From superphanes to beltenes

Rolf Gleiter; Björn Hellbach; Silke Gath; Rolf J. Schaller

doi:10.1351/pac200678040699

Publicly Available Published by De Gruyter January 1, 2009

From superphanes to beltenes

Rolf Gleiter , Björn Hellbach , Silke Gath and Rolf J. Schaller

From the journal Pure and Applied Chemistry

https://doi.org/10.1351/pac200678040699

This short review describes paths to superphanes with metal-stabilized cyclobutadiene and cyclopentadienone rings in a one-pot and stepwise fashion. The stepwise synthesis also led to a new class of belt-like systems with large rings composed of CpCo-stabilized cyclobutadiene rings connected with propane chains. Finally, our research yielded the first beltenes composed of alternating four- and eight-membered conjugated rings.

Keywords: beltenes; cobalt; cyclacenes; cyclobutadiene; superphanes

Conference

International Symposium on Novel Aromatic Compounds (ISNA-11), International Symposium on Novel Aromatic Compounds, ISNA, Novel Aromatic Compounds, 11th, St. John's, Newfoundland, Canada, 2005-08-14–2005-08-18

Online erschienen: 2009-1-1

Erschienen im Druck: 2006-1-1

From superphanes to beltenes

Conference

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