1985 Volume 33 Issue 11 Pages 4671-4679
Reactions of aromatic and aliphatic hydrocarbons with a new reagent system, Fe (CH3CN)2+6-H2O2-Ac2O in CH3CN, gave oxygenation products with fairly high reaction efficiency (Tables I and II) compared to known reagent systems used as enzyme models for mono-oxygenases. Investigations of the mechanism of these reactions indicated the involvement of either complex C, FeIV (OH) (OAc)2+, or complex D, FeIV (OAc)2+2, depending on the organic substrate.