor geometry has been suggested and analyzed based on the theoretical description of critical temperature increase in ENZ metamaterial superconductors [46]. Considerable enhancement of critical temperature has been predicted in such fractal metamaterials due to appearance of large number of additional poles in the inverse dielectric response function of the fractal. Indeed, relatively large value of the superconducting coherence length ξ=1600 nm of bulk aluminum [17] leaves a lot of room for engineering an aluminum-based fractal metamaterial superconductor according to the procedure shown schematically in Figure 22A.
Let us consider the central image (the second fractal order) from Figure 22A. We may use the Maxwell-Garnett approximation [Eq. (8)] in order to determine the effective dielectric permittivity of such metamaterial. However, this time, we will assume that the “first-order metamaterial” described by Eq. (9) plays the role of the “matrix”. The volume fraction of the new matrix is n, and it is diluted with the same dielectric εd with volume fraction (1−n). Mixing of these components results in the effective medium with a dielectric constant
It is easy to verify that in addition to the pole at εm ≈ 0 and the first-order pole described by Eq. (11), the inverse dielectric response function of the “second order” fractal metamaterial has additional poles at
These additional poles may be expressed in the recurrent form as
The latter equation, which expresses
The vertical dashed line in Figure 22B corresponds to the critical value of the metal volume fraction ncr observed in the case of the Al-Al2O3 core-shell superconductor [3]. As indicated in Figure 22B, this value may be used as a guideline to evaluate how many additional poles may be observed in a real fractal metamaterial at a given volume fraction n. The additional poles of the inverse dielectric response function of the fractal metamaterial defined by Eq. (47) may be described as the plasmon-phonon modes of the metamaterial, which participate in the Cooper pairing of electrons in a fashion, which is quite similar to the conventional BCS mechanism.
Let us evaluate what kind of critical temperature increase may be expected in a fractal metamaterial superconductor because of the appearance of all these additional poles in ε−1eff(q, ω). We already have demonstrated that the additional poles of the inverse dielectric response function may be found using an iterative procedure. A similar iterative expression may be derived for Imε−1eff(q, ω) near these poles. Based on Eq. (10), we may write the following expression for the imaginary part of the inverse dielectric response function of the first-order material near the metamaterial pole:
where
assuming that the metamaterial structure contains K fractal orders. The resulting λeff is plotted in Figure 23 for the first four fractal orders. The corresponding
Our results agree with the recent observations [47], [48] that fractal defect structure promotes superconductivity. In particular, it was observed that the microstructures of the transition-metal oxides, including high-Tc copper oxide superconductors, are complex. For example, the oxygen interstitials or vacancies (which strongly influence the dielectric properties of the bulk high-Tc superconductors [49]) exhibit fractal order [47]. These oxygen interstitials are located in the spacer layers separating the superconducting CuO2 planes. They undergo fractal ordering phenomena that induce enhancements in the transition temperatures with no changes in the overall hole concentrations. Such ordering of oxygen interstitials in the La2O2+y spacer layers of La2CuO4+y high-Tc superconductors is characterized by a fractal distribution up to a maximum limiting size of 400 mm. It was observed [47], quite intriguingly, that these fractal distributions of dopants seem to enhance superconductivity at high temperature, which is difficult to explain since the superconducting coherence length in these compounds is very small ξ~1–2 nm [47], [48]. Appearance of the plasmon-phonon modes of the fractal structure described above may resolve this issue, since such fractal phonon modes reside on a scale, which is much larger than several nanometers. We should also mention that such a mechanism may also explain observations of increased critical temperatures in fractal Pb thin films [50].
6 Conclusion
Unlike the traditional searches of higher Tc superconductors, which rely on choosing natural materials exhibiting larger electron-electron interactions, the metamaterial superconductor paradigm offers considerably extended range of search scenarios. The newly developed electromagnetic metamaterials offer the field of superconductivity research many novel tools, which enable intelligent engineering of electron pairing interaction. Considerable enhancement of the electron-electron interaction may be expected in such metamaterial scenarios as in ENZ and hyperbolic metamaterials, as well as in novel fractal metamaterial geometries. In all these cases, the dielectric function may become small and negative in substantial portions of the relevant four-momentum space, leading to enhancement of the electron pairing interaction. This approach has been verified in experiments with tin- and aluminum-based metamaterials. Aluminum-based metamaterial superconductor with Tc=3.9 K have been fabricated, that is three times that of pure aluminum (Tc=1.2 K), which opens up new possibilities to considerably improve Tc of other simple superconductors. Experimental results obtained so far in various ENZ and hyperbolic metamaterial superconductor systems are summarized in Table 1.
Composition | Tc (K) | Reference | |
---|---|---|---|
Bulk | Metamaterial | ||
ENZ | |||
Sn/BaTiO3 | 3.68 | 3.83 | [3] |
Sn/SrTiO3 | 3.68 | 3.80 | [3] |
Al/Al2O3 | 1.2 | 3.9 | [4] |
Hyperbolic | |||
Al/Al2O3 | 1.2 | 2.4 | [5] |
Sn/CaF2 | 3.68 | 3.92 | To be published |
Sn/MgF2 | 3.68 | 3.87 | To be published |
Taking advantage of the demonstrated success of this approach, the critical temperature of hypothetical niobium, MgB2- and H2S-based metamaterial superconductors has been evaluated. The MgB2-based metamaterial superconductors are projected to reach the liquid nitrogen temperature range. In the case of an H2S-based metamaterial, the projected Tc appears to be as high as ~250 K, which almost reaches the room temperature range. We hope that our brief review clearly demonstrates that the future of metamaterial superconductors is bright, and we anticipate many novel exciting scientific and technical applications of these materials.
Acknowledgment
This work was supported in part by DARPA (Award no. W911NF-17-1-0348 “Metamaterial Superconductors”).
References
[1] Smolyaninov II, Smolyaninova VN. Is there a metamaterial route to high temperature superconductivity? Adv Cond Matt Phys 2014;2014:479635.10.1364/CLEO_QELS.2014.FTu1C.2Search in Google Scholar
[2] Smolyaninov II, Smolyaninova VN. Metamaterial superconductors. Phys Rev B 2015;91:094501.10.1103/PhysRevB.91.094501Search in Google Scholar
[3] Smolyaninov II, Smolyaninova VN. Experimental demonstration of superconducting critical temperature increase in electromagnetic metamaterials. Sci Rep 2014;4:7321.10.1038/srep07321Search in Google Scholar PubMed PubMed Central
[4] Smolyaninova VN, Zander K, Gresock T, et al. Using metamaterial nanoengineering to triple the superconducting critical temperature of bulk aluminum. Sci Rep 2015;5:15777.10.1038/srep15777Search in Google Scholar PubMed PubMed Central
[5] Smolyaninova VN, Jensen C, Zimmerman W, et al. Enhanced superconductivity in aluminum-based hyperbolic metamaterials. Sci Rep 2016;6:34140.10.1038/srep34140Search in Google Scholar PubMed PubMed Central
[6] Kirzhnits DA, Maksimov EG, Khomskii DI. The description of superconductivity in terms of dielectric response function. J Low Temp Phys 1973;10:79–83.10.1007/BF00655243Search in Google Scholar
[7] Engheta N. Pursuing near-zero response. Science 2013;340:286–7.10.1126/science.1235589Search in Google Scholar PubMed
[8] Jakob Z, Alekseyev LV, Narimanov E. Optical hyperlens: far-field imaging beyond the diffraction limit. Opt Express 2006;14:8247–56.10.1364/OE.14.008247Search in Google Scholar PubMed
[9] Zayats AV, Smolyaninov II, Maradudin A. Nano-optics of surface plasmon-polaritons. Phys Rep 2005;408:131–314.10.1016/j.physrep.2004.11.001Search in Google Scholar
[10] Pendry JB, Schurig D, Smith DR. Controlling electromagnetic fields. Science 2006;312:1780–2.10.1126/science.1125907Search in Google Scholar PubMed
[11] Smolyaninov II. Quantum topological transition in hyperbolic metamaterials based on high Tc superconductors. J Phys Condens Matter 2014;26:305701.10.1088/0953-8984/26/30/305701Search in Google Scholar PubMed
[12] Allan MP, Fischer MH, Ostojic O, Andringa A. Creating better superconductors by periodic nanopatterning. SciPost Phys 2017;3:010.10.21468/SciPostPhys.3.2.010Search in Google Scholar
[13] Tao S, Li Y, Chen G, Zhao X. Critical temperature of smart meta-superconducting MgB2. J Supercond Nov Magn 2017;30:1405–11.10.1007/s10948-016-3963-7Search in Google Scholar
[14] Campi C, Bianconi A. High temperature superconductivity in a hyperbolic geometry of complex matter from nanoscale to mesoscopic scale. J Supercond Nov Magn 2016;29:627–31.10.1007/s10948-015-3326-9Search in Google Scholar
[15] Smolyaninov II, Smolyaninova VN. Theoretical modeling of critical temperature increase in metamaterial superconductors. Phys Rev B 2016;93:184510.10.1103/PhysRevB.93.184510Search in Google Scholar
[16] Anlage SM. The physics and applications of superconducting metamaterials. J Opt 2011;13:024001.10.1088/2040-8978/13/2/024001Search in Google Scholar
[17] Kittel C. Introduction to solid state physics. New York, Wiley, 2004.Search in Google Scholar
[18] Ashcroft NW, Mermin ND. Solid state physics. New York, Saunders, 1976.Search in Google Scholar
[19] Ginzburg VL. Nobel Lecture: on superconductivity and superfluidity. Rev Mod Phys 2004;76:981–98.10.1103/RevModPhys.76.981Search in Google Scholar
[20] Pashitskii EA. Plasmon mechanism of high temperature superconductivity in cuprate metal-oxide compounds. J Exp Theor Phys 1993;76:425–44.Search in Google Scholar
[21] Choy TC. Effective medium theory. Oxford, Clarendon Press, 1999.Search in Google Scholar
[22] Lindquist RE, Ewald AW. Optical constants of single-crystal gray tin in the infrared. Phys Rev 1964;135:A191–4.10.1103/PhysRev.135.A191Search in Google Scholar
[23] McNeal MP, Jang S-J, Newnham RE. The effect of grain and particle size on the microwave properties of barium titanate. J Appl Phys 1998;83:3288–97.10.1063/1.367097Search in Google Scholar
[24] Alù A, Engheta N. Achieving transparency with plasmonic and metamaterial coatings. Phys Rev E 2005;72:016623.10.1103/PhysRevE.72.016623Search in Google Scholar PubMed
[25] Rajab KZ, Naftaly M, Linfield EH, et al. Broadband dielectric characterization of aluminum oxide. J Micro Elect Pack 2008;5:101–6.10.4071/1551-4897-5.1.1Search in Google Scholar
[26] Shalnikov A. Superconducting thin films. Nature 1938; 142:74.10.1038/142074a0Search in Google Scholar
[27] Cohen RW, Abeles B. Superconductivity in granular aluminum films. Phys Rev 1968;168:444–50.10.1103/PhysRev.168.444Search in Google Scholar
[28] Shih T-S, Liu Z-B. Thermally-formed oxide on aluminum and magnesium. Mater Trans 2006;47:1347–53.10.2320/matertrans.47.1347Search in Google Scholar
[29] Mills DL, Burstein E. Polaritons: the electromagnetic modes of media. Rep Prog Phys 1974;37:817.10.1088/0034-4885/37/7/001Search in Google Scholar
[30] Ordal MA, Long LL, Bell RJ, et al. Optical properties of the metals Al, Co, Cu, Au, Fe, Pb, Ni, Pd, Pt, Ag, Ti, and W in the infrared and far infrared. Appl Opt 1983;22:1099–119.10.1364/AO.22.001099Search in Google Scholar PubMed
[31] Wangberg R, Elser J, Narimanov EE, Podolskiy VA. Nonmagnetic nanocomposites for optical and infrared negative-refractive-index media. J Opt Soc Am B 2006;23:498–505.10.1364/JOSAB.23.000498Search in Google Scholar
[32] Jellison GE, Baba JC. Pseudodielectric functions of uniaxial materials in certain symmetry directions. J Opt Soc Am A 2006;23:468–75.10.1364/JOSAA.23.000468Search in Google Scholar
[33] Tumkur T, Barnakov Y, Kee ST, Noginov MA, Liberman V. Permittivity evaluation of multilayered hyperbolic metamaterials: ellipsometry vs. reflectometry. J Appl Phys 2015;117:103–4.10.1063/1.4914524Search in Google Scholar
[34] Prestigiacomo JC, Liu TJ, Adams PW. Asymmetric avalanches in the condensate of a Zeeman-limited superconductor. Phys Rev B 2014;90:184519.10.1103/PhysRevB.90.184519Search in Google Scholar
[35] Barber ZH, Blamire MG. Niobium nitride/aluminium nitride superconductor/insulator multilayers and tunnel junctions. IEEE Trans Appl Supercond 1997;7:3609–12.10.1109/77.622186Search in Google Scholar
[36] Tarasov MA, Kuzmin LS, Kaurova NS. Thin multilayer aluminum structures for superconducting devices. Instrum Exp Tech 2009;52:877–81.10.1134/S0020441209060220Search in Google Scholar
[37] Macha P, Oelsner G, Reiner J-M, et al. Implementation of a quantum metamaterial using superconducting qubits. Nat Commun 2014;5:5146.10.1038/ncomms6146Search in Google Scholar PubMed
[38] Vaidyanathan K, Ng SH, Morris D, et al. Design and manufacturability tradeoffs in unidirectional and bidirectional standard cell layouts in 14 nm node. Proc SPIE 2012;8327:83270K.10.1117/12.916104Search in Google Scholar
[39] Buzea C, Yamashita T. Review of superconducting properties of MgB2. Supercond Sci Technol 2001;14:11.10.1088/0953-2048/14/11/201Search in Google Scholar
[40] Moshchalkov V, Menghini M, Nishio T, et al. Type-1.5 superconductivity. Phys Rev Lett 2009;102:117001.10.1103/PhysRevLett.102.117001Search in Google Scholar PubMed
[41] Drozdov AP, Eremets MI, Troyan IA, Ksenofontov V, Shylin SI. Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system. Nature 2015;525:73–6.10.1038/nature14964Search in Google Scholar PubMed
[42] Bernstein N, Hellberg CS, Johannes MD, Mazin II, Mehl MJ. What superconducts in sulfur hydrides under pressure, and why. Phys Rev B 2015;91:060511.10.1103/PhysRevB.91.060511Search in Google Scholar
[43] Ummarino G. Eliashberg theory. In: Pavarini E, Koch E, Schollwöck U, eds. Emergent phenomena in correlated matter. Verlag Jülich, Forschungszentrum Jülich, 2013, p.13.13.Search in Google Scholar
[44] Little W. Possibility of synthesizing an organic superconductor. Phys Rev 1964;134:A1416.10.1103/PhysRev.134.A1416Search in Google Scholar
[45] Ginzburg VL. On surface superconductivity. Phys Lett 1964;13:101–2.10.1016/0031-9163(64)90672-9Search in Google Scholar
[46] Smolyaninov II, Smolyaninova VN. Enhancement of critical temperature in fractal metamaterial superconductors. Physica C 2017;535:20–3.10.1016/j.physc.2017.03.002Search in Google Scholar
[47] Fratini M, Poccia N, Ricci A, et al. Scale-free structural organization of oxygen interstitials in La2CuO4+y. Nature 2010;466:841–4.10.1038/nature09260Search in Google Scholar PubMed
[48] Zaanen J. High-temperature superconductivity: the benefit of fractal dirt. Nature 2010;466:825–7.10.1038/466825aSearch in Google Scholar PubMed
[49] Basov DN, Timusk T. Electrodynamics of high-Tc superconductors. Rev Mod Phys 2005;77:721.10.1103/RevModPhys.77.721Search in Google Scholar
[50] Wang J, Ma X-C, Qi Y, Fu Y-S, Ji S-H, Lu L. Negative magnetoresistance in fractal Pb thin films on Si. Appl Phys Lett 2007;90:113109.10.1063/1.2712511Search in Google Scholar
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