Cathodic protection of carbon steel in thin layers of seawater

The purpose of this study is to investigate cathodic protection (CP) efficiency in the tidal zone and its associated processes.

Specific features of CP in the tidal zone, that is, persistence of a thin seawater film and insufficient cathodic potential due to ohmic drop, were addressed. In this preliminary study, carbon steel electrodes were polarized at two cathodic potentials (correct or insufficient protection) while immersed in 1 mm or 5 mm thick natural seawater layers. After CP interruption, the protective ability of the layers covering the steel electrodes was studied using various electrochemical methods, including electrochemical impedance spectroscopy. The layers were characterized by XRD.

The protective ability of calcareous deposits was increased in thin seawater films. Insufficient CP could promote protective aragonite/corrosion products layer.

The combined effects of thin seawater film and applied potential were never addressed, and the conclusions drawn from this preliminary study give new insight on the efficiency of CP in the tidal zone.