Abstract
In this study, niobium carbide (NbC) coatings were grown on AISI D3 cold work tool steel via thermoreactive diffusion (TRD) at 900, 1000 and 1100°C for 2, 4, and 6 h. The microstructures and phase formed, the surface roughnesses, the microhardness and fracture toughness values, and the wear and electrochemical corrosion behavior of the NbC coatings were investigated. Compact, smooth and crack-free NbC layers with 8.75–17.10 µm thickness and 1558–2286 HV0.1 hardness were obtained on the surface of the AISI D3 steel. Depending on the TRD temperature and duration, the NbC coatings improved the wear resistance by up to 5 times and corrosion resistance up to 14 times compared to the untreated alloy. With increasing temperature and duration, the thickness and microhardness values of NbC coatings increased. However, significant changes in wear and corrosion resistance was observed depending on Nb, C, O and Fe contents of NbC coatings rather than thickness and microhardness. The wear resistance was found to depend on fracture toughness as well as hardness. Corrosion resistance depended mostly on the surface roughness and the defects (especially microcracks) present on the surface.
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REFERENCES
Thermochemical Surface Engineering of Steels, Mittemeijer, E.J. and Somers, M.A., Eds., Cambridge: Woodhead Publ., 2014, p. 816.
Çakir, M.V., Prot. Met. Phys. Chem. Surf., 2022, vol. 58, no. 3, p. 562.
Dearnley, P.A., Introduction to Surface Engineering, Cambridge Univ. Press, 2017.
Günen, A., Kanca, Y., Karahan, İ.H., Karakaş, M.S., Gök, M.S., Kanca, E., and Çürük, A., Metall. Mater. Trans. A, 2018, vol. 49, no. 11, p. 5833.
Gunes, I., Ulker, S., and Taktak, S., Prot. Met. Phys. Chem. Surf., 2013, vol. 49, no. 5, p. 567.
Kayali, Y. and Mertgenç, E., Prot. Met. Phys. Chem. Surf., 2020, vol. 56, no. 1, p. 151.
Kloprogge, J.T., Ponce, C.P., and Loomis, T., The Periodic Table: Nature’s Building Blocks, An Introduction to the Naturally Occurring Elements, Their Origins and Their Uses, Elsevier, 2020, chap. 6.
Keddam, M., Hudáková, M., Ptačinová, J., Kusy, M., and Jurči, P., Prot. Met. Phys. Chem. Surf., 2022, vol. 58, no. 2, p. 347.
Klug, J.A., Proslier, T., Elam, J.W., Cook, R.E., Hiller, J.M., Claus, H., and Pellin, M.J., J. Phys. Chem. C, 2011, vol. 115, no. 50, p. 25063.
Wang, L., Sun, J., Kang, B., Li, S., Ji, S., Wen, Z., and Wang, X., J. Power Sources, 2014, vol. 246, p. 775.
Fals, H.C., Roca, A.S., Fogagnolo, J.B., Fanton, L., Belém, M.J.X., and Lima, C.R.C., J. Therm. Spray Technol., 2020, vol. 29, no. 1, p. 319.
Constantinescu, S., Ann. Univ. Dunarea Jos Galati, Fasc. IX, 2016, vol. 34, no. 3, p. 36.
Zhang, K., Wen, M., Meng, Q.N., Hu, C.Q., Li, X., Liu, C., and Zheng, W.T., Surf. Coat. Technol., 2012, vol. 212, p. 185.
Krelling, A.P., Milan, J.C.G., Costa, C.E.D., Almeida, E.A.D.S., and Galiotto, A., Tecnol. Metal., Mater. Min., 2018, vol. 14, no. 2, p. 133.
Ganji, O., Sajjadi, S.A., Yang, Z.G., and Mirjalili, M., Ceram. Int., 2022, vol. 48, no. 6, p. 7475.
Soares, C., Mariani, F.E., Casteletti, L.C., Lombardi, A.N., and Totten, G.E., Mater. Perform. Charact., 2017, vol. 6, no. 4, p. 20160093.
Soltani, R., Sohi, M.H., Ansari, M., Haghighi, A., Ghasemi, H.M., and Haftlang, F., Vacuum, 2017, vol. 146, p. 44.
Amaya, A., Piamba, O., and Olaya, J., Coatings, 2018, vol. 8, no. 6, p. 216.
Sen, U., Thin Solid Films, 2005, vol. 483, nos. 1–2, p. 152.
Ganji, O., Sajjadi, S.A., Yang, Z.G., Mirjalili, M., and Najari, M.R., Ceram. Int., 2020, vol. 46, no. 16, p. 25320.
Günen, A., Kanca, E., Karakaş, M.S., Gök, M.S., Kalkandelen, M., Kurt, B., and Karahan, I.H., Surf. Coat. Technol., 2021, vol. 419, p. 127305.
Kurt, B., Günen, A., Kanca, Y., Koç, V., Gök, M.S., Kırar, E., and Askerov, K., JOM, 2018, vol. 70, no. 11, p. 2650.
Zhang, J., Li, S., Sun, Q., Luo, P., and Sun, Y., Mater. Res. Express, 2019, vol. 6, no. 9, p. 096432.
Castillejo, F.E., Marulanda, D.M., and Olaya, J.J., Ingeniare. Revista Chilena de Ingeniería, 2014, vol. 22, no. 2, p. 189.
Fernandes, F.A.P., Gallego, J., Picon, C.A., Tremiliosi Filho, G., and Casteletti, L.C., Surf. Coat. Technol., 2015, vol. 279, p. 112.
Mariani, F.E., Rêgo, G.C., Bonella, P.G., Neto, A.L., Totten, G.E., and Casteletti, L.C., J. Mater. Eng. Perform., 2020, vol. 29, no. 6, p. 3516.
Mariani, F.E., Takeya, G.S., Lombardi, A.N., Picone, C.A., and Casteletti, L.C., Surf. Coat. Technol., 2020, vol. 397, p. 126050.
Bahoosh, M., Shahverdi, H.R., and Farnia, A., Eng. Failure Anal., 2018, vol. 92, p. 480.
Kulka, M., Makuch, N., and Piasecki, A., Surf. Coat. Technol., 2017, vol. 325, p. 515.
Campos, I., Rosas, R., Figueroa, U., VillaVelázquez, C., Meneses, A., and Guevara, A., Mater. Sci. Eng., A, 2008, vol. 488, nos. 1–2, p. 562.
Günen, A., Keddam, M., Alkan, S., Erdoğan, A., and Çetin, M., Mater. Charact., 2022, vol. 186, p. 111778.
Günen, A., J. Eng. Mater. Technol., 2020, vol. 142, no. 1, p. 011010.
Das, D., Dutta, A.K., and Ray, K.K., Mater. Sci. Eng., A, 2010, vol. 527, no. 9, p. 2182.
Militzer, M. and Garcin, T., in Advanced High Strength Steel, Springer, 2018, p. 11.
Amini, K., Akhbarizadeh, A., and Javadpour, S., Vacuum, 2012, vol. 86, no. 10, p. 1534.
Luo, S.Y., J. Mater. Process. Technol., 1999, vol. 88, nos. 1–3, p. 122.
Roberts, G.A., Kennedy, R., and Krauss, G., Tool Steels, ASM Int., 1998.
Kim, H., Kang, J.Y., Son, D., Lee, T.H., and Cho, K.M., Mater. Charact., 2015, vol. 107, p. 376.
Worrell, W.L. and Chipman, J., J. Phys. Chem., 1964, vol. 68, no. 4, p. 860.
Momeni, M., Kheirandish, S., Saghafian, H., Hedjazi, J., and Momeni, M., Mater. Des. (1980–2015), 2014, vol. 54, p. 742.
Pöckl, G., Proc. 4th ASM Heat Treatment and Surface Engineering Conference in Europe, Florence, 1998.
Günen, A., Soylu, B., and Karakaş, Ö., Surf. Coat. Technol., 2022, vol. 437, p. 128280.
Zhao, X., Togaru, M., Guo, Q., Weinberger, C.R., Lamberson, L., and Thompson, G.B., J. Eur. Ceram. Soc., 2019, vol. 39, no. 16, p. 5167.
Cuppari, M.G.D.V. and Santos, S.F., Metals, 2016, vol. 6, no. 10, p.250.
Friction, Wear and Wear Protection, Fischer, A. and Bobzin, K., Eds., John Wiley and Sons, 2009, vol. 10.
Günen, A. and Çürük, A., JOM, 2020, vol. 72, no. 2, p. 673.
Döleker, K.M., Erdogan, A., Yener, T., Karaoglanlı, A.C., Uzun, O., Gök, M.S., and Zeytin, S., Surf. Coat. Technol., 2021, vol. 412, p. 127069.
Yener, T., Erdogan, A., Gök, M.S., and Zeytin, S., J. Tribol., 2021, vol. 143, no. 1, p. 011703.
Filipovic, M., Kamberovic, Z., Korac, M., and Gavrilovski, M., Met. Mater. Int., 2013, vol. 19, no. 3, p. 473.
Chintha, A.R., Valtonen, K., Kuokkala, V.T., Kundu, S., Peet, M.J., and Bhadeshia, H.K.D.H., Wear, 2019, vol. 428, p. 430.
Lorenzo-Martin, C., Ajayi, O., Erdemir, A., Fenske, G.R., and Wei, R., Wear, 2013, vol. 302, nos. 1–2, p. 963.
Kulka, M., Makuch, N., Pertek, A., and Piasecki, A., Opt. Laser Technol., 2012, vol. 44, no. 4, p. 872.
Wang, S.Q., Wei, M.X., Wang, F., and Zhao, Y.T., Tribol. Int., 2010, vol. 43, no. 3, p. 577.
Wei, M.X., Chen, K.M., Wang, S.Q., and Cui, X.H., Tribol. Lett., 2011, vol. 42, no. 1, p. 1.
Babilas, R., Łoński, W., Młynarek, K., Bajorek, A., and Radoń, A., Metall. Mater. Trans. A, 2020, vol. 51, no. 8, p. 4215.
Ejaz, A., Lu, Z., Chen, J., Xiao, Q., Ru, X., Han, G., and Shoji, T., Corros. Sci., 2015, vol. 101, p. 165.
Wallaert, E., Depover, T., Arafin, M., and Verbeken, K., Metall. Mater. Trans. A, 2014, vol. 45, no. 5, p. 2412.
Li, J., Wu, J., Wang, Z., Zhang, S., Wu, X., Huang, Y., and Li, X., Int. J. Hydrogen Energy, 2017, vol. 42, no. 34, p. 22175.
Orjuela, G.A., Rincon, R., and Olaya, J.J., Surf. Coat. Technol., 2014, vol. 259, p. 667.
Nieto, F.E.C., Floréz, J.J.O., and Orjuela, J.E.A., Ingeniare. Revista Chilena de Ingeniería, 2016, vol. 24, no. 2, p. 206.
Günen, A., Kalkandelen, M., Karahan, İ.H., Kurt, B., Kanca, E., Gök, M.S., and Serdar Karakaş, M., J. Eng. Mater. Technol., 2020, vol. 142, no. 4, p. 041008.
Jovičević-Klug, P., Kranjec, T., Jovičević-Klug, M., Kosec, T., and Podgornik, B., Materials, 2021, vol. 14, no. 21, p. 6357.
Rosenfeld, I.L. and Marshakov, I.K., Corrosion, 1964, vol. 20, no. 4, p. 115t.
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Günen, A., Açıkgöz, H.H. & Karahan, İ.H. Niobium Carbide Coatings Grown on Cold Work Tool Steel AISI D3 by Thermomechanical Processing: Characterization, Wear and Corrosion Behaviors. Prot Met Phys Chem Surf 59, 648–670 (2023). https://doi.org/10.1134/S207020512370065X
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DOI: https://doi.org/10.1134/S207020512370065X