This research aimed to investigate the technique of taking photograph in case of adjusting opposite direction of color temperature of color illumination. A room was illuminated by seven colors illuminants; red, yellow, green, blue, magenta, cyan and white. Then took photograph under white balance setting in 5 differences; 5500K, 6000K, 6500K, 7000K, and 7500K. The photographs printed on the semigloss paper and measured the color of photograph compared with the color of the real scene. The research showed that the setting white balance at 6500K gave the almost same color of the real scene.