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Publicly Available Published by De Gruyter January 1, 2009

Catalytic activation of nitrogen derivatives with transition-metal complexes

  • Hélène Lebel , Olivier Leogane , Kim Huard and Sylvain Lectard
From the journal Pure and Applied Chemistry
https://doi.org/10.1351/pac200678020363
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Abstract

Studies regarding the transition-metal-catalyzed decomposition of nitrogen derivatives toward Curtius rearrangement and the formation of nitrenes which undergo C-H insertion and aziridination reactions are presented. These processes lead to the formation of C-N bond with a high level of selectivity and efficiency.

Keywords: aziridination; C–H insertion; Curtius rearrangement; nitrene; rhodium

Conference

IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-13), International Symposium on Organometallic Chemistry Directed Toward Organic Synthesis, OMCOS, Organometallic Chemistry Directed Toward Organic Synthesis, 13th, Geneva, Switzerland, 2005-07-17–2005-07-21

Published Online: 2009-01-01
Published in Print: 2006-01-01

© 2013 Walter de Gruyter GmbH, Berlin/Boston

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From the journal
Pure and Applied Chemistry
Pure and Applied Chemistry
Volume 78 Issue 2
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Journal and Issue

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Foreword
Preface
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