地球化学
Online ISSN : 2188-5923
Print ISSN : 0386-4073
ISSN-L : 0386-4073
総説
炭酸塩による放射性核種の収着に関する研究 –研究の現状と課題–
金井 豊
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ジャーナル フリー

2007 年 41 巻 1 号 p. 1-16

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Studies on sorption/adsorption behavior of radioactive nuclides by carbonates in the environment including the experimental methods and the partition coefficients are reviewed, and the future necessary researches for the geological disposal of high level radioactive waste are shown. The ubiquitous carbonates are expected to sorb and retain the leached nuclides. The partition coefficient is an important value for the sorption - inclusion process of element into the carbonate crystal. It is calculated by two ways; empirically and thermodynamically, however, they are quite different. As the former depends on the physicochemical parameters such as precipitation rate and temperature, etc., the relationships between the empirical partition coefficient and the physicochemical parameters should be clarified. Furthermore, the data for fission product elements and actinides should also be collected systematically because they are insufficiently reported.

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© 2007 日本地球化学会
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