Abstract
The mesoporous Ni20/Al-KIT-6 (denoted as N20AxK) catalysts with different Al content (1–9 wt%) were prepared, metal Ni and KIT-6 modified by Al were used as active component and support, respectively. The physicochemical properties of the prepared N20AxK catalysts were characterized by H2-TPR, XRD, BET, TEM, and H2-TPD. The catalytic hydrodeoxygenation(HDO) performance of N20AxK catalysts was evaluated by ethyl acetate catalytic HDO. The results show that the catalytic HDO performance of the prepared N20AxK catalysts is related to the adsorption and activation performance for H2 molecules, as well as the dispersion of matal Ni active components. N20A5K catalyst shows the best H2 adsorption property and Ni dispersion. N20A5K catalyst presents superior catalytic HDO performance. At 300 °C and atmospheric pressure, the conversion of ethyl acetate and ethane selectivity of N20A5K catalyst are 99.3 % and 97.4 %, respectively. Besides, the N20A5K catalyst exhibits good stability.
Funding statement: This research is funded by Research Foundation of Chongqing Technology and Business University (No. 1752001); Scientific and Technological Key Program of Chongqing Municipal Education Commission (KJZD-K201800801).
References
Aguado, J., G. Calleja, A. Carrero, and J. Moreno. 2010. “Morphological Modifications of Cr/SBA-15 and Cr/Al-SBA-15 Ethylene Polymerization Catalysts: Influence on Catalytic Behaviour and Polymer Properties.” Microporous and Mesoporous Materials 131: 294–302.10.1016/j.micromeso.2010.01.006Search in Google Scholar
Ambursa, M. M., L. H. Voon, and P. Sudarsanam. 2017. “Bimetallic Cu-Ni Catalysts Supported on MCM-41 and Ti-MCM-41porous Materials for Hydrodeoxygenation of Lignin Model Compound into Transportation Fuels.” Fuel Process Technology 162: 87–97.10.1016/j.fuproc.2017.03.008Search in Google Scholar
Ameen, M., M. T. Azizan, and Y. Suzana. 2017. “Catalytic Hydrodeoxygenation of Triglycerides an Approach to Clean Diesel Fuel Production.” Renewable and Sustainable Energy Reviews 80: 1072–88.10.1016/j.rser.2017.05.268Search in Google Scholar
Andrade, G. F., D. C. F. Soares, and R. G. D. Sabtos. 2013. “Mesoporous Silica SBA-16 Nanoparticles: Synthesis, Physicochemical Characterization,release Profile, and in Vitro Cytocompatibility Studies.” Microporous and Mesoporous Materials 168: 102–10.10.1016/j.micromeso.2012.09.034Search in Google Scholar
Arai, M., M. Fukushima, and Y. Nishiyama. 1996. “Interrupted-Temperature Programmed Desorption of Hydrogen over Silica-Supported Platinum Catalysts: The Distribution of Activation Energy of Desorption and the Phenomena of Spillover and Reverse Spillover of Hydrogen.” Applied Surface Science 99 (2): 145–50.10.1016/0169-4332(95)00598-6Search in Google Scholar
Arun, N., J. Maley, and N. Chen. 2017. “NiMo Nitride Supported on γ-Al2O3for Hydrodeoxygenation of Oleic Acid: Novel Characterization and Activity Study.” Catalysis Today 291: 153–59.10.1016/j.cattod.2017.03.053Search in Google Scholar
Arun, N., R. V. Sharma, and A. K. Dalai. 2015. “Green Diesel Synthesis by Hydrodeoxygenation of Bio-Based Feedstocks: Strategies for Catalyst Design and Development.” Renewable and Sustainable Energy Reviews 48: 240–55.10.1016/j.rser.2015.03.074Search in Google Scholar
Boudjahem, A. G., and M. M. Bettahar. 2017. “Effect of Oxidative Pre-Treatment on Hydrogen Spillover for a Ni/SiO2 Catalyst.” Journal of Molecular Catalysis A: Chemical 426 (1381–1169): 190–97.10.1016/j.molcata.2016.11.014Search in Google Scholar
Calleja, G., J. Aguado, and A. Carrero. 2007. “Preparation, Characterizationand Testing of Cr/AlSBA-15 Ethylene Polymerization Catalysts.” Journal of Molecular Catalysis A: Chemical 316: 22–31.Search in Google Scholar
Cerqueira, H. S., P. Magnoux, and D. Martin. 2001. “Coke Formation and Coke Profiles During the Transformation of Various Reactants at 450 °C over a USHY Zeolite.” Applied Catalysis A: General 208 (1): 359–67.10.1016/S0926-860X(00)00734-1Search in Google Scholar
Chen, J. Z., and Q. Y. Xu. 2016. “Hydrodeoxygenation of Biodiesel-Related Fatty Acid Methyl Esters to Diesel-Range Alkanes over Zeolite-Supported Ruthenium Catalysts.” Catalysis Science & Technology 6: 7239–51.10.1039/C6CY01242FSearch in Google Scholar
Chen, S., C. X. Miao, and Y. Luo. 2017. “Study of Catalytic Hydrodeoxygenation Performance of Ni Catalysts: Effects of Prepared Method.” Renewable Energy 115: 1109–17.10.1016/j.renene.2017.09.028Search in Google Scholar
Chen, S., X. Y. Pan, and C. X. Miao. 2018. “Study of Catalytic Hydrodeoxygenation Performance for the Ni/KIT-6 Catalysts.” Journal of Saudi Chemical Society 22 (5): 614–27.10.1016/j.jscs.2017.11.002Search in Google Scholar
Conner, W. C., and J. L. Falconer. 1997. “Spillover in Heterogeneous Catalysis.” Progress in Chemistry 95 (3): 123–30.10.1021/cr00035a014Search in Google Scholar
Coumans, A. E., and E. J. M. Hensen. 2017. “A Model Compound (Methyl Oleate, Oleic Acid, Triolein) Study of Triglycerides Hydrodeoxygenation over Alumina-Supported NiMo Sulfide.” Applied Catalysis B: Environmental 201: 290–301.10.1016/j.apcatb.2016.08.036Search in Google Scholar
Fukuhara, C., K. Hayakawa, Y. Suzuki, W. Kawasaki, and R. Watanabe. 2017. “A Novel Nickel-Based Structured Catalyst for CO2 Methanation: A Honeycomb-Type Ni/CeO2 Catalyst to Transform Greenhouse Gas into Useful Resources.” Applied Catalysis A: General 532: 12–18.10.1016/j.apcata.2016.11.036Search in Google Scholar
Guisnet, M., and P. Magnoux. 1997. “Deactivation by Coking of Zeolite Catalysts. Prevention of Deactivation. Optimal Conditions for Regeneration.” Catalysis Today 36 (4): 477–83.10.1016/S0920-5861(96)00238-6Search in Google Scholar
Hachemi, I., K. Jeništová, P. Mäki-Arvela, and N. Kumar. 2016. “Comparative Study of Sulfur-Free Nickel and Palladium Catalysts in Hydrodeoxygenation of Different Fatty Acid Feedstocks for Production of Biofuels.” Catalysis Science Technology 6: 1476–87.10.1039/C5CY01294ESearch in Google Scholar
Kellenberger, A., E. Jahne, H. J. Adler, T. Khandelwal, and L. Dunscha. 2008. “In Situ FTIR Spectroelectro Chemistry of Poly[2-(3-thienyl)ethyl Acetate] and Its Hydrolyzed Derivatives.” Electrochimica Acta 53: 7054–60.10.1016/j.electacta.2008.05.025Search in Google Scholar
Kumar, P., S. R. Yenumala, and S. K. Maity. 2014. “Kinetics of Hydeoxygenation of Stearic Acid Using Supported Nickel Catalysts: Effects of Supports.” Applied Catalysis A: General 471: 28–38.10.1016/j.apcata.2013.11.021Search in Google Scholar
Laursen, A. B., J. Sehested, I. Chorkendorff, and P. C. K. Vesborg. 2018. “Availability of Elements for Heterogeneous Catalysis: Predicting the Industrial Viability of Novel Catalysts.” Chinese Journal of Catalysis 39 (1): 16–26.10.1016/S1872-2067(17)62979-6Search in Google Scholar
Lee, P. I., and J. A. Schwarz. 1982. “Adsorption-Desorption Kinetics of H2from Supported Nickel Catalysts.” Journal of Catalysis 73: 272–87.10.1016/0021-9517(82)90100-2Search in Google Scholar
Li, X., X. Y. Luo, and Y. B. Jin. 2018. “Heterogeneous Sulfur-Free Hydrodeoxygenation Catalysts for Selectively Upgrading the Renewable Bio-Oils to Second Generation Biofuels.” Renewable and Sustainable Energy Reviews 82: 3762–97.10.1016/j.rser.2017.10.091Search in Google Scholar
Li, Y., C. S. Zhang, and Y. G. Liu. 2017. “Coke Formation on the Surface of Ni/HZSM-5 and Ni-Cu/HZSM-5 Catalysts during Bio-Oil Hydrodeoxygenation.” Fuel 189: 23–31.10.1016/j.fuel.2016.10.047Search in Google Scholar
Liu, H. R., S. Y. Xu, and G. L. Zhou. 2018. “CO2Hydrogenation to Methane over Co/KIT-6 Catalysts: Effect of Co Content.” Fuel 217: 570–76.10.1016/j.fuel.2017.12.112Search in Google Scholar
Liu, H. R., G. L. Zhou, and H. M. Xie. 2018. “CO2Hydrogenation to Methane over Co/KIT-6 Catalyst: Effect of Reduction Temperature.” Chemical Engineering Journal 351: 65–73.10.1016/j.cej.2018.06.087Search in Google Scholar
Liu, X., J. Chen, and J. Zhang. 2008. “Hydrodechlorination of Chlorobenzene over Silica-Supported Nickel Phosphide Catalysts.” Industrial & Engineering Chemistry Research 47 (15): 5362–68.10.1021/ie7017542Search in Google Scholar
Liu, X. G., J. X. Chen, and J. Y. Zhang. 2007. “A Novel Catalyst for Gas Phase Hydrodechlorination of Chlorobenzene: Silica Supported Ni3P.” Catalysis Communications 8 (12): 1905–09.10.1016/j.catcom.2007.03.008Search in Google Scholar
Lv, Y. H., Z. Xin, and X. Meng. 2018. “Ni Based Catalyst Supported on KIT-6 Silica for CO Methanation: Confinement Effect of Three Dimensional Channel on NiO and Ni Particles.” Microporous and Mesoporous Materials 262: 89–97.10.1016/j.micromeso.2017.06.022Search in Google Scholar
Ma, Y. Q., Q. H. Wang, X. H. Sun, C. F. Wu, and Z. Gao. 2017. “Kinetics Studies of Biodiesel Production from Waste Cooking Oil Using FeCl3-Modified Resin as Heterogeneous Catalyst.” Renewable Energy 107: 522–30.10.1016/j.renene.2017.02.007Search in Google Scholar
Melendez-Ortiz, H. I., B. Puente-Urbina, and G. C. Leon. 2016. “Synthesis of Spherical SBA-15 Mesoporous Silica. Influence of Reaction Conditions on the Structural Order and Stability.” Ceramics International 42: 7564–70.10.1016/j.ceramint.2016.01.163Search in Google Scholar
Michalska, K., P. Kowalika, M. Konkol, and W. Prochniak. 2016. “The Effect of Copper on Benzene Hydrogenation to Cyclohexane over Ni/Al2O3 Catalyst.” Applied Catalysis A: General 523: 54–60.10.1016/j.apcata.2016.05.016Search in Google Scholar
Mortensen, P. M., J. D. Grunwaldt, and P. A. Jensen. 2011. “A Review of Catalytic Upgrading of Bio-Oil to Engine Fuels.” Applied Catalysis A: General 407 (1): 1–19.10.1016/j.apcata.2011.08.046Search in Google Scholar
Nie, Z. Y., Z. N. Zhang, and J. X. Chen. 2017. “Effect of Ni and Noble Metals (Ru, Pd and Pt) on Performance of Bifunctional MoP/SiO2 for Hydroconversion of Methyl Laurate.” Applied Surface Science 420: 511–22.10.1016/j.apsusc.2017.05.173Search in Google Scholar
Nikparsaa, P., A. A. Mirzaeia, and H. Atashib. 2014. “Effect of Reaction Conditions and Kinetic Study on the Fischer-Tropsch Synthesis over Fused Co-Ni/Al2O3 Catalyst.” Journal of Fuel Chemistry and Technology 42: 710–18.10.1016/S1872-5813(14)60032-3Search in Google Scholar
Ortega-Domínguez, R. A., H. Vargas-Villagrán, and C. Peñaloza-Orta. 2017. “A Facile Method to Increase Metal Dispersion and Hydrogenation Activity of Ni/SBA-15 Catalysts.” Fuel 198: 110–22.10.1016/j.fuel.2016.12.037Search in Google Scholar
Phung, T. K., A. Alessandro, B. Aliakbarian, and E. Finocchio. 2013. “Catalytic Conversion of Ethyl Acetate and Acetic Acid on Alumina as Models of Vegetable Oils Conversion to Biofuels.” Chemical Engineering Journal 215: 838–48.10.1016/j.cej.2012.11.057Search in Google Scholar
Pozan, G. L. S. 2012. “Effect of Support on the Catalytic Activity of Manganese Oxide Catalyts for Toluene Combustion.” Journal of Hazardous Materials 221–222: 124–30.10.1016/j.jhazmat.2012.04.022Search in Google Scholar PubMed
Sanaeishoar, H., M. Sabbaghan, F. Mohave, and R. Nazarpour. 2016. “Disordered Mesoporous KIT-1 Synthesized by DABCO-Based Ionic Liquid and Its Characterization.” Microporous and Mesoporous Materials 228: 305–09.10.1016/j.micromeso.2016.04.003Search in Google Scholar
Shin, E. J., A. Spiller, and G. Tavoularis. 1999. “Chlorine Nickel Interactions in Gas Phase Catalytic Hydrodechlorination: Catalyst Deactivation and the Nature of Reactive Hydrogen.” Physical Chemistry Chemical Physics 1 (1): 3173–81.10.1039/a902345cSearch in Google Scholar
Smirnov, A. A., Z. Geng, and S. A. Khromova. 2017. “Nickel Molybdenum Carbides: Synthesis, Characterization, and Catalytic Activity in Hydrodeoxygenation of Anisole and Ethyl Caprate.” Journal of Catalysis 354: 61–77.10.1016/j.jcat.2017.07.009Search in Google Scholar
Vedyagin, A. A., A. M. Volodin, R. M. Kenzhin, and V. O. Stoyanovskii. 2017. “Effect of Metal-Metal and Metal-Support Interaction on Activity and Stability of Pd-Rh/alumina in CO Oxidation.” Catalysis Today 293–294: 73–81.10.1016/j.cattod.2016.10.010Search in Google Scholar
Wang, J., Z. P. Zhong, B. Zhang, K. Ding, and Z. Y. Xue. 2017. “Upgraded Bio-Oil Production via Catalytic Fast Co-Pyrolysis of Waste Cooking Oil and Tea Residual.” Waste Management 60: 357–62.10.1016/j.wasman.2016.09.008Search in Google Scholar PubMed
Wang, W., R. Qi, and W. J. Shan. 2014. “Synthesis of KIT-6 Type Mesoporous Silicas with Tunable Pore Sizes, Wall Thickness and Particle Sizes via the Partitioned Cooperative Self-Assembly Process.” Microporous and Mesoporous Materials 194: 167–76.10.1016/j.micromeso.2013.10.028Search in Google Scholar
Xia, H. A., J. H. An, and M. Hong. 2019. “Aerobic Oxidation of 5-hydroxymethylfurfural to 2,5-difurancarboxylic Acid over Pd-Au Nanoparticles Supported on Mg-Al Hydrotalcite.” Catalysis Today 319: 113–20.10.1016/j.cattod.2018.05.050Search in Google Scholar
Xia, H. A., H. Hu, and S. Q. Xu. 2018. “Catalytic Conversionof Glucose to 5-hydroxymethyfural over Fe/β Zeolites with Extra-Framework Isolated Fe Species in a Biphasic Reaction System.” Biomass & Bioenergy 108: 426–32.10.1016/j.biombioe.2017.12.007Search in Google Scholar
Xia, H. A., S. Q. Xu, and H. Hu. 2018. “Efficient Conversion of 5-hydroxymethylfurfural to High-Valued Chemicals by Chemo- and Bio-Catalysis.” RSC Advances 8: 30875–86.10.1039/C8RA05308ASearch in Google Scholar PubMed PubMed Central
Zhou, G. L., B. C. Dai, and H. M. Xie. 2017. “CeCu Composite Catalyst for CO Synthesis by Reverse Water–Gas Shift Reaction: Effect of Ce/Cu Mole Ratio.” Journal of CO2 Utilization 21: 292–301.10.1016/j.jcou.2017.07.004Search in Google Scholar
Zhou, G. L., H. R. Liu, and S. Y. Xu. 2018. “CO2 Hydrogenation to Methane over Mesoporous Co/SiO2 Catalysts: Effect of Structure.” Journal of CO2 Utilization 26: 221–29.10.1016/j.jcou.2018.04.023Search in Google Scholar
Znak, L., and J. Zielin´ski. 2008. “Effects of Support on Hydrogen Adsorption/Desorption on Nickel.” Applied Catalysis A: General 334: 268–76.10.1016/j.apcata.2007.10.015Search in Google Scholar
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