Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Thermal Reactions of Clavulones Leading to a Novel Prostanoid with a 10-Acetoxy-11-ene Structure
Kazuo IGUCHI, Soichiro KANETA, Yasuji YAMADA
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Keywords: marine prostanoid, clavulone, thermal reaction, [3, 3]-sigmatropic rearrangement, exciton chirality rule, CD
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1992 Volume 40 Issue 7 Pages 1923-1924

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Abstract

Thermal reactions of clavulones, I, II, and III gave a novel prostanoid with a 10-acetoxy-11-ene system through a [3, 3]-sigmatropic rearrangement of allylic acetate.

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