Lanthanopolyoxotungstoborates: Synthesis, Characterization, and Layer-by-Layer Assembly of Europium Photoluminescent Nanostructured Films
New lanthanopolyoxotungstoborates, K6-xHH[Ln(BW11O39)(H2O)3]·nH2O, Ln(III) = Sm, Eu, Tb, Er, were prepared and
characterized by spectroscopic methods (Fourier transform infrared, Fourier transform-Raman, 11B solid-state nuclear magnetic resonance, and photoluminescence) and elemental analysis. A layer-by-layer
assembly method was employed to fabricate multilayered films containing the europium heteropolyanion and the polyelectrolytes poly(sodium 4-styrenesulfonate) and poly(diallydimethylammonium chloride). The
photoluminescence behavior of these final nanostructures was investigated and compared with that of the starting Eu(III) polyoxometalate used as the building unit.
Keywords: LANTHANIDES; NANOSTRUCTURES; PHOTOLUMINESCENCE; POLYOXOMETALATES; THIN FILMS
Document Type: Research Article
Publication date: 01 January 2004
- Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
- Editorial Board
- Information for Authors
- Subscribe to this Title
- Terms & Conditions
- Ingenta Connect is not responsible for the content or availability of external websites
- Access Key
- Free content
- Partial Free content
- New content
- Open access content
- Partial Open access content
- Subscribed content
- Partial Subscribed content
- Free trial content