石油及沉积有机质中C<sub>1</sub>-和C<sub>2</sub>-烷基二苯并噻吩鉴定及分布

师生宝; 李美俊; 朱雷

doi:10.11781/sysydz201405612

石油及沉积有机质中C₁-和C₂-烷基二苯并噻吩鉴定及分布

doi: 10.11781/sysydz201405612

师生宝^1,2,
李美俊^1,2,
朱雷^1,2

1.
中国石油大学油气资源与探测国家重点实验室, 北京 102249
2. 中国石油大学地球科学学院, 北京 102249

基金项目: 国家自然科学基金(41272158)和中国石油大学(北京)科研基金项目(KYJJ2012-01-03，KYJJ2012-01-23)资助。

详细信息

作者简介:
师生宝(1979-)，男，工程师，从事有机地球化学实验及科研工作。E-mail：shengbao@cup.edu.cn。

中图分类号: TE122.1⁺13
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- 被引次数: 0
出版历程
- 收稿日期: 2013-03-29
- 修回日期: 2014-03-28
- 刊出日期: 2014-09-28

Identification and distribution of C₁-and C₂-alkylated dibenzothiophenes in petroleum and sedimentary organic matter

1.
State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum, Beijing 102249, China
2. College of Geosciences, China University of Petroleum, Beijing 102249, China

摘要

摘要: 根据标样共注实验、保留指数对比、结合化合物结构及性质，对石油和沉积有机质中二苯并噻吩类含硫多环芳烃化合物的C₁-和C₂-烷基取代的二苯并噻吩化合物进行了鉴定，确定了其在HP-5MS色谱柱上的保留指数。研究结果纠正了多个前人鉴定有误的异构体，完整、系统地确定了4个C₁-和14个C₂-烷基取代二苯并噻吩系列化合物的保留指数和色谱质谱出峰顺序，初步探讨了石油及沉积有机质中烷基二苯并噻吩化合物的分布特征。
- 二苯并噻吩 /
- 标样 /
- 保留指数 /
- 色谱质谱 /
- 沉积有机质
Abstract: Based on internal standards co-elution, retention indices comparison and molecular structure and chemical properties, a series of C₁-and C₂-alkylated dibenzothiophene isomers in oils and related sedimentary organic matters were firmly identified in this paper. The corresponding retention indices were also determined. This study corrected several compound peaks on mass chromatograms which were wrongly identified in previous publications. The elution order of all C₁ and C₂-dibenzothiophene isomers on GC column (HP-5MS) was systematically determined, and the distribution patterns of C₁-and C₂-alkylated dibenzothiophenes in petroleum and sedimentary organic matters were preliminarily discussed.
- dibenzothiophene /
- internal standard /
- retention index /
- GC-MS /
- sedimentary organic matter

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参考文献(25)

[1]	Ho T Y,Rogers M A,Drushel H V,et al.Evolution of sulfur compounds in crude oils[J].AAPG Bulletin,1974,58(11):2338-2348.
[2]	Hughes W B.Use of thiophenic organosulfur compounds in cha-racterizing crude oils derived from carbonate versus siliclastic sources[M]//Palacas J B,ed. Petroleum geochemistry and source rock potential of carbonate rocks,AAPG studies in geology. Oklahoma:AAPG Press,1984:181-196.
[3]	Hughes W B,Holba A G,Dzou L I P.The ratios of dibenzothiophene to phenanthrene and pristane to phytane as indicators of depositional environment and lithology of petroleum source rocks[J].Geochimica et Cosmochimica Acta,1995,59(17):3581-3598.
[4]	包建平,王铁冠,陈发景,等.烃源岩中烷基二苯并噻吩组成及其地球化学意义[J].石油大学学报:自然科学版,1996,20(1):19-23. Bao Jianping,Wang Tieguan,Chen Fajing,et al.Relative abundance of alkyl dibenzothiophene in the source rocks and their geochemical significances[J].Journal of the University of Petroleum China,1996,20(1):19-23.
[5]	Shen Ping,Wang Wanchun,Zhang Xiaobao,et al.Differentiating depositional environments and maturity of crude oils using GC-AED benzothiophenic spectra[J].Science in China:Series D:Earth Sciences,1998,41(4):401-407.
[6]	Huang Haiping,Pearson M J.Source rock palaeoenvironments and controls on the distribution of dibenzothiophenes in lacustrine crude oils,Bohai Bay Basin,eastern China[J].Organic Geochemistry,1999,30(11):1455-1470.
[7]	Chakhmakhchev A,Suzuki M,Takayama K,et al.Distribution of alkylated dibenzothiophenes in petroleum as a tool for maturity assessments[J].Organic Geochemistry,1997,26(7-8):483-489.
[8]	张敏,张俊.塔里木盆地原油噻吩类化合物的组成特征及地球化学意义[J].沉积学报,1999,17(1):121-126. Zhang Min,Zhang Jun.Composition characteristics and geochemical significance of thiophene-type compounds for crude oils in Tarim Basin[J].Acta Sedimentologica Sinica,1999,17(1):121-126.
[9]	李景贵.海相碳酸盐岩二苯并噻吩类化合物成熟度参数研究进展与展望[J].沉积学报,2000,18(3):480-483. Li Jinggui.Research development and prospect of maturity parameters of methylated dibenzothiophenes in marine carbonate rocks[J].Acta Sedimentologica Sinica,2000,18(3):480-483.
[10]	魏志彬,张大江,张传禄,等.甲基二苯并噻吩分布指数(MDBI)作为烃源岩成熟度标尺的探讨[J].地球化学,2001,30(3):242-247. Wei Zhibin,Zhang Dajiang,Zhang Chuanlu,et al.Methyldibenzothiophenes distribution index as a tool for maturity assessments of source rocks[J].Geochimica,2001,30(3):242-247.
[11]	罗建,程克明,付立新,等.烷基二苯并噻吩:烃源岩热演化新指标[J].石油学报,2001,22(3):27-31. Luo Jian,Cheng Keming,Fu Lixin,et al.Alkylated dibenzothiophene index:a new method to assess thermal maturity of source rocks[J].Acta Potrolei Sinica,2001,22(3):27-31.
[12]	Wang Tieguan,He Faqi,Li Meijun,et al.Alkyldibenzothiophenes:molecular tracers for filling pathway in oil reservoirs[J].Chinese Science Bulletin,2004,49(22):2399-2404.
[13]	Li Meijun,Wang Tieguan,Liu Ju,et al.Total alkyl dibenzothiophenes content tracing the filling pathway of condensate reservoir in the Fushan depression,South China Sea[J].Science in China: Series D:Earth Sciences,2008,51(SⅡ):138-145.
[14]	Connan J,Bouroullec J,Dessort D,et al.The microbial input in carbonate-anhydrite facies of a Sabkha palaeoenvironment from Guatemala:A molecular approach[J]//Organic Geochemistry,1986,10(1/3):29-50.
[15]	Mssner S G,De Alda M J L,Sandera L C,et al.Gas chromatographic retention behavior of polycyclic aromatic sulfur heterocyclic compounds,(dibenzothiophene,naphthothiophenes,benzonaphthothiophenes and alkyl-substituted derivatives) on stationary phases of different selectivity[J].Journal of Chromatography A,1999,841(2):207-228.
[16]	Schade T,Andersson J T.Speciation of alkylated dibenzothiophenes through correlation of structure and gas chromatographic retention indexes[J].Journal of Chromatography A,2006,1117(2):206-213.
[17]	Asif M,Alexander R,Fazeelat T,et al.Geosynthesis of dibenzothiophene and alkyl dibenzothiophenes in crude oils and sediments by carbon catalysis[J].Organic Geochemistry,2009,40(8):895-901.
[18]	Kováts E.Gas-chromatographische Charakterisierung organischer Verbindungen.Teil 1:Retentionsindices aliphatischer Halogenide,Alkohole,Aldehyde und Ketone[J].Helvetica Chimica Acta,1958,41(7):1915-1932.
[19]	Van Den Dool H,Dec Kratz P.A generalization of the retention index system including linear temperature programmed gas:li-quid partition chromatography[J].Journal of Chromatography A,1963,11:463-471.
[20]	Lee M L,Vassilaros D L,White C M,et al.Retention indices for programmed-temperature capillary-column gas chromatography of polycyclic aromatic hydrocarbons[J].Analytical Chemistry,1979,51(6):768-773.
[21]	Andersson J T.Gas chromatographic retention indices for all C₁- and C₂-alkylated benzothiophenes and their dioxides on three different stationary phases[J].Journal of Chromatography A,1986,354:83-98.
[22]	Richard L.Calculation of the standard molal thermodynamic properties as a function of temperature and pressure of some geochemically important organic sulfur compounds[J].Geochimica et Cosmochimica Acta,2001,65(21):3827-3877.
[23]	Radke M.Application of aromatic compounds as maturity indicators in source rocks and crude oils[J].Marine and Petroleum Geology,1988,5(3):224-236.
[24]	Radke M,Welte D H,Willsch H.Distribution of alkylated aromatic hydrocarbons and dibenzothiophenes in rocks of the Upper Rhine Graben[J].Chemical Geology,1991,93(3/4):325-341.
[25]	Radke M,Willsch H.Extractable alkyldibenzothiophenes in Posidonia Shale (Toarcian) source rocks:Relationship of yields to petroleum formation and expulsion[J].Geochimica et Cosmochimica Acta,1994,58(23):5223-5244.