The infrared anti-reflection film is prepared by ion beam assisted thermal evaporation deposition technology. The film has good firmness and can meet the needs of wet transfer. By adjusting the number of layers of the graphene mesh, the electromagnetic shielding and optical transparency properties are simultaneously improved. The infrared anti-reflection film and graphene mesh are combined to design and prepare a compatible electromagnetic shielding infrared anti-reflection film device with sandwich structure. The test results of the device show that the peak transmittance of the graphene mesh/infrared film/substrate/infrared film combination structure in the 3 to 5 μm band is 95.06%, and the average transmittance is 93.40%. The peak shielding effectiveness (SE) in the 12 to 18 GHz frequency band is 14.50 dB, and the average SE is 12.98 dB. It shows that the film device of this structure maintains the high transmittance of the infrared anti-reflection film and has good electromagnetic shielding effectiveness.