Abstract—
Polycrystalline praseodymium orthoniobate, PrNbO4, has been studied by high-temperature X‑ray diffraction and differential scanning calorimetry. We have determined the temperature of the fergusonite–scheelite structural phase transition and shown it to be a second-order transition.
Similar content being viewed by others
REFERENCES
Li, C., Bayliss, R.D., and Skinner, S.J., Crystal structure and potential interstitial oxide ion conductivity of LnNbO4 and LnNb0.92W0.08O4.04 (Ln = La, Pr, Nd), Solid State Ionics, 2014, vol. 262, pp. 530–535. https://doi.org/10.1016/j.ssi.2013.12.023
Cao, Y., Duan, N., Yan, D., Chi, B., Pu, J., and Jian, L., Enhanced electrical conductivity of LaNbO4 by A-site substitution, Int. J. Hydrogen Energy, 2016, vol. 41, pp. 20 633–20 639. https://doi.org/10.1016/j.ijhydene.2016.08.056
Haugsrud, R. and Norby, T., Proton conduction in rare-earth ortho-niobates and ortho-tantalates, Nat. Mater., 2006, vol. 5, pp. 193–196. https://doi.org/10.1038/nmat1591
Magrasó, A., Fontaine, M.-L., Bredesen, R., Haugsrud, R., and Norby, T., Cathode compatibility, operation, and stability of LaNbO4-based proton conducting fuel cells, Solid State Ionics, 2014, vol. 262, pp. 382–387. https://doi.org/10.1016/j.ssi.2013.12.009
Balamurugan, C., Lee, D.-W., and Subramania, A., Preparation and LPG-gas sensing characteristics of p‑type semiconducting LaNbO4 ceramic material, Appl. Surf. Sci., 2013, vol. 283, pp. 58–64. https://doi.org/10.1016/j.apsusc.2013.06.013
Dzierzgowski, K., Wachowski, S., Gojtowska, W., Lewandowska, I., Jasiński, P., Gazda, M., and Mielewczyk-Gryń, A., Praseodymium substituted lanthanum orthoniobate: electrical and structural properties, Ceram. Int., 2018, vol. 44, no. 7, pp. 8210–8215. https://doi.org/10.1016/j.ceramint.2018.01.270
Rooksby, H.P. and White, E.A.D., The structures of 1 : 1 compounds of rare earth oxides with niobia and tantala, Acta Crystallogr., 1963, vol. 16, pp. 888–890. https://doi.org/10.1107/S0365110X63002395
Sarin, P., Hughes, R.W., Lowry, D.R., Apostolov, Z.D., and Kriven, W.M., High-temperature properties and ferroelastic phase transitions in rare-earth niobates (LnNbO4), J. Am. Ceram. Soc., 2014, vol. 97, pp. 3307–3319. https://doi.org/10.1111/jace.13095
Jian, L. and Wayman, C., Monoclinic-to-tetragonal phase transformation in a ceramic rare-earth orthoniobate LaNbO4, J. Am. Ceram. Soc., 1997, vol. 80, pp. 803–806. https://doi.org/10.1111/j.1151-2916.1997.tb02905.x
Kukueva, L.L., Ivanova, L.A., and Venevtsev, Yu.N., Ferroelastics with the fergusonite type structure, Ferroelectrics, 1984, vol. 55, pp. 129–133. https://doi.org/10.1080/00150198408015351
Brixner, L.H., Whitney, J.F., Zumsteg, F.C., and Jones, G.A., Ferroelasticity in the LnNbO4-type rare earth niobates, Mater. Res. Bull., 1977, vol. 12, pp. 17–24. https://doi.org/10.1016/0025-5408(77)90084-8
Nikiforova, G., Khoroshilov, A., Tyurin, A., Gurevich, V., and Gavrichev, K., Heat capacity and thermodynamic properties of lanthanum orthoniobate, J. Chem. Thermodyn., 2019, vol. 132, pp. 44–53. https://doi.org/10.1016/j.jct.2018.12.041
Kondrat’eva, O.N., Nikiforova, G.E., Tyurin, A.V., Khoroshilov, A.V., Gurevich, V.M., and Gavrichev, K.S., Thermodynamic properties of, and fergusonite-to-scheelite phase transition in gadolinium orthoniobate GdNbO4 ceramics, J. Alloys Compd., 2019, vol. 779, pp. 660–666. https://doi.org/10.1016/j.jallcom.2018.11.272
McCarthy, G.J., X-ray studies of RENbO4 compounds, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1971, vol. 27, pp. 2285–2286. https://doi.org/10.1107/S0567740871005697
Knyazev, A.V., Smirnova, N.N., Mączka, M., Knyazeva, S.S., and Letyanina, I.A., Thermodynamic and spectroscopic properties of spinel with the formula Li4/3Ti5/3O4, Thermochim. Acta, 2013, vol. 559, pp. 40–45. https://doi.org/10.1016/j.tca.2013.02.019
ACKNOWLEDGMENTS
In this study, we used equipment at the Shared Physical Characterization Facilities Center, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences.
Funding
This work was supported by the Russian Federation Ministry of Science and Higher Education (state research target for the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, basic research) and the Russian Foundation for Basic Research (grant no. 18-03-00343).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by O. Tsarev
Rights and permissions
About this article
Cite this article
Nikiforova, G.E., Khoroshilov, A.V., Gavrichev, K.S. et al. Fergusonite–Scheelite Phase Transition of Praseodymium Orthoniobate. Inorg Mater 55, 964–967 (2019). https://doi.org/10.1134/S0020168519090085
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168519090085