Skip to content
Licensed Unlicensed Requires Authentication Published by De Gruyter March 26, 2021

Development of activated carbon from sawdust by pyrolysis and methylene blue adsorption

  • Alexander Asanja Jock EMAIL logo , Atuman Samaila Joel , Olu Olumide Olubajo , Charity Uren Zang , Magdelene Sazeya Ayuba and Philip Thomas Wakili

Abstract

In this study, activated carbon was developed from saw-dust by pyrolysis. The activated carbon was characterized for elemental composition, morphology and surface chemistry. The potential of the prepared activated carbon for the removal of methylene blue (MB) from aqueous solution was investigated. Batch adsorption experiments were conducted to evaluate the adsorption isotherm, kinetic and thermodynamic of MB onto saw-dust activated carbon. The MB removal efficiency was 99.2% and the Lamgmuir isothermal model having correlation coefficient (R2) of 0.98 gave the best fit. The kinetics of MB adsorption onto activated carbon was described with the pseudo second order model indicates the dominance of chemisorption mechanism. Thermodynamic parameters showed that the adsorption of MB on saw dust activated carbon adsorbent was endothermic in nature and a non-spontaneous process. The activation energy of 34.7 kJ/mol further reveals that the adsorption process was chemisorption. Generally, the results suggest that the saw-dust activated carbon is a viable adsorbent for effective removal of MB from wastewater effluent contaminated with dye.


Corresponding author: Alexander Asanja Jock, Department of Chemical and Petroleum Engineering, University of Uyo, PMB 1017, Uyo, Nigeria, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The author(s) declared no conflicts of interest with respect to the research, authorship, and/or publication of this article.

References

Adesina, O. A., A. O. Elvis, D. S. N. Mohallem, and J. S. Olusegun. 2019. “Adsorption of Methylene Blue and Congo Red from Aqueous Solution Using Synthesized Alumina–Zirconia Composite.” Environmental Technology 42 (7): 1–12, doi:https://doi.org/10.1080/09593330.2019.1652696.Search in Google Scholar

Adewoye, L. T., S. I. Mustapha, A. G. Adeniyi, J. O. Tijani, M. A. Amoloye, and L. J. Ayinde. 2017. “Optimization of Nickel (II) and Chromium (III) Removal from Contaminated Water Using Sorghum Bicolor.” Nigerian Journal of Technology 36 (3): 960–72. https://doi.org/10.4314/njt.v36i3.41.Search in Google Scholar

Alandis, M. N., W. Mekhamer, O. Aldayel, A. A. J. Hefne, and M. Alam. 2019. “Adsorptive Applications of Montmorillonite Clay for the Removal of Ag(I) and Cu(II) from Aqueous Medium.” Journal of Chemistry 2019: 1–7, doi:https://doi.org/10.1155/2019/7129014.Search in Google Scholar

Alene, N. A., Y. G. Abate, and T. A. Habte. 2020. “Bio Adsorption of Basic Blue Dye from Aqueous Solution onto Raw and Modified Waste Ash as Economical Alternative Bioadsorbent.” Journal of Chemistry: 1–11. https://doi.org/10.1155/2020/8746035.Search in Google Scholar

Aljlil, A. S., and D. F. Alsewailem. 2014. “Adsorption of Cu & Ni on Bentonite Clayfrom Waste Water.” Athens Journal of Sciences 1 (1): 21–30. https://doi.org/10.30958/ajs.1-1-2.Search in Google Scholar

Amin, T. M., A. A. Alazba, and M. Shafiq. 2017. “Nonspontaneous and Multilayer Adsorption of Malachite Green Dye by Acacia nilotica Waste with Dominance of Physisorption.” Water Science Technology 76 (7): 1805–15. https://doi.org/10.2166/wst.2017.366.Search in Google Scholar

Atef, S. A. 2015. “Adsorption Behavior of Methyl Orange onto Wheat Bran: Role of Surface and pH.” Oriental Journal of Chemistry 31 (2): 643–51.10.13005/ojc/310205Search in Google Scholar

Es-sahbany, H., M. Berradi, S. Nkhili, R. Hsissou, M. Allaoui, M. M. Belfaquir, and S. M. El Youbi. 2019. “Removal of Heavy Metals (Nickel) Contained in Wastewater-Models by the Adsorption Technique on Natural Clay.” Materials Today: Proceedings 13: 866–75. https://doi.org/10.1016/j.matpr.2019.04.050.Search in Google Scholar

Gorzin, F., and B. R. M. M. Abadi. 2018. “Adsorption of Cr(VI) from Aqueous Solution by Adsorbent Prepared Frompaper Mill Sludge: Kinetics and Thermodynamics Studies.” Adsorption Science & Technology 36 (1–2): 149–69, https://doi.org/10.1177/0263617416686976.Search in Google Scholar

Imam, S. A., and M. Abdullahi. 2017. “Adsorptive Removal of Methylene Blue Using Groundnut Shell Activated Carbon Coated with Fe2O3.” Journal of Applied Chemistry 10 (4): 12–21, https://doi.org/10.9790/5736-1004011221.Search in Google Scholar

Ingrachen-Brahmi, D., H. Belkacemi, and A. B. L. Mahtout. 2020. “Adsorption of Methylene Blue Onsilica Gel Derived from Algerian Siliceous By-Product of Kaolin.” Journal of Materials and Environmental Science 11 (7): 1044–57.Search in Google Scholar

Jawad, H. A., R. Razuan, N. Appaturi, and D. L. Wilson. 2019. “Adsorption and Mechanism Study for Methylene Blue Dye Removal with Carbonized Watermelon (Citrullus lanatus) Rind Prepared via One-step Liquid Phase H2SO4 Activation.” Surfaces and Interfaces 16: 76–84. https://doi.org/10.1016/j.surfin.2019.04.012.Search in Google Scholar

Jock, A. A., A. A. Z. Muhammad, S. Abdulsalam, U. A. El-Nafaty, and U. O. Aroke. 2016. “Physicochemical Characteristics of Surface Modified Dijah–Monkin Bentonite.” Particulate Science and Technology 36 (3): 1–12.10.1080/02726351.2016.1245689Search in Google Scholar

Kanawade, M. S., and W. R. Gaikwad. 2011. “Removal of Methylene Blue from Effluent by Using Activated Carbon and Water Hyacinth as Adsorbent.” International Journal of Chemical Engineering and Applications 2 (5): 317–9, https://doi.org/10.7763/IJCEA.2011.V2.126.Search in Google Scholar

Khan, I. M. 2020. “Adsorption of Methylene Blue onto Natural Saudi Red Clay: Isotherms, Kinetics and Thermodynamic Studies.” Materials Research Express 7: 1–14. https://doi.org/10.1088/2053-1591/ab903c.Search in Google Scholar

Khodaie, M., N. Ghasemi, B. Moradi, and M. Rahimi. 2013. “Removal of Methylene Blue from Wastewater by Adsorption onto ZnCl2 Activated Corn Husk Carbon Equilibrium Studies.” Journal of Chemistry 2013: 1–6, doi:https://doi.org/10.1155/2013/383985.Search in Google Scholar

Kuang, Y., X. Zhang, and S. Zhou. 2020. “Adsorption of Methylene Blue in Water onto Activated Carbon by Surfactant Modification.” Water 12 (587): 1–19, https://doi.org/10.3390/w12020587.Search in Google Scholar

Kumar, S. P., S. Sivaprakash, and N. Jayakumar. 2017. “Removal of Methylene Blue Dye from Aqueous Solutions Using Lagerstroemia Indica Seed (LIS) Activated Carbon.” International Journal of Materials Sciences 12 (1): 107–16.Search in Google Scholar

Lee, Z. L., and M. A. A. Zaini. 2020. “One-step ZnCl2/FeCl3 Composites Preparation of Magnetic Activated Carbon for Effective Adsorption of Rhodamine B Dye.” Toxin Reviews 1–19, doi:https://doi.org/10.1080/15569543.2020.1837172.Search in Google Scholar

Linh, H. X., T. N. Thu, Q. T. Toan, T. D. Huong, T. B. Giang, P. K. H. Ha, T. H. Nguyen, N. T. K. Chung, K. T. Nguyen, and T. N. Hai. 2019. “Fast and Effective Route for Removing Methylene Blue from Aqueous Solution by Using Red Mud Activated Graphite Composites.” Journal of Chemistry 2019: 1–8, doi:https://doi.org/10.1155/2019/2858170.Search in Google Scholar

Liu, Y., J. Jia, T. Geo, X. Wang, D. Yu, and F. Li. 2020. “Rapid, Selective Adsorption of Methylene Blue from Aqueous Solution by Durable Nanofibrous Membranes.” Journal of Chemical Engineering 65 (8): 3998–4008. https://doi.org/10.1021/acs.jced.0c00318.Search in Google Scholar

Makhado, E., S. Pandey, D. K. Modibane, M. Kang, and J. M. Hato. 2020. “Sequestration of Methylene Blue Dye Using Sodium Alginate Poly(Acrylicacid)@ZnO Hydrogel Nanocomposite: Kinetic, Isotherm, and Thermodynamic Investigations.” International Journal of Biological Macromolecules 162: 60–73. https://doi.org/10.1016/j.ijbiomac.2020.06.143.Search in Google Scholar

Neolaka, A. B. Y., B. S. E. Kalla, A. G. Malelak, K. N. Rukman, G. Supriyanto, and N. T. N. Puspaningsih. 2018. “Adsorption of Methylene Blue Using Acid Activated Green Color Natural Zeolite from Ende-Flores, Indonesia.” Rasayan Journal of Chemistry 11 (2): 494–504. https://doi.org/10.31788/RJC.2018.1121994.Search in Google Scholar

Oribayo, O., O. O. Olaleye, A. S. Akinyanju, K. O. Omoloja, and S. O. Williams. 2020. “Coconut Shell-Based Activated Carbon as Adsorbent for the Removal of Dye from Aqueous Solution: Equilibrium, Kinetics, and Thermodynamic Studies.” Nigerian Journal of Technology 39 (4): 1076–84. https://doi.org/10.4314/njt.v39i4.14.Search in Google Scholar

Pandey, S. 2017. “A Comprehensive Review on Recent Developments in Bentonite-Based materials Used as Adsorbents for Wastewater Treatment.” Journal of Molecular Liquids 241: 1091–113. https://doi.org/10.1016/j.molliq.2017.06.115.Search in Google Scholar

Pandey, S., and B. S. Mishra. 2011. “Sol–gel Derived Organic–Inorganic Hybrid Materials: Synthesis, Characterizations and Applications.” Journal of Sol-Gel Science and Technology 59: 73–94, https://doi.org/10.1007/s10971-011-2465-0.Search in Google Scholar

Pandey, S., and J. Ramontja. 2016a. “Turning to Nanotechnology for Water Pollution Control: Applications of Nanocomposites.” Focus Sciences 2 (3): 1–10. https://doi.org/10.21859/focsci-020455.Search in Google Scholar

Pandey, S., and J. Ramontja. 2016b. “Natural Bentonite Clay and its Composites for Dye Removal: Current State and Future Potential.” American Journal of Chemistry and Applications 3 (2): 8–19.Search in Google Scholar

Pandey, S., and S. Tiwari. 2015. “Facile Approach to Synthesize Chitosan Based Composite Characterization and Cadmium (II) Ion Adsorption Studies.” Carbohydrate Polymers 134: 646–56. https://doi.org/10.1016/j.carbpol.2015.08.027.Search in Google Scholar

Pandey, S., E. Fosso-Kankeu, J. M. Spiro, F. Waander, N. Kumar, S. S. Ray, J. Kim, and M. Kang. 2020b. “Equilibrium, Kinetic, and Thermodynamic Studies of Lead Ion Adsorption from Mine Wastewater onto MoS2-Clinoptilolite Composites.” Materials Today Chemistry 18: 1–11. https://doi.org/10.1016/j.mtchem.2020.100376.Search in Google Scholar

Pandey, S., Y. J. Do, J. Kim, and M. Kang. 2020a. “Fast and Highly Efficient Removal of Dye from Aqueous Solution Using Natural Locust Bean Gum Based Hydrogels as Adsorbent.” International Journal of Biological Macromolecules 143: 60–75. https://doi.org/10.1016/j.ijbiomac.2019.12.002.Search in Google Scholar

Pathania, D., S. Sharma, and P. Singh. 2013. “Removal of Methylene Blue by Adsorption Ontoactivated Carbon Developed from Ficus caricabast.” Arabian Journal of Chemistry 10 (1): S144–1451. https://doi.org/10.1016/j.arabjc.2013.04.021.Search in Google Scholar

Saleem, J., U. B. Shahid, M. Hijab, H. Mackey, and G. McKay. 2019. “Production and Applications of Activated Carbons as Adsorbents from Olive Stones.” Biomass Conversion and Biorefinery 9: 775–802. https://doi.org/10.1007/s13399-019-00473-7.Search in Google Scholar

Siddiqui, F., Y. M. Soliman, W. House, and A. Ibragimov. 2016. “Pre-Darcy Flow Revisited Under Experimental Investigation.” Journal of Analytical Science and Technology 7 (2): 1–9, https://doi.org/10.1186/s40543-015-0081-2.Search in Google Scholar

Soucy, J., A. Koubaa, S. Migneault, and B. Riedl. 2016. “Chemical Composition and Surface Properties of Paper Mill Sludge and their Impact on High Density Polyethylene (HDPE) Composites.” Journal of Wood Chemistry and Technology 36 (2): 77–93. https://doi.org/10.1080/02773813.2015.1057647.Search in Google Scholar

Staron, P., J. Chwastowski, and M. Banach. 2019. “Sorption Behavior of Methylene Blue from Aqueous Solution by Raphia Fibers.” International Journal of Environmental Science and Technology 16: 8449–60. https://doi.org/10.1007/s13762-019-02446-9.Search in Google Scholar

Sun, D., Z. Zhang, M. Wang, and Y. Wu. 2013. “Adsorption of Reactive Dyes on Activated Carbon Developed from Enteromorpha prolifera.” American Journal of Analytical Chemistry 4: 17–26. https://doi.org/10.4236/ajac.2013.47a003.Search in Google Scholar

Tahir, H., M. Sultan, and Z. Qadir. 2013. “Physiochemical Modification and Characterization of Bentonite Clay and its Application for the Removal of Reactive Dyes.” International Journal of Chemistry 5 (3): 1–14, https://doi.org/10.5539/ijc.v5n3p19.Search in Google Scholar

Tang, S. H., and M. A. A. Zaini. 2020. “Microporous Activated Carbon Prepared from Yarn Processing Sludgevia Composite Chemical Activation for Excellent Adsorptive Removal of Malachite Green.” Surfaces and Interfaces 22: 1–20, doi:https://doi.org/10.1016/j.surfin.2020.100832.Search in Google Scholar

Zaini, A. A. M., and M. R. Sudi. 2017. “Valorization of Human Hair as Methylene Blue Dye Adsorbents.” Green Processing and Synthesis 7: 344–52. https://doi.org/10.1515/gps-2017-0021.Search in Google Scholar

Received: 2020-12-12
Accepted: 2021-03-13
Published Online: 2021-03-26

© 2021 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 27.4.2024 from https://www.degruyter.com/document/doi/10.1515/ijcre-2020-0239/html
Scroll to top button