主催: 応用物理学会, 高分子学会, 日本化学会 液晶討論会世話人会
会議名: 第23回 液晶討論会
回次: 23
開催地: 東京工業大学
開催日: 1997/09/25 - 1997/09/27
We have investigated the molecular dynamics in the chiral smectic phases of an antiferroelectric liquid crystal, (S)-MHPOBC, by means of solid-state13C NMR spectroscopy with CP/MAS and MASGHD techniques. In the CP/MAS spectra on heating, the half-width of an aromatic peak increases with increasing temperature in crystalline phase until it attains a maximum at about 75℃, and decrease in smectic phases. Assuming that the observed line broadening of MHPOBC occurs under the condition of ω1・τ〜1, where ω1 is a contact time and τ is a correlation time, the crrelation time (τ) of the molecular motion for the core part is estimated to be about 10-6s.