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Use of soil spectral reflectance to estimate texture and fertility affected by land management practices in Ethiopian tropical highland

  • Gizachew Ayalew Tiruneh ,

    Roles Conceptualization, Data curation, Methodology, Supervision, Validation, Writing – original draft, Writing – review & editing

    tiruneh1972@gmail.com

    Affiliation Faculty of Agriculture and Environmental Sciences, Debre Tabor University, Debre Tabor, Ethiopia

  • Derege Tsegaye Meshesha,

    Roles Conceptualization, Data curation, Methodology, Supervision, Validation, Writing – original draft, Writing – review & editing

    Affiliation College of Agriculture and Environmental Sciences, Bahir Dar University, Bahir Dar, Ethiopia

  • Enyew Adgo,

    Roles Conceptualization, Supervision, Validation, Writing – review & editing

    Affiliation College of Agriculture and Environmental Sciences, Bahir Dar University, Bahir Dar, Ethiopia

  • Atsushi Tsunekawa,

    Roles Funding acquisition, Project administration, Writing – review & editing

    Affiliation Arid Land Research Center, Tottori University, Tottori, Japan

  • Nigussie Haregeweyn,

    Roles Conceptualization, Funding acquisition, Supervision, Validation, Writing – review & editing

    Affiliation International Platform for Dryland Research and Education, Tottori University, Tottori, Japan

  • Ayele Almaw Fenta,

    Roles Conceptualization, Formal analysis, Methodology, Project administration, Supervision, Writing – review & editing

    Affiliation Arid Land Research Center, Tottori University, Tottori, Japan

  • Anteneh Wubet Belay,

    Roles Investigation, Project administration, Writing – review & editing

    Affiliation College of Agriculture and Environmental Sciences, Bahir Dar University, Bahir Dar, Ethiopia

  • Nigus Tadesse,

    Roles Conceptualization, Data curation, Formal analysis, Validation, Writing – review & editing

    Affiliation College of Agriculture and Environmental Sciences, Bahir Dar University, Bahir Dar, Ethiopia

  • Genetu Fekadu,

    Roles Conceptualization, Data curation, Formal analysis, Validation, Writing – review & editing

    Affiliation College of Agriculture and Environmental Sciences, Bahir Dar University, Bahir Dar, Ethiopia

  • José Miguel Reichert

    Roles Conceptualization, Data curation, Formal analysis, Investigation, Writing – review & editing

    Affiliation Soils Department, Universidade Federal de Santa Maria (UFSM), Santa Maria, RS, Brazil

Abstract

As classical soil analysis is time-consuming and expensive, there is a growing demand for visible, near-infrared, and short-wave infrared (Vis-NIR-SWIR, wavelength 350–2500 nm) spectroscopy to predict soil properties. The objectives of this study were to investigate the effects of soil bunds on key soil properties and to develop regression models based on the Vis-NIR-SWIR spectral reflectance of soils in Aba Gerima, Ethiopia. Soil samples were collected from the 0–30 cm soil layer in 48 experimental teff (Eragrostis tef) plots and analysed for soil texture, pH, organic carbon (OC), total nitrogen (TN), available phosphorus (av. P), and potassium (av. K). We measured reflectance from air-dried, ground, and sieved soils with a FieldSpec 4 Spectroradiometer. We used regression models to identify and predict soil properties, as assessed by the coefficient of determination (R2), root mean square error (RMSE), bias, and ratio of performance to deviation (RPD). The results showed high variability (CV ≥ 35%) and substantial variation (P < 0.05 to P < 0.001) in soil texture, OC, and av. P in the catchment. Soil reflectance was lower from bunded plots. The pre-processing techniques, including multiplicative scatter correction, median filter, and Gaussian filter for OC, clay, and sand, respectively were used to transform the soil reflectance. Statistical results were: R2 = 0.71, RPD = 8.13 and bias = 0.12 for OC; R2 = 0.93, RPD = 2.21, bias = 0.94 for clay; and R2 = 0.85 with RPD = 7.54 and bias = 0.0.31 for sand with validation dataset. However, care is essential before applying the models to other regions. In conclusion, the findings of this study suggest spectroradiometry can supplement classical soil analysis. However, more research is needed to increase the prediction performance of Vis-NIR-SWIR reflectance spectroscopy to advance soil management interventions.

Introduction

Ethiopia has a wide spatial diversity of soil properties [1]. Improved sustainable land management (SLM) practices including soil bunding may alter key soil qualities [2,3] and control soil loss [4,5], and thereby soil functions [6,7]. SLM activities influence soil physicochemical properties and minimize soil degradation while improving yields [8,9] and they improve people’s livelihoods [10]. However, livelihoods are at risk because of soil fertility depletion [11]. Hence, increasing crop production to feed the population is a challenge.

Understanding soil quality requires characterization and assessing spatial variation of soil properties related to crop growth and development [12,13]. Information on soil fertility is needed for site-specific crop and fertilizer management [14,15]. Crop production and yield, plant indicators, and soil texture and colour are widely used to measure soil fertility [16]. The lack of an up-to-date soil database impedes government efforts to boost agricultural production in Ethiopia. Most soil guidelines are not site-specific and soil fertility interventions tend to be blanket recommendations [17,18]. Failing to use soil data can result in nutrient depletion [19], compaction, flooding, and low crop yields [20]. Thus, detailed soil data are essential.

Knowledge of soil resources is essential for developing effective land-use planning and implementing SLM practices. Little information is available for the Upper Blue Nile Basin of Ethiopia, where soils and land-use types patterns fluctuate within small distances [21,22]. Reasons include unavailability and inflated costs of soil laboratory tests, particularly for many soil samples gathered over time and in large areas.

To determine soil properties, Ethiopia has relied on costly and time-consuming traditional analytical methods. However, it faces a crucial difficulty in using these methods owing to the high cost of chemicals and the poor performance of laboratories. As a result, rapid sampling and analysis of soil properties in the field and laboratory are unavailable.

Laboratory soil spectrometry in the visible, near-infrared, and short-wave infrared (Vis-NIR-SWIR, 350–2500 nm) range provides an option for physical and chemical soil studies [23]. Contents of soil OC [24,25], clay [26], TN [27], and soil texture [28] have been well estimated from Vis-NIR-SWIR spectra.

Land-use and management strategies highly influence soil properties [8,29,30]. Understanding variations in soil properties across fields is critical for assessing crop growth and development restrictions related to soil nutrients and to proposing corrective steps for optimal development and effective land-use management [8]. SLM activities, including soil bunds, should address increased human demands and maintain environmental sustainability [31]. Bunds are slope-side embankments made of soil, stone, or a combination of the two. Soil eroded between two bunds is dumped behind the lower bund, which is then lifted to create a bench terrace is formed [32]. Bunds improve soil fertility by reducing runoff and soil loss [33,34].

Furthermore, implementing effective soil bunding can be beneficial in restoring degraded soil quality and functions while ensuring sustainable production. Consequently, understanding how soil properties change as a result of various land management practices is vital to proposing optimal management practices. This research would also help farmers and local planners in developing successful land conservation strategies.

Soil erosion and depleted soil productivity have been major issues in the Aba Gerima catchment, resulting in low crop yields. It would also be useful to replace traditional laboratory soil analysis with more accurate and low-cost methods. Spectroradiometry performed well in measuring soil carbon in different agroecologies, soil forms, and land management activities of Ethiopia [34], but spectroradiometric evidence of the effects of soil bunding on soil characteristics is lacking in the catchment, Ethiopia, and Africa as a whole. Thus, the objectives of this study were to develop regression models from Vis-NIR-SWIR spectral reflectance data and assess the effects of soil bunding on soil texture, pH, OC, TN, av. P, and av. K by using spectroradiometric evidence.

Materials and methods

Description of the study area

The study was carried out at Aba Gerima (11°39′0″N– 11°40′30″N and 37°29′30″E– 37°31′30″E), a tropical highland of Ethiopia (Fig 1B). By the Köppen–Geiger classification, the site represents midland, [35], with altitudes varying from 1,900 to 2,000 m above sea level.

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Fig 1.

Locations of study catchment and soil sampling plots: (a) Ethiopia, (b) Aba Gerima land-use/land-cover (LULC) types, and (c) Soil sampling plots.

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Records from 1994 to 2021 at nearby meteorological stations show that the study area receives an average annual rainfall of 1,076 to 1,953 mm and has an average monthly maximum temperature of 27.0°C and an average monthly minimum temperature of 12.6°C (Fig 2; S1 Table). The main rainfall occurs from June to August, and the rest of the year is dry [36].

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Fig 2. Long-term (1994–2021) monthly rainfall (RF), maximum temperature (Tmax), and minimum temperature (Tmin) in the study area.

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Methods

Soil sampling approaches

Cultivated lands were considered in 2019 according to land-use/land-cover information [37]. The catchment having an area of 426 hectare was categorized into three topographic classes, namely gently (2%–5%), moderately (5%–10%), and strongly sloping (10%–15%). There were 24 plots without soil bunds (WB) and 24 plots with soil bunds (SB) reinforced with grass and stone. The soil bunds were built all over the catchment [38,39]. The stone bunds and soil bunds are commonly used on steep slopes (Fig 3A) and moderate slopes (Fig 3B), respectively. The bunds are five years old, have bottom width of 0.8 m and a height of 0.5 m, as described by [40]. Bahir Dar University permitted the work, field site access, and soil sampling in the catchment. Forty-eight representative soil-sampling plots were identified, with a minimum size of 40 m × 40 m (1600 m2) each. All plots were intentionally distributed (Fig 1E). Each plot was geo-referenced with a handheld GPS device (GPSMAP64, Garmin, Olathe, Kansas, USA). In each plot, five soil samples were collected at the top (0–30 cm depth) with an Edelman auger and mixed well in a bucket to make a 1-kg composite soil sample.

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Fig 3.

Treated with stone-faced soil bunds (a) and with soil bunds (b) at the upper and lower slopes in Aba Gerima catchment.

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Physicochemical soil analysis

Composite soil samples (n = 48) were air-dried, ground, and sieved to 2 mm. Later, they were analysed for soil texture, pH, OC, TN, av. P, and av. K at Amhara Design and Supervision Works Enterprise. After the annihilation of organic matter (OM) and soil dispersion, soil texture (sand, silt, and clay) was determined by the hydrometer method [41]. Silt and clay were determined from hydrometer readings after 40 s and clay particles in suspension after 2 h, and the percentage of sand was estimated subtracting by 100 from (clay (%) + sand (%)). Finally, we calculated soil textural classes using the textural triangle of the USDA system [42,43].

Soil pH was determined potentiometrically with a digital pH meter in a 1:2.5 (soil:water) supernatant suspension [44]. Into 100-mL beakers, we poured 10 g of air-dried soil and 25 mL of purified water, stirred it for 1 min with a glass rod and allowed it to equilibrate for 1 h before we measured the pH of the supernatant. Soil OC content was analysed with the wet digestion method, which entails digesting the OC with potassium dichromate in a sulphuric acid solution [45].

Soil TN was determined by the Kjeldahl process, which involves oxidizing OM with condensed sulfuric acid and converting the organic N into ammonia. We weighed 1 g of air-dried soil (<0.5 mm sieve) into a digestion tube; added 2 g of catalyst mixture and a couple of carborundum boiling stones, then stirred the mixture; added 7 mL of concentrated H2SO4; and digested the mixture on a block digester preheated to 300°C until the digest was white. After it cooled, we added 50 mL of distilled water, transferred the digest into macro Kjeldahl flasks, and rinsed it with distilled water. We weighed 20 mL of boric acid into a receiver flask, added two drops of indicator solution, and placed the flask under the condenser. Then 75 mL of 40% NaOH was carefully squeezed down the neck of each distillation flask containing the digest, and the mixture was gently stirred. The digests were placed in Kjeldahl distillation flasks, fitted to the appropriate holders, and heated to begin the distillation. The receiver flask was removed when about 80 mL of distillate was obtained. The solution in the receiver flask was stirred with a magnetic stirrer bar and titrated with 0.1 N H2SO4 from green to pink.

Available P was quantified by the Bray II approach, shaking the soil sample with 0.3 N ammonium fluoride in 0.1 N hydrochloric acid, as described by [46]. The av. P was then measured by spectrophotometer [47]. Available K was analysed by extracting the soil sample with Morgan’s solution and measured with a flame photometer [48].

Soil spectra collection and pre-processing

Each air-dried and ground soil sample (Fig 4D) was placed on a table covered with black geo-membrane. The soil reflectance data in the Vis-NIR-SWIR (350–2500 nm) range were collected with an ASD FieldSpec 4 spectroradiometer (Analytical Spectral Devices [ASD] Inc., Boulder, CO, USA; Fig 4D). Reflectance was measured between 10:30 and 11:00 in direct sunlight. The field of view was set at 25°, and the distance between the trigger of the spectroradiometer’s fibre optic cable and the soil specimen was held at 10 cm for all observations. The spectroradiometer was recalibrated against a white Spectralon (Labsphere Inc., North Sutton, NH, USA) every 10 min.

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Fig 4.

Soil spectral measurement: (a) soil samples, (b) FieldSpec Pro spectroradiometer with battery, (c) a close-up of fiber optic cable, and (d) soil reflectance measurement with the sensor.

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The radiometer was placed on a table at 1 m above the ground. To avoid unwanted scattering, the table was covered with black geo-membrane. Each scan took 22 s, and a reading was done on each sample. The reflected spectra were recorded and processed in Remote Sensing 3 v.6.4, View Spec Pro v.6.2 software (ASD Inc.). The pre-processing techniques, such as multiplicative scatter correction, median filter, and Gaussian filter for OC, clay, and sand, respectively were used to transform the spectrum using licensed Unscrambler v.10.5 software (CAMO, Inc., Oslo, Norway). The analysis omitted the noisy spectral regions between 1,340–1,459 nm 1,802–1,971 nm, and 2402–2500 nm [49,50] before spectral modeling.

Data analysis

Before analysis, we verified the soil dataset (n = 48) for normality assumption by the skewness, kurtosis, and Shapiro–Wilk tests (P < 0.05). The data were tested by Pearson’s linear correlation analysis in SAS v. 9.4 and SPSS v. 24.0 (SPSS Inc., Chicago, IL, USA) software.

We analysed variance and regression in SAS v. 9.4 and separated the means by the least significant difference test (P < 0.05). The datasets were divided randomly into 65% of datasets for calibration (31 samples) and 35% of datasets for validation (17 samples). We calculated the coefficient of determination (R2; [51]), root mean square error (RMSE), bias, and ratio of performance to deviation (RPD) [52] (McDowell et al., 2012).) for calibration (31 soil samples) and validation (17 soil samples) as: Eq 1 Eq 2 Eq 3 Eq 4 where n is the number of observations, ŷ is the predicted value, ӯ is the mean observed value, y is the observed (measured) value, and SD is the standard deviation of observed values.

When R2 approaches 1, RPD > 2 RMSE and bias approaches 0, a model improves as a predictor and becomes more efficient [53]. According to [54], models with RPD > 2 are considered “excellent” models with RPD ranging from 1.4 to 2 are considered “acceptable,” and models with RPD < 1.4 are considered “poor.”

Results and discussion

General statistics for measured soil properties

Soil OC, TN, and av. P had high variability (CV ≥ 35%), but soil pH had low variability (CV ≤ 15%) ([55]; Table 1). The high variability in soil properties might be due to soil erosion [56]. The low variability of soil pH corroborates findings of pH varies slightly [6].

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Table 1. Descriptive statistics and Shapiro–Wilk probability test of soil parameters in Aba Gerima catchment, Blue Nile basin.

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The skewness, kurtosis, and Shapiro–Wilk (P < 0.05) tests indicated that soil texture, pH, and av. K (Table 1; S1S3 Figs) met the assumption of homogeneity of variance [57]. However, soil OC, TN, and av. P tended to be logarithmically distributed owing to their positive skewness and slightly asymmetrical distribution (Figs 5 and S1). Similar results are presented in the literature [58].

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Fig 5. Pearson’s correlation matrix among soil variables in the 0–30 cm soil layer.

Correlation values are colour-coded. OC, organic carbon; TN, total nitrogen; av. P, available phosphorus; av. K, available potassium. Asterisks indicate significant differences: *P < 0.05 and **P < 0.01.

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Correlation and regression analyses

Soil pH exhibited a weak relationship with av. K and clay content with av. P (Fig 4; [59]). Soil OC had no relation with av. P or av. K. Similarly (except pH vs. av. K), soil pH and OC did not correlate with K or P contents in Ethiopia [60], Morocco [61], and China [62]. However, the increased soil OC, pH, and clay content might contribute to higher av. P and av. K contents. As the strong positive correlation between soil OC and TN indicated collinearity, we eliminated TN from the variance and spectral analyses. In contrast, [63] found a close relationship between soil OC and TN, as most of the TN was bound in the soil OM.

Influences of soil bunding on changes in soil properties

Soil texture, OC, and av. P contents varied substantially (P < 0.05 to P < 0.001) between bunded and non-bunded plots in the three slope classes (Table 2). Soil pH in the Aba Gerima catchment varied from strongly (<5.5) to moderately acidic (5.6–6.5) [64]. In bunded plots, higher soil pH values could be attributed to clay and OM, which retain more basic cations. Lower pH values obtained at non-bunded plots might be due to the inappropriate use of ammonium-based fertilizers and pesticides [65], increased leaching of basic cations, and nitrification ([34,66]. Consequently, the soils of the study area could be affected by acidity problems. Thus, soil pH is a key parameter to monitor the influences of SLM practices on soil quality and crop growth in the region.

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Table 2. Analysis of variance in the effect of bunding on soil properties in Aba Gerima.

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The Aba Gerima catchment’s soils range from clayey to sandy loam [S4 Fig; 41]. The dominance of silt and clay particles in bunded plots in all three slope classes (S1B, S2B, S3B; Table 2) could be due to the control of soil erosion by bunding. Conversely, the dominance of sand in non-bunded plots on strong slopes (S2W and S3W) might be related to the erosion of finer soil particles [67]. Similarly, bunded soils have higher silt and clay content and lower sand content than non-bunded soils [68,69].

Contents of OC (excluding S1B), av. P, and av. K were low [64], lower than values reported in the same catchment [6] and the Uwite Catchment, Ethiopia [70]. However, the OC concentration of the soil in S1B was within the recommended range for plant growth.

Low levels of OC and av. K could be ascribed to higher rates of erosion due to rainfall, inappropriate cultivation, removal of crop remains and animal dung, a high rate of mineralization through increased temperature, and leaching [71,72]. The highest contents of clay (61%), OC (2.30%), av. P (13.72 ppm), and av. K (116.55 mg/kg) were found in bunded plots on gentle slopes (S1B), possibly due to the accumulation of fine soil particles and available nutrients. These findings support reports that bunding improves soil fertility [6,73] and indicate that it improved clay and silt accumulation, soil OC, av. P, and av. K contents 5 years after implementation.

The pH, OC, av. P, and av. K values were lower than critical levels, explaining reduced soil quality in the Aba Gerima catchment. Thus, enhancing the quality of Ethiopian soils requires increasing soil OM content through the implementation of SLM methods and biomass accumulation [8,74].

Reflectance characteristics of soils

The mean spectral reflectance of the 48 soil samples tended to increase between 350 and 1100 nm (visible and near-infrared regions) (Fig 6). The lower reflectance of soils from bunded plots could be due to higher soil OM content and smaller particle size [75,76] or to intensive mineral fertilization, higher microbial activity, and lower soil pH [77]. As evidenced by the absorption peaks in Fig 6 [78,79], it could potentially be attributable to the Fe-OH or Mg-OH in the soils.

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Fig 6. Soil reflectance spectra with and without bunding.

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The soils of the catchment vary from clayey to sandy loam soils (S2 Fig). Reflectance was highest from sandy loam soils throughout the spectrum, lowest from clay soils at 400–1000 nm and loam soils at 1000–2400 nm (Fig 7). As a result, smaller soil particles have higher reflectance. This finding is consistent the results [80] that sandy soils had higher reflectance and clay soils had lower reflectance. As particle size decreases, multiple scattering increases, thus increasing reflectance [81]. Furthermore, the soil spectral reflectance curve showed different trends at different wavelengths, rising rapidly at 400–600 nm and more steadily at 800–2450 nm.

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Fig 7. Influence of soil texture on soil spectral signatures.

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Soils with higher OC content are darker and have lower spectral reflectance than soils with lower OC content (Fig 8) [82]. The presence of OM strongly influences soil reflectance, which decreases as OM content increases [83]. Similarly, as soil moisture increases, the reflectance of incoming visible light falls consistently, making soils look darker [84]. In comparison to dark soils, red soils have less OM and more iron oxides. As a result, soils rich in iron have greater reflectance than soils rich in soil OC [85].

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Fig 8. Effects of soil organic carbon content on soil spectral reflectance.

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Modeling of soil properties

Fig 9 shows the results of the PLSR analysis calibrated to predict OC, clay, and sand content using pre-processed soil reflectance. For each visible band (400–700 nm), near-infrared band (701–1300 nm), and short-wave infrared band (1301–2500 nm), the red box shows the high loading and influential wavelengths associated with soil properties Higher loading values could indicate which portions of the wavelengths are the most influential in the calibration.

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Fig 9. Loading (contribution) of relevant wavelength for modeling soil properties.

(a) Clay, (b) Sand, and (c) organic carbon contents.

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In the visible range, wavelengths with the highest correlation loading values are 355 and 570 nm for organic carbon, and 568 and 570 nm for clay content; 568 and 570 nm for sand content prediction. Thus, the visible spectrum was the most influential in the OC, clay, and sand prediction models. This behavior could owing be to the soil color, which is dominated by free iron oxides [86,87]. The authors [88] also reported 480–600 nm and 720–820 nm as key spectral regions for the OC prediction model.

In the NIR region, the band found at 845 and 850 nm for organic carbon and clay and 1290 nm for sand can be related to the chromophorous components mainly hematite and goethite [89] and the OC content [90]. Furthermore, high correlation loading values were observed at 1592 and 1595 nm for clay and organic carbon content detection at 2293 and 2300 nm. This response could be due to clay, soil water content, and OM content [91,92]. In general, different wavelengths were discovered to be significant for the different soil properties.

As [93] indicated combining the optimum spectral bands was recommended for soil OC detection. The equation for the optimal band combination equations to predict soil OC with the highest R2 (0.92) and the lowest RMSE (0.27) was: For clay content, the best fit (R2 = 0.86, RMSE = 0.60) was: For sand, the best fit (R2 = 0.94, RMSE = 0.74) was: Based on the regression coefficients, the most influential wavelengths for OC, clay, and sand content prediction were λ850, λ1592, and λ1295 nm, respectively.

We plotted the measured soil properties (%) against the predicted soil properties (%) to validate the model (Fig 10). The simple regression analyses were used the pre-processed dataset (S2 Table) to test the accuracy of prediction of the soil properties. For clay content, the R2, bias, and RPDfor validation dataset were (0.93, 0.94, and 2.21, respectively (Fig 10), better than values reported by 0.70 [94], [95] (0.64), and 0.66 [96], and more accurately than values reported in the literature: R2 = 0.73 with RMSE = 5.40 [28], R2 = 0.83 with RMSE = 0.34 [97], R2 = 0.62 with RMSE = 2.06 [98], and R2 = 0.71–84 [99].

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Fig 10.

Scatterplots of the model validation results for soil organic carbon (a), clay content (b), and sand content (c). R2, coefficient of determination and RPD, ratio of performance to deviation.

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For sand content, we achieved R2 = 0.94 with RMSE = 0.74 for calibration and R2 = 0.85 with bias = 0.31 and RPD = 7.54 for validation (Fig 10). The sand model was considered excellent according to the R2, RPD threshold values [54] (Chang et al. (2001), acceptable bias levels [53] (Bellon-Maurel et al., 2010). Similar values were reported: R2 = 0.80 with RMSE = 3.28 [28], R2 = 0.81 with RMSE = 3.84 [26], R2 = 0.90 with RMSE = 11.66 [98], and R2 = 0.56 to 0.71 [99]. Our predictions of sand content were more accurate than in the literature: R2 = 0.76 with RMSE = 0.92 [97] and R2 = 0.77 [100]. This information could be used to develop and monitor soil management scenarios [26].

For soil OC, we achieved R2 = 0.92 with RMSE = 0.27 for calibration and R2 of 0.71 with bias = 0.12 and RPD = 8.13; bias = 0.12 for validation (Fig 10), which are considered good by R2 threshold values of [101], fair by the RPD threshold values [54] (Chang et al. (2001), and acceptable by bias values [53].

The OC model’s performance is similar to earlier findings: R2 = 0.84–0.93 [102], R2 = 0.63–0.90 with RMSE = 6.40–0.78 [103], R2 = 0.91 [104], R2 = 0.85 with RMSE = 3.77 [105], R2 = 0.57–0.7 [106], R2 = 0.77–0.83 [107,108]; and R2 = 0.764 with RMSE = 0.344 for validation [109,110]. However [111,112], found lower prediction performance (R2 values varying from 0.57 to 0.73 and RPD values ranging from 1.80 to 1.93) for soil OC models. In general, regression models based on Vis-NIR-SWIR reflectance spectroscopy could be used to predict soil properties in the study area.

Conclusions

Soil bunding in the Aba Gerima catchment, Ethiopia, positively influenced clay, silt, OC, and av. K contents of soils. Soil physicochemical properties (texture, OC, and av. P) varied widely between bunded and non-bunded plots in different slope classes. In contrast, soil pH and contents of clay, silt, sand, OC, av. P, and av. K were all higher in soils on lower slopes than on higher slopes. These findings suggest that site-specific information could inform land management interventions, such as soil bunding, for sustainable soil management. The reflectance of soils from bunded plots was lower, which improved soil fertility.

This study looked at how Vis-NIR-SWIR (350–2500 nm) soil spectral data could be used to determine some soil physical and chemical parameters. The use of regressive functions to estimate the calibrated soil attributes with their pretreatment spectral reflectance data was proposed due to high correlation loading and regression coefficients. Regression models were developed for predicting the clay, sand, and OC contents with acceptable accuracy (R2 > 0.70, RPD > 2, and bias values < 0).

Our findings suggest that Vis-NIR-SWIR reflectance spectroscopy might be utilized for soil characterization, evaluation, and monitoring in a quick and non-destructive manner. The findings have implications for spatial management and monitoring of soil physicochemical properties across the catchment. Soil prediction models based on spectroradiometry will help land-users and policymakers by contributing to the development of sustainable and site-specific soil management strategies.

As the tempo-spatial variation of soil properties between regions would influence the accuracy of the estimation model, caution should be vital before applying the models to other areas. Nonetheless, further research is required to identify which portions of the spectrum contribute to the models, improve the predictive capacity of Vis-NIR-SWIR spectroscopy, support land management interventions, and explore their effects on other soil parameters such as biological properties.

Supporting information

S1 Fig. Descriptive summary and Normality test of soil organic carbon (OC), total nitrogen (TN), and available phosphorus (av. P) in Aba Gerima catchment.

SE, standard error; SD, standard deviation; CV = coefficient of variation; min, minimum; max, maximum.

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(JPG)

S2 Fig. Descriptive summary and Normality test of soil pH, sand (%), silt (%), and clay (%) in Aba Gerima catchment.

SE, standard error; SD, standard deviation; CV = coefficient of variation; min, minimum; max, maximum.

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(JPG)

S3 Fig. Descriptive summary and Normality test of logOC (%), logTN (%), logav.P (ppm), and av.K (mg/Kg) in Aba Gerima catchment.

Log, logarithmically transformed; OC, organic carbon; TN, total nitrogen; av. K, available phosphorus; available potassium, min, minimum and max, maximum.

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(JPG)

S4 Fig. Soil textural classes in Aba Gerima catchment.

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(JPG)

S1 Table. Climatic data of Aba Gerima catchment.

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(XLSX)

S2 Table. Pre-processed soil spectral data for selected wavelengths of study catchment.

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(XLSX)

Acknowledgments

We thank Agerselam Gualie and Melkamu Wudu for their support during our field and laboratory work. The authors acknowledged the Japan International Cooperation Agency (JICA) for purchasing an ASD FieldSpec 4 spectroradiometer and the licensed Unscrambler software for the study. The authors also express their gratitude to the reviewers and editors for their insightful comments and recommendations.

References

  1. 1. Kassawmar T, Zeleke G, Bantider A, Gessesse GD, Abraha L. A synoptic land change assessment of Ethiopia’s Rain-fed Agricultural Area for evidence-based agricultural ecosystem management. Heliyon 2018; 4(11):e00914. pmid:30450439
  2. 2. Reichert JM, Pellegrini A, Rodrigues MF. Tobacco growth, yield and quality affected by soil constraints on steep lands. Ind Crops Prod. 2019a; 128:512–526. https://doi.org/10.1016/j.indcrop.2018.11.037.
  3. 3. Weiler DA, Moro VJ, Awe GO, da Silva Oliveira DM, Cerri CEP, Reichert JM, et al. Carbon Balance in Sugarcane Areas under Different Tillage Systems. Bioenerg Res. 2019; 12:778–788. https://doi.org/10.1007/s12155-019-10002-z.
  4. 4. Valente ML, Reichert JM, Legout C, Tiecher T, Cavalcante RBL, Evrard O. Quantification of sediment source contributions in two paired catchments of the Brazilian Pampa using conventional and alternative fingerprinting approaches. Hydrolo Process. 2020; 34(13):2965–2986. https://doi.org/10.1002/hyp.13768.
  5. 5. Ebling ÉD, Reichert JM, Peláez JJZ, Rodrigues MF, Valente ML, Cavalcante RBL, et al. Event-based hydrology and sedimentation in paired watersheds under commercial eucalyptus and grasslands in the Brazilian Pampa biome. Int Soil Water Conserv Res. 2021; 9(2):180–194. Reviews 2021; 81, 464–472. https://doi.org/10.1016/j.iswcr.2020.10.008.
  6. 6. Ebabu K, Tsunekawa A, Haregeweyn N, Adgo E, Meshesha DT, Aklog D, et al., Effects of land-use and sustainable land management practices on runoff and soil loss in the Upper Blue Nile basin, Ethiopia. Sci Total Environ. 2019; 648:1462–1475. pmid:30340291
  7. 7. Berihun ML, Tsunekawa A, Haregeweyn N, Dile YT, Tsubo M, Fenta AA, et al. Evaluating runoff and sediment responses to soil and water conservation practices by employing alternative modeling approaches. Sci Total Environ. 2020; 747:141118. pmid:32771781
  8. 8. Reichert JM, Fontanela E, Awe GO, Fasinmirin JT. Is cassava yield affected by inverting tillage, chiseling or additional compaction of no-till sandy-loam soil?. Bras Cienc Solo 2021a; 45:e0200134. 10.36783/18069657rbcs20200134.
  9. 9. Reichert JM, Corcini AL, Awe GO, Reinert DJ, Albuquerque JA, Gallarreta CCG, et al. Onion-forage cropping systems on a Vertic Argiudoll in Uruguay: Onion yield and soil organic matter, aggregation, porosity and permeability. Soil Tillage Res. 2022; 216:105229. https://doi.org/10.1016/j.still.2021.105229.
  10. 10. Asnake M, Heinimann A, Gete Z, Hurni H. Factors affecting the adoption of physical SWC practices in the Ethiopian highlands. Int Soil Water Conserv Res. 2018; 6(1): 23e30. https://doi.org/10.1016/j.iswcr.2017.12.006.
  11. 11. Van Beek CL, Elias E, Yihenew GS, Heesmans H, Tsegaye A, Feyisa H, et al. Soil nutrient balances under diverse agro-ecological settings in Ethiopia. Nutr Cycl Agroecosyst. 2016; 106(3):257–274. https://doi.org/10.1007/s10705-016-9803-0.
  12. 12. Wondwosen T, Sheleme B. Identification of growth limiting nutrient (s) in Alfisols: Soil physico-chemical properties, nutrient concentrations and biomass yield of maize. Am J of Plant Nutr and Fertilization Techn. 2011; 1:23–35. https://doi.org/10.3923/ajpnft.2011.23.35.
  13. 13. de Marins AC, Reichert JM, Secco D, Rosa HA, Veloso G. Crambe grain yield and oil content affected by spatial variability in soil physical properties. Renewable and Sustainable Energy Reviews. 2018 Jan 1; 81:464–72. https://doi.org.10.1016/j.rser.2017.08.003.
  14. 14. Bogunovic I, Trevisani S, Seput M, Juzbasic D, Durdevic B. Short-range and regional spatial variability of soil chemical properties in an agro-ecosystem in eastern Croatia. Catena 2017; 154:50–62. https://doi.org/10.1016/j.catena.2017.02.018.
  15. 15. Rosemary F, Indraratne SP, Weerasooriya R, Mishra U. Exploring the spatial variability of soil properties in an Alfisol soil catena. Catena 2017; 150: 53–61. https://doi.org/10.1016/j.catena.2016.10.017.
  16. 16. Karltun E, Lemenih M, Tolera M. Comparing farmers’ perception of soil fertility change with soil properties and crop performance in beseku, Ethiopia. Land Degrad Dev. 2013; 24(3): 228–235. https://doi.org/10.1002/ldr.1118.
  17. 17. Molla A. Farmers’ knowledge helps develop site-specific fertilizer rate recommendations, central highlands of Ethiopia. World Appl Sci J. 2013; 22(4): 555–563.https://doi.org/10.5829/idosi.wasj.2013.22.04.1196.
  18. 18. Laekemariam F, Kibret K, Mamo T, Karltun E, Gebrekidan H. Physiographic characteristics of agricultural lands and farmers’ soil fertility management practices in Wolaita zone, Southern Ethiopia. Environ Syst Res. 20165(1): 1–15. https://doi.org/10.1186/ss40068-016-0076-z.
  19. 19. Onweremadu EU. Assessment of mined soils in erosion-degraded farmlands in south- eastern Nigeria. Estudos de Biologia 2006; 28(65).
  20. 20. Chintala R, Mollinedo J, Schumacher TE, Malo DD, Julson JL. Effect of biochar on chemical properties of acidic soil. Arch Agron Soil Sci. 2014; 60(3):393–404. https://doi.org/10.1080/03650340.2013.789870.
  21. 21. Haregeweyn N, Tsunekawa A, Poesen J, Tsubo M, Meshesha DT, Fenta AA, et al. Comprehensive assessment of soil erosion risk for better land-use planning in river basins: case study of the Upper Blue Nile River. Sci Total Environ. 2017; 574:95–108. pmid:27623531
  22. 22. Woldesenbet TA, Elagib NA, Ribbe L, Heinrich J. Catchment response to climate and land-use changes in the Upper Blue Nile sub-basins. Ethiopia. Sci Total Environ. 2018; 644:193–206. pmid:29981519
  23. 23. Gholizadeh A, Borůvka L, Saberioon M and Vašát R. Visible, near-infrared, and mid-infrared spectroscopy applications for soil assessment with emphasis on soil organic matter content and quality: State-of-the-art and key issues. Appl Spectrosc. 2013; 67(12):1349–1362. pmid:24359647
  24. 24. Carmon N, Ben-Dor E. An advanced analytical approach for spectral-based modelling of soil properties. Int. J. Emerg. Technol. Adv Eng. 2017; 7:90–97. https://doi.org/10.1002/9781119043553.
  25. 25. Vašát R, Kodešová R, Borůvka L, Jakšík O, Klement A, Brodský L. Combining reflectance spectroscopy and the digital elevation model for soil oxidizable carbon estimation. Geoderma 2017; 303:133–142. https://doi.org/10.1016/j.geoderma.2017.05.018.
  26. 26. Tümsavaş Z, Tekin Y, Ulusoy Y. and Mouazen AM. Prediction and mapping of soil clay and sand contents using visible and near-infrared spectroscopy. Biosyst Eng. 2018; 1–11. https://doi.org/10.1016/j.biosystemseng.2018.06.008.
  27. 27. Morellos A, Pantazi XE, Moshou D, Alexandridis T, Whetton R, Tziotzios G, et al. Machine learning based prediction of soil total nitrogen, organic carbon, and moisture content by using Vis-NIR spectroscopy. Biosyst Eng. 2016. 152: 104–116. http://doi.org/10.1016/j.biosystemseng.2016.04.018.
  28. 28. Vasava HB, Gupta A, Arora R, Das BS. Assessment of soil texture from spectral reflectance data of bulk soil samples and their dry-sieved aggregate size fractions. Geoderma 2019; 337:914–926. https://doi.org/10.1016/j.geoderma.2018.11.004.
  29. 29. Goulart RZ, Reichert JM, Rodrigues MF, Neto MC, Ebling ED. Comparing tillage methods for growing lowland soybean and corn during wetter-than-normal cropping seasons. Paddy Water Environ. 2021; 1–15. https://doi.org/10.1007/s10333-021-30.00841-y.
  30. 30. Reichert JM, Gubiani PI, dos Santos DR, Reinert DJ, Aita C, Giacomini SJ. Soil properties characterization for land-use planning and soil management in watersheds under family farming. Int Soil Water Conserv Res. 2022; 10(1):119–28. https://doi.org/10.1016/j.iswcr.2021.05.003.
  31. 31. Bastos Lima MG. The Contested Sustainability of Biofuels in a North-South Context. The Politics of Bioeconomy and Sustainability Springer, Cham. 2021; 23–47. https://doi.org/10.1007/978-3-030-66838-92.
  32. 32. Volli C. Policies for sustainable land management in highlands of Ethiopia: W. Jemberu et al. Catena 157 (2017) 195–204 203 summary papers and proceedings of a seminar held at ILRI, Addis Ababa, Ethiopia. In: Socio-economics and Policy Research Working Paper 30. 2002.
  33. 33. Nyssen J, Poesen J, Gebremichael D, Vancampenhout K, D’aes M, Yihdego GM, et al. Interdisciplinary on-site evaluation of stone bunds to control soil erosion on crop land in Northern Ethiopia. Soil Tillage Res. 2007; 94 (1):151–163.
  34. 34. Amare T, Hergarten C, Hurni H, Wolfgramm B, Yitaferu B, Selassie YG. Prediction of soil organic carbon for Ethiopian highlands using soil spectroscopy. int sch res notices. 2013;2013. https://doi.org/10.1155/2013/720589.
  35. 35. Peel MC, Finlayson BL, McMahon TA. Updated world map of the Köppen-Geiger climate classification. Hydrology Earth Sys Sci Discussions 2007; 4:439–473.
  36. 36. NMSA (National Meteorological Survey Agency). 2004. Ethiopia, http://www.Ethiomet.gov.et/.
  37. 37. Ethiopian Mapping Agency (EMA), P.O.Box 597, Addis Abeba. http://www.ema.gov.et/ Accessed January 18, 2019.
  38. 38. Adimassu Z, Mekonnen K, Yirga C, Kessler A. Effect of soil bunds on runoff, soil and nutrient losses, and crop yield in the central highlands of Ethiopia. Land Degrad Dev. 2014; 25(6):554–564. http://doi.10.1002/ldr.2182.
  39. 39. Adimassu Z, Langan S, Barron J. Highlights of soil and water conservation investments in four regions of Ethiopia, Colombo, Sri Lanka: International Water Management Institute (IWMI). 35p. (IWMI Working Paper 182). 2018. http://doi.10.5337/2018.214.
  40. 40. Ministry of Agriculture (MoA). Soil and water conservation field manual. Addis Ababa, Ethiopia. 2001.
  41. 41. Bouyoucos GJ. Hydrometer method improved for making particle size analyses of soils. Agron J. 1962; 54:464–465. http://dx.doi.org/10.2134/agronj1962.000219620054000550028x.
  42. 42. USDA (United States Department of Agriculture). Soil survey laboratory methods manual. Soil Survey investigations Rep. 42, Ver.3.0. National Soil Survey Center, Lincoln, NE. 1996.
  43. 43. Rowell DL. Soil Science: Methods and Applications. Longman Singapore Publishers Ltd., Singapore, 1997; 350p.
  44. 44. Peech M. Hydrogen-ion activity. Amer Soc Agron. Madison, Wisconsin. 2016; 9: 914–926.
  45. 45. Walkley A, Black CA. An examination of the Degtijareff method for determining soil organic matter and a proposed modification of the chromic acid filtration method. Soil Sci. 1934; 37:93–101. https://doi.org/10.1097/00010694-193401000-00003.
  46. 46. Bray RH, Kurtz LT. Determination of total, organic, and available forms of phosphorus in soils. Soil Sci. 1945; 59(1):39–46. http://doi.10.1097/00010694-194501000–00006.
  47. 47. Murphy J, Riley JP. A modified single-solution method for the determination of phosphorus in natural waters. Anal Chim Acta 1962; 27:31–36. http://dx.doi.org/10.1016/S0003-2670(00)88444-5.
  48. 48. Morgan GH. Chemical diagnosis by the Universal Soil Testing System. Conn Agr Exp Sta (New Haven), Bull.450. USA. 1941; 573–628.
  49. 49. Dor EB, Ong C, Lau IC. Reflectance measurements of soils in the laboratory: Standards and protocols. Geoderma. 2015 May 1; 245:112–24. http://dx.doi.org/10.1016/j.geoderma.2015.01.002.
  50. 50. Xu S, Shi X, Wang M, Zhao Y. Effects of subsetting by parent materials on prediction of soil organic matter content in a hilly area using Vis–NIR spectroscopy. PLoS One. 2016 Mar 14;11(3):e0151536. pmid:26974821
  51. 51. Moriasi DN, Arnold JG, Van Liew MW, Bingner RL, Harmel RD, Veith TL. Model evaluation guidelines for systematic quantification of accuracy in watershed simulations. Trans ASABE 2007; 50(3):885–900.
  52. 52. McDowell ML, Bruland GL, Deenik JL, Grunwald S, Knox NM. Soil total carbon analysis in Hawaiian soils with visible, near-infrared and mid-infrared diffuse reflectance spectroscopy. Geoderma. 2012 Nov 1; 189:312–20. https://doi.org/10.1016/j.geoderma.2012.06.009.
  53. 53. Bellon-Maurel V, Fernandez-Ahumada E, Palagos B, Roger JM, McBratney A. Critical review of chemometric indicators commonly used for assessing the quality of the prediction of soil attributes by NIR spectroscopy. TrAC Trends in Analytical Chemistry. 2010 Oct 1; 29(9):1073–81. https://doi.org/10.1016/j.trac.2010.05.006.
  54. 54. Chang CW, Laird DA, Mausbach MJ, Hurburgh CR. Near‐infrared reflectance spectroscopy–principal components regression analyses of soil properties. Soil Science Society of America Journal. 2001 Mar; 65(2):480–90.
  55. 55. Warrick AW. Spatial variability. Environmental soil physics, Hillel D., Ed., Academic Press, Cambridge, MA, USA. 1998; 655–675.
  56. 56. Fenta AA, Yasuda H, Shimizu K, Haregeweyn N, Negussie A. Dynamics of soil erosion as influenced by watershed management practices: a case study of the Agula watershed in the semi-arid highlands of northern Ethiopia. Environ Manag. 2016; 58(5): 889–905. pmid:27605225
  57. 57. Ramos C, Costa PA, Rudnicki T, Marôco AL, Leal I, Guimarães R, et al. The effectiveness of a group intervention to facilitate posttraumatic growth among women with breast cancer. Psycho-Oncol. 2018; 27(1):258–264. pmid:28743174
  58. 58. Emadi M, Baghernejad M, Maftoun M. Assessment of some soil properties by spatial variability in saline and sodic soils in Arsanjan plain, Southern Iran. Pakistan journal of biological sciences: PJBS 2008; 11(2):238–243. pmid:18817196
  59. 59. Sugiyono. Metode Penelitian Kuantitatif Kualitatif dan R&D. Bandung: Alfabeta. 2013.
  60. 60. Takala B. Ameliorative Effects of Coffee Husk Compost and Lime Amendment on Acidic Soil of Haru, Western Ethiopia. Journal Soil Water Science 2020; 4(1):141–150.
  61. 61. Hassania El EH, Mohamed El B. Characterizing spatial variability of some soil properties in Beni-Moussa irrigated perimeter from Tadla plain (Morocco) using geostatistics and kriging techniques. J Sediment Environ. 2021; 6(3):381–394. https://doi.org/10.1007/s43217-021-00050-x.
  62. 62. Yin X, Zhao L, Fang Q, Ding G. Differences in Soil Physicochemical Properties in Different-Aged Pinus massoniana Plantations in Southwest China. Forests; 2021; 12(8):987. https://doi.org/10.3390/f12080987.
  63. 63. Yadda TA, Zebire DA. Effects of different land-use managements on soil Fertility status in Rift Valley Areas of Gamo-Konso Massifs, Ethiopia. J Appl Sci Environ. 2019; 23(8):1557–1565.
  64. 64. EthioSIS (Ethiopia Soil Information System). Soil fertility status and fertilizer recommendation atlas for Tigray regional state, Ethiopia. July 2014, Addis Ababa, Ethiopia. 2014.
  65. 65. Tellen VA, Yerima BP. Effects of land-use change on soil physicochemical properties in selected areas in the North West region of Cameroon. Environ. Syst Res. 2018; 7, 3. https://doi.org/10.1186/s40068-018-0106-0.
  66. 66. Osman EAM, El-Masry AA, Khatab KA. Effect of nitrogen fertilizer sources and foliar spray of humic and/or fulvic acids on yield and quality of rice plants. Adv Appl Sci Res. 2013; 4(4): 174–183.
  67. 67. Reichert JM, Norton LD. Rill and interrill erodibility and sediment characteristics of clayey Australian Vertosols and a Ferrosol. Soil Res. 2013; 51(1):1–9. https://doi.org/10.1071/SR12243.
  68. 68. Dagnachew M, Moges A, Kebede A, Abebe A. Effects of soil and water conservation measures on soil quality indicators”: the case of Geshy subcatchment, Gojeb river catchment, Ethiopia. Appl Environ Soil Sci. 2020; 2020:16. https://doi.org/10.1155/20201868792.
  69. 69. Guadie M, Molla E, Mekonnen M, Cerd`a A. Effects of soil bund and stone-faced soil bund on soil physicochemical properties and crop yield under rain-fed conditions of northwest Ethiopia. Land 2020; 9(1):13, 2020. https://doi.org/10.3390/land9010013.
  70. 70. Hadaro M, Ayele T, Parshotam Datt S, Teshome R. Soil Properties as Affected by Soil Conservation Practices and Soil Depths in Uwite Watershed, Hadero Tunto District, Southern Ethiopia. Appl Environ Soil Sci. 2021; 2021:1–13. https://doi.org/10.1155/2021/5542326.
  71. 71. Iticha B, Takele C. Digital soil mapping for site-specific management of soils. Geoderma 2019; 351:85–91. https://doi.org/10.1016/j.geoderma.2019.05.026.
  72. 72. Tiruneh GA, Alemayehu TY, Meshesha DT, Vogelmann ES, Reichert JM, Haregeweyn N. 2021. Spatial variability of soil chemical properties under different land-uses in Northwest Ethiopia. PloS ONE 16(6): e0253156. pmid:34161393
  73. 73. Belayneh M, Yirgu T, Tsegaye D. Effects of soil and water conservation practices on soil physicochemical properties in Gumara watershed, Upper Blue Nile Basin, Ethiopia. Ecol Process 2019; 8(1):1–14. https://doi.org/10.1186/s13717-019-0188-2.
  74. 74. Awe GO, Reichert JM, Holthusen D, Ambus JV, de Faccio Carvalho PC. Characterization of microstructural stability of biochar-amended Planosol under conventional tillage for irrigated lowland rice ecosystem. Soil Tillage Res. 2021; 212:105051. https://doi.org/10.1016/j.still.2021.105051.
  75. 75. Ben-Dor E, Chabrillat S, Demattê JA, Taylor GR, Hill J, Whiting ML, Sommer S. Using imaging spectroscopy to study soil properties. Remote Sens Environ. 2009; 1; 113: S38–55. https://doi.org/10.1016/j.rse.2008.09.019.
  76. 76. Conforti M, Froio R, Matteucci G, Buttafuoco G. Visible and near-infrared spectroscopy for predicting texture in forest soil: an application in southern Italy. iForest-Biogeosciences and Forestry 2015; 8(3):339. https://doi.org/10.3832/ifor1221-007.
  77. 77. Mitran T, Ravisankar T, Fyzee MA, Suresh JR, Sujatha G, Sreenivas K. Retrieval of soil physicochemical properties towards assessing salt-affected soils using Hyperspectral Data. Geocarto Int. 2015; 30(6):701–721. https://doi.org/10.1080/10106049.2014.985745.
  78. 78. Hong Y, Chen S, Zhang Y, Chen Y, Yu L, Liu Y, et al. Rapid identification of soil organic matter level via visible & near-infrared spectroscopy: Effects of two-dimensional correlation coefficient and extreme learning machine. Sci Total Environ. 2018; 644:1232–1243. pmid:30743836
  79. 79. Yu F, Hunt AG. Predicting soil formation on the basis of transport-limited chemical weathering. Geomorphology 2018; 301:21–27. https://doi.org/10.1016/j.geomorph.2017.10.027.
  80. 80. Demattê JA, da Silva Terra F. Spectral pedology: a new perspective on evaluation of soils along pedogenetic alterations. Geoderma 2014; 217:190–200. https://doi.org/10.1016/j.geoderma.2013.11.012.
  81. 81. Liu HJ, Wu BF, Zhao CJ, Zhao YS. Effect of spectral resolution on black soil organic matter content predicting model based on laboratory reflectance. Spectrosc Spect Anal. 2012; 32(3): 739–742. https://doi.org/10.3964/j.issn.1000-0593(2012)03-0739-04. pmid:22582644
  82. 82. Rossel RV, Walvoort DJJ, McBratney AB, Janik LJ, Skjemstad JO. Visible, near-infrared, mid-infrared or combined diffuse reflectance spectroscopy for simultaneous assessment of various soil properties. Geoderma 2006; 131(1–2): 59–75.
  83. 83. Coleman TL, Montgomery OL. Soil moisture, organic matter, and iron content effect on the spectral characteristics of selected Vertisols and Alfisols in Alabama. Photogramm Eng Remote Sens. 1987; 53(12):1659–1663.
  84. 84. Weidong L, Baret F, Xingfa G, Qingxi T, Lanfen Z, Bing Z. Relating soil surface moisture to reflectance. Remote Sens Environ. 2002; 81(2–3): 238–246. https://doi.org/10.1016/S0034-4257(01)00347-9.
  85. 85. Palacios-Orueta A, Ustin SL. Remote sensing of soil properties in the Santa Monica Mountains I. Spectral analysis. Remote Sens Environ. 1998; 65(2):170–183.
  86. 86. Ben-Dor E, Chabrillat S, Demattê JA, Taylor GR, Hill J, Whiting ML, et al. Using imaging spectroscopy to study soil properties. Remote sensing of environment. 2009 Sep 1;113:S38–55. https://doi.org/10.1016/j.rse.2008.09.019.
  87. 87. Rossel RV, Behrens T. Using data mining to model and interpret soil diffuse reflectance spectra. Geoderma. 2010 Aug 15; 158(1–2):46–54. https://doi.org/10.1016/j.geoderma.2009.12.025.
  88. 88. Nanni MR, Demattê JA. Spectral reflectance methodology in comparison to traditional soil analysis. Soil science society of America journal. 2006 Mar; 70(2): 393–407. https://doi.org/10.2136/sssaj2003.0285.
  89. 89. Sherman DM, Waite TD. Electronic spectra of Fe3+ oxides and oxide hydroxides in the near IR to near UV. American Mineralogist. 1985 Dec 1;70(11–12):1262–9.
  90. 90. Ben-Dor E, Irons JR, Epema GF. Soil reflectance. Remote sensing for the earth sciences: Manual of remote sensing. 1999; 3(3).
  91. 91. Nocita M, Stevens A, Toth G, Panagos P, van Wesemael B, Montanarella L. Prediction of soil organic carbon content by diffuse reflectance spectroscopy using a local partial least square regression approach. Soil Biology and Biochemistry. 2014 Jan 1; 68:337–47. https://doi.org/10.1016/j.soilbio.2013.10.022.
  92. 92. Hong Y, Chen Y, Zhang Y, Liu Y, Liu Y, Yu L, et al. Transferability of Vis‐NIR models for soil organic carbon estimation between two study areas by using spiking. Soil Science Society of America Journal. 2018 Sep;82(5):1231–42. https://doi.org/10.2136/sssaj2018.03.0099.
  93. 93. Hong Y, Guo L, Chen S, Linderman M, Mouazen AM, Yu L, et al. Exploring the potential of airborne hyperspectral image for estimating topsoil organic carbon: Effects of fractional-order derivative and optimal band combination algorithm. Geoderma. 2020 Apr 15; 365: 114228. https://doi.org/10.1016/j.geoderma.2020.114228.
  94. 94. Camargo LA, Júnior JM, Barrón V, Alleoni LRF, Barbosa RS, Pereira GT. Mapping of clay, iron oxide and adsorbed phosphate in Oxisols using diffuse reflectance spectroscopy. Geoderma 2015; 251:124–132. https://doi.org/10.1016/j.geoderma.2015.03.03.027.
  95. 95. Zhang C, Jiang H, Liu F, He Y. Application of Near-Infrared Hyperspectral Imaging with Variable Selection Methods to Determine and Visualize Caffeine Content of Coffee Beans. Food Bioprocess Technol. 2017; 10: 213–221. https://doi.org/10.1007/s11947-016-809-8.
  96. 96. Silva IM, Romero DJ, Guimarães CCB, Alves MR, Osco LP, Souza ABE, et al. Readily dispersible clay in soils from different Brazilian regions by visible, near, and mid-infrared spectral data. Int J Remote Sens. 2021; 42(18): 6943–6960. https://doi.org/10.1080/01431161.2021.1948625.
  97. 97. Yang M, Mouazen A, Zhao X, Guo X. Assessment of a soil fertility index using visible and near‐infrared spectroscopy in the rice paddy region of southern China. Eur J Soil Sci. 2020; 71(4): 615–626. https://doi.org/10.1111/ejss.12907.
  98. 98. Haghi RK, Pérez-Fernández E, Robertson AHJ. Prediction of various soil properties for a national spatial dataset of Scottish soils based on four different chemometric approaches: A comparison of near-infrared and mid-infrared spectroscopy. Geoderma 2021; 396:115071. https://doi.org/10.1016/j.geoderma.2021.115071.
  99. 99. Zhao D, Arshad M, Li N, Triantafilis J. Predicting soil physical and chemical properties using Vis-NIR in Australian cotton areas. Catena 2021; 196:104938. https://doi.org/10.1016/j.catena.2020.104938.
  100. 100. Rodríguez-Pérez JR, Marcelo V, Pereira-Obaya D, García-Fernández M, Sanz-Ablanedo E. Estimating Soil Properties and Nutrients by Visible and Infrared Diffuse Reflectance Spectroscopy to Characterize Vineyards. Agronomy 2021; 11(10):1895. https://doi.org/10.3390/agronomy11101895.
  101. 101. Saeys W, Mouazen AM, Ramon H. Potential for onsite and online analysis of pig manure using visible and near-infrared reflectance spectroscopy. Biosyst Eng. 2005; 91(4):393–402.
  102. 102. Leone AP A Viscarra-Rossel R, Amenta P, Buondonno A. Prediction of soil properties with PLSR and Vis-NIR spectroscopy: Application to Mediterranean soils from Southern Italy. Curr Anal Chem. 2012; 8(2):283–299.
  103. 103. Kuang B, Mouazen AM. Influence of the number of samples on prediction error of visible and near-infrared spectroscopy of selected soil properties at the farm scale. Eur J Soil Sci. 2012; 63(3):421–429. https://doi.org/10.1111/j.1365-2389.2012.01456.X.
  104. 104. Yang H, Kuang B, Mouazen AM. Quantitative analysis of soil nitrogen and carbon at a farm scale using visible and near-infrared spectroscopy coupled with wavelength reduction. Eur J Soil Sci. 2012; 63(3):410–420. https://doi.org/10.1111/j.1365-2389.2012.01443.x.
  105. 105. Amin I, Fikrat F, Mammadov E, Babayev M. Soil organic carbon prediction by Vis-NIR spectroscopy: Case study the Kur-Aras Plain, Azerbaijan. Commun in Soil Sci Plant Anal. 2020; 51(6):726–734. https://doi.org/10.1080/00103624.2020.1729367.
  106. 106. Gomez C, Le Bissonnais Y, Annabi M, Bahri H, Raclot D. Laboratory Vis–NIR spectroscopy as an alternative method for estimating the soil aggregate stability indexes of Mediterranean soils. Geoderma 2013; 209: 86–97. https://doi.org//10.1016/j.geoderma.013.06.002.
  107. 107. Gras JP, Barthès BG, Mahaut B, Trupin S. Best practices for obtaining and processing field visible and near-infrared (VNIR) spectra of topsoils. Geoderma 2014; 214:126–134. https://doi.org/10.1016/j.geoderma.2013.09.021.
  108. 108. Wijevardane N, Ge Y, Wills S, Loecke T. Prediction of soil carbon in the conterminous united states: visible and near-infrared reflectance spectroscopy analysis of the rapid carbon assessment project. Soil Sci Soc Am J. 2016; 80(4):973–982. https://doi.org/10.2136/sssaj2016.02.0052.
  109. 109. Luce MS, Ziadi N, Zebarth BJ, Grant CA, Tremblay GF, Gregorich EG. Rapid determination of soil organic matter quality indicators using visible near-infrared reflectance spectroscopy. Geoderma 2014; 232:449–458. https://doi.org/10.1016/j.geoderma2014.05.023.
  110. 110. Feyziyev F, Babayev M, Priori S, L’Abate G. Using visible-near-infrared spectroscopy to predict soil properties of mugan plain, Azerbaijan. Open J Soil Sci. 2016; 6 (03):52–58. https://doi.org/10.4236/ojss.2016.63006.
  111. 111. Summers D, Lewis M, Ostendorf B, Chittleborough D. Visible near-infrared reflectance spectroscopy as a predictive indicator of soil properties. Ecological Indicators. 2011 Jan 1;11(1):123–31. https://doi.org/10.1016/j.ecolind.2009.05.001.
  112. 112. Gomez C, Le Bissonnais Y, Annabi M, Bahri H, Raclot D. Laboratory Vis–NIR spectroscopy as an alternative method for estimating the soil aggregate stability indexes of Mediterranean soils. Geoderma. 2013 Nov 1; 209: 86–97.