Abstract
Fabricating well-defined and stable nanoparticle crystals in a controlled fashion receives growing attention in nanotechnology. The order and packing symmetry within a nanoparticle crystal is of utmost importance for the development of materials with unique optical and electronic properties. To generate stable and ordered 3D nanoparticle structures, nanotechnology is combined with supramolecular chemistry to control the self-assembly of 2D and 3D receptor-functionalized nanoparticles. This review focuses on the use of molecular recognition chemistry to establish stable, ordered, and functional nanoparticle structures. The host–guest complexation of β-cyclodextrin (CD) and its guest molecules (e.g., adamantane and ferrocene) are applied to assist the nanoparticle assembly. Direct adsorption of supramolecular guest- and host-functionalized nanoparticles onto (patterned) CD self-assembled monolayers (SAMs) occurs via multivalent host–guest interactions and layer-by-layer (LbL) assembly. The reversibility and fine-tuning of the nanoparticle-surface binding strength in this supramolecular assembly scheme are the control parameters in the process. Furthermore, the supramolecular nanoparticle assembly has been integrated with top-down nanofabrication schemes to generate stable and ordered 3D nanoparticle structures, with controlled geometries and sizes, on surfaces, other interfaces, and as free-standing structures.
References
1 10.1021/la062084g, R. Vendamme, T. Ohzono, A. Nakao, M. Shimomura, T. Kunitake. Langmuir23, 2792 (2007).Search in Google Scholar
2 10.1021/cm061759y, C. H. Lu, I. Donch, M. Nolte, A. Fery. Chem. Mater.18, 6204 (2006).Search in Google Scholar
3 10.1038/nmat1212, C. Y. Jiang, S. Markutsya, Y. Pikus, V. V. Tsukruk. Nat. Mater.3, 721 (2004).Search in Google Scholar
4 10.1021/ac010118d, Y. Lvov, F. Caruso. Anal. Chem.73, 4212 (2001).Search in Google Scholar
5 10.1002/adma.200502444, C. Y. Jiang, V. V. Tsukruk. Adv. Mater.18, 829 (2006).Search in Google Scholar
6 10.1038/361026a0, N. D. Denkov, O. D. Velev, P. A. Kralchevsky, I. B. Ivanov, H. Yoshimura, K. Nagayama. Nature361, 26 (1993).Search in Google Scholar
7 10.1002/1616-3028(200104)11:2<95::AID-ADFM95>3.0.CO;2-O, G. A. Ozin, S. M. Yang. Adv. Funct. Mater.11, 95 (2001).Search in Google Scholar
8 10.1126/science.281.5378.802, J. Wijnhoven, W. L. Vos. Science281, 802 (1998).Search in Google Scholar
9 10.1016/S0022-0728(00)00053-X, M. Lahav, A. N. Shipway, I. Willner, M. B. Nielsen, J. F. Stoddart. J. Electroanal. Chem.482, 217 (2000).Search in Google Scholar
10 10.1002/1521-4095(20020517)14:10<722::AID-ADMA722>3.0.CO;2-T, V. Paraschiv, S. Zapotoczny, M. R. de Jong, G. J. Vancso, J. Huskens, D. N. Reinhoudt. Adv. Mater.14, 722 (2002).Search in Google Scholar
11 10.1126/science.277.5330.1232, G. Decher. Science277, 1232 (1997).Search in Google Scholar
12 10.1021/ja051093t, O. Crespo-Biel, B. Dordi, D. N. Reinhoudt, J. Huskens. J. Am. Chem. Soc.127, 7594 (2005).Search in Google Scholar PubMed
13 10.1021/la051387s, R. Zirbs, F. Kienberger, P. Hinterdorfer, W. H. Binder. Langmuir21, 8414 (2005).Search in Google Scholar PubMed
14 10.1021/jp0443308, J. I. Park, W. R. Lee, S. S. Bae, Y. J. Kim, K. H. Yoo, J. Cheon, S. Kim. J. Phys. Chem. B109, 13119 (2005).Search in Google Scholar PubMed
15 10.1038/nmat1532, M. A. Meitl, Z. T. Zhu, V. Kumar, K. J. Lee, X. Feng, Y. Y. Huang, I. Adesida, R. G. Nuzzo, J. A. Rogers. Nat. Mater.5, 33 (2006).Search in Google Scholar
16 10.1002/adma.200501072, P. Maury, M. Escalante, D. N. Reinhoudt, J. Huskens. Adv. Mater.17, 2718 (2005).Search in Google Scholar
17 10.1021/ja011048v, Y. Yin, Y. Lu, B. Gates, Y. Xia. J. Am. Chem. Soc.123, 8718 (2001).Search in Google Scholar PubMed
18 10.1021/la0610497, X. Y. Ling, D. N. Reinhoudt, J. Huskens. Langmuir22, 8777 (2006).Search in Google Scholar PubMed
19 10.1021/la047982w, V. Mahalingam, S. Onclin, M. Peter, B. J. Ravoo, J. Huskens, D. N. Reinhoudt. Langmuir20, 11756 (2004).Search in Google Scholar PubMed
20 10.1021/la701671s, X. Y. Ling, L. Malaquin, D. N. Reinhoudt, H. Wolf, J. Huskens. Langmuir23, 9990 (2007).Search in Google Scholar PubMed
21 10.1016/j.cbpa.2006.09.007, J. Huskens. Curr. Opin. Chem. Biol.10, 537 (2006).Search in Google Scholar PubMed
22 10.3390/ijms9040486, X. Y. Ling, I. Y. Phang, D. N. Reinhoudt, G. J. Vancso, J. Huskens. Int. J. Mol. Sci.9, 486 (2008).Search in Google Scholar PubMed PubMed Central
23 X. Y. Ling, D. N. Reinhoudt, J. Huskens. “Chemically directed self-assembly of nanoparticle structures on surfaces”, In Supramolecular Chemistry of Organic-Inorganic Hybrid Materials, K. Rurack (Ed.), Wiley, Weinheim (2009).10.1002/9780470552704.ch13Search in Google Scholar
24 10.1039/b600093m, M. J. W. Ludden, D. N. Reinhoudt, J. Huskens. Chem. Soc. Rev.35, 1122 (2006).Search in Google Scholar PubMed
25 10.1021/cm703597w, X. Y. Ling, D. N. Reinhoudt, J. Huskens. Chem. Mater.20, 3574 (2008).Search in Google Scholar
26 H. Xu, X. Y. Ling, J. van Bennekom, X. Duan, M. Ludden, D. N. Reinhoudt, M. Wessling, R. Lammertink, J. Huskens. J. Am. Chem. Soc.131, 793 (2009).Search in Google Scholar
27 10.1088/0957-4484/18/4/044007, P. Maury, M. Péter, O. Crespo-Biel, X. Y. Ling, D. N. Reinhoudt, J. Huskens. Nanotechnology18, 044007 (2007).Search in Google Scholar
28 10.1002/anie.200804596, X. Y. Ling, I. Y. Phang, W. Maijenburg, H. Schönherr, D. N. Reinhoudt, G. J. Vancso, J. Huskens. Angew. Chem., Int. Ed.48, 983 (2009).Search in Google Scholar PubMed
29 10.1021/am900071y, X. Y. Ling, I. Y. Phang, D. N. Reinhoudt, G. J. Vancso, J. Huskens. ACS Appl. Mater. Interf.1, 960 (2009).Search in Google Scholar PubMed
30 10.1002/smll.200900068, X. Y. Ling, I. Y. Phang, H. Schönherr, D. N. Reinhoudt, G. J. Vancso, J. Huskens. Small5, 1428 (2009).Search in Google Scholar PubMed
31 10.1039/b822156a, X. Y. Ling, I. Y. Phang, D. N. Reinhoudt, G. J. Vancso, J. Huskens. Faraday Discuss.143, 117 (2009).Search in Google Scholar PubMed
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