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Catalytic Synthesis of Methylthiophenes

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Abstract

The gas-phase reaction of dimethyl disulfide with thiophene over Co/HZSM-5 catalyst in a helium medium under atmospheric pressure at 250–350°C gave a mixture of mono-, di-, tri-, and tetramethylthiophenes with an overall selectivity of 94–96%.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akad. Lavrent’eva 5, Novosibirsk, 630090, Russia

    A. V. Mashkina & L. N. Khairulina

Authors
  1. A. V. Mashkina
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  2. L. N. Khairulina
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Correspondence to A. V. Mashkina.

Additional information

Original Russian Text © A.V. Mashkina, L.N. Khairulina, 2018, published in Zhurnal Organicheskoi Khimii, 2018, Vol. 54, No. 12, pp. 1780–1783.

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Mashkina, A.V., Khairulina, L.N. Catalytic Synthesis of Methylthiophenes. Russ J Org Chem 54, 1794–1797 (2018). https://doi.org/10.1134/S1070428018120096

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  • DOI: https://doi.org/10.1134/S1070428018120096

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