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Publicly Available Published by De Gruyter January 1, 2009

Cation-dependent photochromic properties of novel ditopic receptors

  • O. A. Fedorova , Y. V. Fedorov , E. N. Andrjukhina , S. P. Gromov and M. V. Alfimov

Novel crown-containing 2-styrylbenzothiazoles were prepared to obtain optical ditopic receptors that can bind alkaline-earth metal cations by a crown ether fragment and could serve as host for the heavy metal cations and proton owing to the presence of the heterocyclic part. Photochemical transformations of the ditopic receptors depend on the type of metal cations present in solution. They include trans–cis-isomerization, [2+2]-cycloaddition, and electrocyclic reaction.


Conference

IUPAC Symposium on Photochemistry, International Symposium on Photochemistry, PHOTO, Photochemistry, XIXth, Budapest, Hungary, 2002-07-14–2002-07-19


Online erschienen: 2009-1-1
Erschienen im Druck: 2003-1-1

© 2013 Walter de Gruyter GmbH, Berlin/Boston

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