Preparation and Characterization of the LiNi_0.8Co_0.1Mn_0.1O₂ Cathode Active Material by Electrophoretic Deposition

The electrophoretic deposition (EPD) process enables more uniform coating layers and saves time over the traditional laminating (LN) process. LiNi_0.8Co_0.1Mn_0.1O₂ (NCM811) is prepared by EPD and LN processes in this study. The electrode materials, which are composed of active materials, conductive agents, and binders, are more uniformly dispersed on the substrate by the EPD process when compared with the LN process. Since the weight ratio of NCM811 can be changed through the EPD process, the specific capacity is calculated by weighing the deposited active materials after the process. The crystal structure and particle morphology of the prepared cathode electrode are investigated by X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM), respectively. The electrode prepared by EPD delivers a specific discharge capacity of 189.3 mAh g⁻¹ at a current rate of 0.2 C at the first cycle and exhibits capacity retention of 88.6% after the 40th cycle. Compared with LN, EPD shows a good rate capability at various current rates from 0.2 to 2.5 C. These results provide the evidence of the superior electrochemical properties and process efficiency of the electrodes prepared by EPD.