Chemical Protection Studies of Activated Carbon Spheres based Permeable Protective Clothing Against Sulfur Mustard, a Chemical Warfare Agent

  • Manisha Sathe DRDO-Defence Research and Development Establishment, Gwalior - 474 002
  • Pushpendra K. Sharma DRDO-Defence Research and Development Establishment, Gwalior - 474 002
  • Virendra K. Singh DRDO-Defence Research and Development Establishment, Gwalior - 474 002
  • Nagesh K. Tripathi DRDO-Defence Research and Development Establishment, Gwalior - 474 002
  • Vijay Verma DRDO-Defence Research and Development Establishment, Gwalior - 474 002
  • Shiv Prakash Sharma DRDO-Defence Research and Development Establishment, Gwalior - 474 002
  • L.N. S. Tomar DRDO-Defence Research and Development Establishment, Gwalior - 474 002
  • Ajay Chaturvedi DRDO-Defence Research and Development Establishment, Gwalior - 474 002
  • S. S. Yadav DRDO-Defence Research and Development Establishment, Gwalior - 474 002
  • Vikas B. Thakare DRDO-Defence Research and Development Establishment, Gwalior - 474 002
  • Jyotiranjan Acharya DRDO-Defence Research and Development Establishment, Gwalior - 474 002
  • Arvind Kumar Gupta DRDO-Defence Research and Development Establishment, Gwalior - 474 002
  • K. Ganesan DRDO-Defence Research and Development Establishment, Gwalior - 474 002
Keywords: Chemical warfare agents, Chemical protective suit, Activated carbon spheres, Sulphur mustard, Chemical protection, NBC protective suit

Abstract

Technological advancements in the field of chemical threat have made it possible to create extremely dangerous chemical warfare agents (CWA). Hence, the effective protection of personnel is very important in a chemical warfare scenario amidst the current climate of terrorism awareness. In particular, body protection plays a substantial role in the chemical defence considering the urgency of situation in the nuclear, biological and chemical environment. Activated carbon spheres (ACS) based permeable chemical protective clothing (coverall) was developed for protection against CWA. The adsorbent material i.e, ACS used in this protective clothing provided higher adsorption capacity (1029 mg/g in terms of iodine) and low thermal burden (34 °C WBGT index) compared to earlier indigenously developed NBC suit. This article focuses on the extensive evaluation of chemical protective clothing against sulfur mustard (HD), a CWA. The results revealed that the developed protective clothing provided more than 24 h protection against HD. This chemical protective suit is light weight (< 2.75 kg for XL size). It also has higher air permeability (> 30 cm3/s/cm2) as well as less water vapour resistance (< 9.6 m2Pa/W). With continued innovations in materials and attention to key challenges it is expected that advanced, multifunction chemical protective suit will play a pivotal role in the CWA protection scenario.

Author Biographies

Manisha Sathe, DRDO-Defence Research and Development Establishment, Gwalior - 474 002

Dr Manisha Sathe received her PhD from Jiwaji University, Gwalior, in 2002. Currently, she is a Scientist F in DRDO Defence Research & Development Establishment, Gwalior. Her research area includes: natural product chemistry, hapten immunoassay and development of materials for protective ensemble.
In current study, she contributed to provide the overall guidance and critical suggestions in the test and evaluation of the swatch samples taken from NBC Suit Mk V.

Pushpendra K. Sharma, DRDO-Defence Research and Development Establishment, Gwalior - 474 002

Mr Pushpendra K Sharma received his MSc from MDSU, Ajmer, in 2005 and M.Tech from IIT, Dehli, in 2011. Currently, he is a Scientist D in DRDO-Defence Research & Development Establishment, Gwalior. His research area includes adsorbent materials, development of detection and decontamination systems for CWAs based on electrochemical methods using conducting polymers, metal, metal oxide and phthalocyanine nanocomposite materials. In addition of this, he is also contributed in the detection of BWAs based on SPR methodology.

In the current study, he was involved in conceptualisation and developing the testing procedures for testing and evaluation and manuscript writing.

Virendra K. Singh, DRDO-Defence Research and Development Establishment, Gwalior - 474 002

Dr Virendra V. Singh received his PhD from Jiwaji University, Gwalior, in 2011. Currently, he is a Scientist D in DRDO-Defence Research & Development Establishment, Gwalior. His current research interests include adsorbent materials, self-propelled micro/nanomotors, fabrication of different reactive micromotors for remediation applications, and development of detection systems based on conducting polymers, graphene nanomaterials, and ionic liquids using electrochemical methods.

In the current study, he was involved in conceptualisation and designing of the liquid challenge test assembly and data compilation.

Nagesh K. Tripathi, DRDO-Defence Research and Development Establishment, Gwalior - 474 002

Dr Nagesh K. Tripathi received his PhD (Chemical Engineering) from National Institute of Technology, Rourkela. Currently, he is a Scientist D in DRDO-Defence Research & Development Establishment, Gwalior. His areas of research are scale up of activated carbon spheres production, development of chemical protective suit and process development for production of recombinant proteins.

In the current study, he was involved in the process development of ACS and quality control of ACS required for the coating and lamination.

Vijay Verma, DRDO-Defence Research and Development Establishment, Gwalior - 474 002

Mr Vijay Verma obtained Diploma in Textile Technology from ODCH, Delhi in 2004. Currently, he is a Technical Officer B in DRDO-Defence Research & Development Establishment, Gwalior.

In current study, he contributed in the textile testing and evaluation of NBC protecting clothing.

Shiv Prakash Sharma, DRDO-Defence Research and Development Establishment, Gwalior - 474 002

Shiv Prakash Sharma did his MSc from Jai Narain Vyas University in Chemistry in 2002. Currently, he is a Scientist D in DRDO-Defence Research & Development Establishment, Gwalior. His area of interest is testing and evaluation of NBC protecting clothing and chemical detectors.

In current study, he contributed in the conducting experiments for vapour challenge study.

L.N. S. Tomar, DRDO-Defence Research and Development Establishment, Gwalior - 474 002

L.N.S.Tomar did his MSc from M.P. Bhoj Open, university in chemistry. Currently, he is a Technical Officer B in DRDODefence Research & Development Establishment, Gwalior. His area of interest includes testing and evaluation of NBC protecting clothing and chemical detectors.

In current study, he contributed in the quantitative analysis of liquid and vapour challenge studies.

Ajay Chaturvedi, DRDO-Defence Research and Development Establishment, Gwalior - 474 002

Mr Ajay Chaturvedi did his BE in Electronics and communication from MITS, Gwalior in 2005. Currently, he is a Scientist D  in DRDO-Defence Research & Development Establishment, Gwalior. His area of interest includes development of flame photometry based chemical agent detectors.

In current study, he contributed in the designing the vapour challenge test setup.

S. S. Yadav, DRDO-Defence Research and Development Establishment, Gwalior - 474 002

Mr S.S. Yadav obtained BSc from Jiwaji University, in 1988. Currently, he is a Technical Officer C in DRDO-Defence Research & Development Establishment, Gwalior.

In current study, he contributed in the qualitative testing and evaluation of NBC protecting clothing.

Vikas B. Thakare, DRDO-Defence Research and Development Establishment, Gwalior - 474 002

Dr Vikas B. Thakare obtained Bachelor in Textile Technology from VJTI, Mumbai and PhD in Management from ITM University, Gwalior. Currently, he is a Scientist G in DRDODefence Research & Development Establishment, Gwalior. His area of interest includes development of next generation protective gears for CBRN Defence.

In current study, he contributed to provide the overall guidance and critical suggestions in the study.

Jyotiranjan Acharya, DRDO-Defence Research and Development Establishment, Gwalior - 474 002

Dr Jyotiranjan Acharya received his MSc (Organic Chemistry) and PhD (Medicinal Chemistry) from Jiwaji University, Gwalior, India, in 1999 and 2008, respectively. Currently, he is a Scientist E in DRDO-Defence Research & Development Establishment, Gwalior. His area of interest includes: Development of antidotes against anticholinesterase agents.

In the current study, he contributed in the synthesis, purification and characterisation of Sulphur Mustard.

Arvind Kumar Gupta, DRDO-Defence Research and Development Establishment, Gwalior - 474 002

Dr Arvind Kumar Gupta received his MSc in chemistry and PhD from Jiwaji University, Gwalior, in 1987 and 2003, respectively. Currently he is Scientist G in DRDO-Defence Research & Development Establishment, Gwalior. His area of interest includes Synthesis, characterisation and analysis of chemical warfare agents and their antidotes. 

In the current study, he contributed in the overall guidance in synthesising the highly toxic chemical warfare agents.

K. Ganesan, DRDO-Defence Research and Development Establishment, Gwalior - 474 002

Dr K. Ganesan obtained PhD (Chemistry) from Jiwaji University, Gwalior. Presently, he is Scientist G in DRDO-Defence Research & Development Establishment, Gwalior. His areas of work include: defence against chemical warfare agents and development of new mosquito control techniques.

In current study, he contributed to provide the overall guidance and critical suggestions in the study.

Published
2019-12-16
How to Cite
Sathe, M., Sharma, P., Singh, V., Tripathi, N., Verma, V., Sharma, S., Tomar, L., Chaturvedi, A., Yadav, S., Thakare, V., Acharya, J., Gupta, A., & Ganesan, K. (2019). Chemical Protection Studies of Activated Carbon Spheres based Permeable Protective Clothing Against Sulfur Mustard, a Chemical Warfare Agent. Defence Science Journal, 69(6), 577-584. https://doi.org/10.14429/dsj.69.13958
Section
Materials Science & Metallurgy