metal-organic compounds
The PbII atom in the title compound, [Pb(C9H6NO)2], is N,O-chelated by two organic ligands, and two molecules are linked across a centre of inversion to form a dinuclear entity. These dinuclear entities are linked by somewhat weaker PbO bonds into a chain. There are two independent molecules in the asymmetric unit with similar geometry around the Pb atoms, which have a pseudo-pentagonal–bipyramidal coordination with one of the axial positions occupied by the Pb lone pair. Some distances involving the Pb atoms are significantly different between the two molecules.
Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805011852/dn6216sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536805011852/dn6216Isup2.hkl |
CCDC reference: 274388
Computing details top
Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPIII (Burnett & Johnson, 1996) and ORTEPIII for Windows (Farrugia, 1997); software used to prepare material for publication: SHELXL97.
Crystal data top
[Pb(C9H6NO)2] | F(000) = 3712 |
Mr = 495.59 | Dx = 2.138 Mg m−3 |
Monoclinic, C2/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -C 2yc | Cell parameters from 4994 reflections |
a = 35.937 (2) Å | θ = 2.5–27.4° |
b = 8.3365 (4) Å | µ = 10.97 mm−1 |
c = 25.432 (1) Å | T = 295 K |
β = 126.076 (1)° | Column, yellow |
V = 6158.1 (5) Å3 | 0.18 × 0.17 × 0.15 mm |
Z = 16 |
Data collection top
Bruker APEX CCD area-detector diffractometer | 6956 independent reflections |
Radiation source: fine-focus sealed tube | 4910 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.028 |
φ and ω scans | θmax = 27.5°, θmin = 1.4° |
Absorption correction: multi-scan (SADABS; Bruker, 2002) | h = −41→46 |
Tmin = 0.077, Tmax = 0.193 | k = −10→10 |
20725 measured reflections | l = −32→31 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.030 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.075 | H-atom parameters constrained |
S = 1.00 | w = 1/[σ2(Fo2) + (0.0333P)2] where P = (Fo2 + 2Fc2)/3 |
6956 reflections | (Δ/σ)max = 0.001 |
415 parameters | Δρmax = 1.07 e Å−3 |
0 restraints | Δρmin = −1.12 e Å−3 |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
x | y | z | Uiso*/Ueq | ||
Pb1 | 0.231838 (7) | 0.50370 (2) | 0.489411 (8) | 0.03595 (7) | |
Pb2 | 0.002870 (5) | 0.25041 (2) | 0.502647 (7) | 0.03364 (7) | |
O1 | 0.2049 (1) | 0.7784 (3) | 0.4769 (2) | 0.045 (1) | |
O2 | 0.2101 (1) | 0.2648 (3) | 0.4259 (2) | 0.046 (1) | |
O3 | 0.0093 (1) | 0.0165 (3) | 0.5623 (2) | 0.041 (1) | |
O4 | 0.0440 (1) | 0.4799 (3) | 0.5029 (2) | 0.045 (1) | |
N1 | 0.1452 (2) | 0.5296 (4) | 0.4204 (2) | 0.037 (1) | |
N2 | 0.2202 (1) | 0.5482 (5) | 0.3842 (2) | 0.039 (1) | |
N3 | 0.0457 (1) | 0.3040 (4) | 0.6206 (2) | 0.033 (1) | |
N4 | 0.0850 (1) | 0.1902 (4) | 0.5504 (2) | 0.037 (1) | |
C1 | 0.1165 (2) | 0.4073 (6) | 0.3925 (3) | 0.051 (2) | |
C2 | 0.0687 (2) | 0.4261 (8) | 0.3615 (3) | 0.067 (2) | |
C3 | 0.0515 (2) | 0.5730 (8) | 0.3599 (3) | 0.067 (2) | |
C4 | 0.0816 (2) | 0.7037 (6) | 0.3901 (3) | 0.049 (1) | |
C5 | 0.0663 (2) | 0.8559 (7) | 0.3928 (3) | 0.069 (2) | |
C6 | 0.0976 (3) | 0.9764 (6) | 0.4249 (3) | 0.061 (2) | |
C7 | 0.1445 (2) | 0.9525 (6) | 0.4535 (3) | 0.049 (2) | |
C8 | 0.1612 (2) | 0.8055 (5) | 0.4510 (2) | 0.039 (1) | |
C9 | 0.1286 (2) | 0.6775 (6) | 0.4195 (2) | 0.037 (1) | |
C10 | 0.2257 (2) | 0.6878 (6) | 0.3645 (3) | 0.054 (2) | |
C11 | 0.2173 (2) | 0.7050 (7) | 0.3029 (3) | 0.065 (2) | |
C12 | 0.2027 (2) | 0.5777 (8) | 0.2625 (3) | 0.064 (2) | |
C13 | 0.1960 (2) | 0.4308 (7) | 0.2820 (3) | 0.054 (2) | |
C14 | 0.1795 (2) | 0.2975 (8) | 0.2408 (3) | 0.074 (2) | |
C15 | 0.1731 (2) | 0.1567 (8) | 0.2630 (3) | 0.080 (2) | |
C16 | 0.1829 (2) | 0.1433 (6) | 0.3252 (3) | 0.061 (2) | |
C17 | 0.1998 (2) | 0.2731 (6) | 0.3675 (2) | 0.041 (1) | |
C18 | 0.2050 (2) | 0.4186 (6) | 0.3434 (2) | 0.038 (1) | |
C19 | 0.0629 (2) | 0.4435 (6) | 0.6490 (2) | 0.042 (1) | |
C20 | 0.0866 (2) | 0.4699 (6) | 0.7152 (3) | 0.052 (2) | |
C21 | 0.0928 (2) | 0.3424 (7) | 0.7533 (2) | 0.057 (2) | |
C22 | 0.0744 (2) | 0.1887 (6) | 0.7259 (2) | 0.044 (1) | |
C23 | 0.0777 (2) | 0.0557 (7) | 0.7621 (3) | 0.065 (2) | |
C24 | 0.0590 (2) | −0.0830 (8) | 0.7309 (3) | 0.068 (2) | |
C25 | 0.0362 (2) | −0.1030 (6) | 0.6639 (3) | 0.053 (2) | |
C26 | 0.0317 (2) | 0.0262 (5) | 0.6255 (3) | 0.037 (1) | |
C27 | 0.0513 (2) | 0.1743 (5) | 0.6583 (2) | 0.034 (1) | |
C28 | 0.1054 (2) | 0.0505 (6) | 0.5748 (3) | 0.048 (1) | |
C29 | 0.1524 (2) | 0.0263 (6) | 0.6074 (3) | 0.057 (2) | |
C30 | 0.1792 (2) | 0.1538 (7) | 0.6147 (3) | 0.056 (2) | |
C31 | 0.1595 (2) | 0.3048 (6) | 0.5895 (2) | 0.040 (1) | |
C32 | 0.1844 (2) | 0.4418 (7) | 0.5952 (3) | 0.055 (2) | |
C33 | 0.1623 (2) | 0.5842 (7) | 0.5710 (3) | 0.053 (2) | |
C34 | 0.1153 (2) | 0.5998 (6) | 0.5401 (2) | 0.046 (1) | |
C35 | 0.0881 (2) | 0.4711 (5) | 0.5315 (2) | 0.038 (1) | |
C36 | 0.1112 (2) | 0.3197 (5) | 0.5573 (2) | 0.033 (1) | |
H1 | 0.1280 | 0.3066 | 0.3934 | 0.061* | |
H2 | 0.0491 | 0.3384 | 0.3423 | 0.080* | |
H3 | 0.0201 | 0.5866 | 0.3388 | 0.081* | |
H5 | 0.0352 | 0.8745 | 0.3729 | 0.083* | |
H6 | 0.0876 | 1.0766 | 0.4279 | 0.074* | |
H7 | 0.1649 | 1.0376 | 0.4745 | 0.059* | |
H10 | 0.2353 | 0.7765 | 0.3918 | 0.065* | |
H11 | 0.2218 | 0.8036 | 0.2903 | 0.077* | |
H12 | 0.1971 | 0.5879 | 0.2220 | 0.077* | |
H14 | 0.1730 | 0.3037 | 0.1996 | 0.088* | |
H15 | 0.1619 | 0.0674 | 0.2359 | 0.096* | |
H16 | 0.1780 | 0.0460 | 0.3382 | 0.073* | |
H19 | 0.0589 | 0.5299 | 0.6229 | 0.051* | |
H20 | 0.0979 | 0.5710 | 0.7331 | 0.062* | |
H21 | 0.1093 | 0.3564 | 0.7980 | 0.068* | |
H23 | 0.0927 | 0.0636 | 0.8068 | 0.078* | |
H24 | 0.0612 | −0.1710 | 0.7551 | 0.082* | |
H25 | 0.0241 | −0.2026 | 0.6448 | 0.064* | |
H28 | 0.0873 | −0.0364 | 0.5698 | 0.058* | |
H29 | 0.1654 | −0.0741 | 0.6240 | 0.068* | |
H30 | 0.2107 | 0.1399 | 0.6367 | 0.067* | |
H32 | 0.2160 | 0.4351 | 0.6155 | 0.066* | |
H33 | 0.1791 | 0.6742 | 0.5754 | 0.064* | |
H34 | 0.1017 | 0.7000 | 0.5246 | 0.055* |
Atomic displacement parameters (Å2) top
U11 | U22 | U33 | U12 | U13 | U23 | |
Pb1 | 0.0361 (1) | 0.0271 (1) | 0.0307 (1) | 0.0056 (1) | 0.0119 (1) | 0.0010 (1) |
Pb2 | 0.0329 (1) | 0.0259 (1) | 0.0327 (1) | 0.0028 (1) | 0.0141 (1) | −0.0022 (1) |
O1 | 0.034 (2) | 0.032 (2) | 0.054 (2) | 0.006 (1) | 0.018 (2) | −0.003 (2) |
O2 | 0.050 (2) | 0.030 (2) | 0.044 (2) | 0.004 (2) | 0.020 (2) | −0.003 (2) |
O3 | 0.054 (2) | 0.029 (2) | 0.041 (2) | −0.002 (1) | 0.028 (2) | −0.004 (1) |
O4 | 0.041 (2) | 0.032 (2) | 0.060 (2) | 0.007 (1) | 0.029 (2) | 0.002 (2) |
N1 | 0.037 (3) | 0.037 (2) | 0.034 (2) | −0.002 (2) | 0.020 (2) | −0.003 (2) |
N2 | 0.033 (2) | 0.039 (2) | 0.036 (2) | −0.003 (2) | 0.015 (2) | −0.003 (2) |
N3 | 0.031 (2) | 0.027 (2) | 0.037 (2) | −0.001 (2) | 0.018 (2) | −0.005 (2) |
N4 | 0.037 (2) | 0.031 (2) | 0.046 (2) | 0.0083 (17) | 0.027 (2) | 0.003 (2) |
C1 | 0.047 (3) | 0.043 (3) | 0.061 (4) | −0.008 (3) | 0.031 (3) | −0.002 (3) |
C2 | 0.051 (4) | 0.064 (4) | 0.080 (5) | −0.017 (3) | 0.036 (4) | 0.000 (4) |
C3 | 0.035 (3) | 0.077 (4) | 0.089 (5) | −0.003 (3) | 0.036 (4) | −0.003 (4) |
C4 | 0.044 (3) | 0.050 (3) | 0.065 (4) | 0.007 (3) | 0.039 (3) | 0.008 (3) |
C5 | 0.048 (4) | 0.071 (4) | 0.098 (5) | 0.017 (3) | 0.049 (4) | 0.011 (4) |
C6 | 0.072 (5) | 0.053 (4) | 0.080 (5) | 0.025 (3) | 0.056 (4) | 0.011 (3) |
C7 | 0.059 (4) | 0.038 (3) | 0.054 (3) | 0.010 (3) | 0.035 (3) | −0.002 (3) |
C8 | 0.043 (3) | 0.034 (3) | 0.034 (3) | 0.008 (2) | 0.019 (2) | 0.004 (2) |
C9 | 0.035 (3) | 0.041 (3) | 0.037 (3) | 0.007 (2) | 0.022 (2) | 0.007 (2) |
C10 | 0.057 (4) | 0.043 (3) | 0.058 (4) | −0.007 (3) | 0.032 (3) | −0.004 (3) |
C11 | 0.071 (4) | 0.067 (4) | 0.053 (4) | −0.004 (3) | 0.035 (3) | 0.014 (3) |
C12 | 0.078 (5) | 0.074 (4) | 0.053 (4) | 0.006 (4) | 0.046 (4) | 0.002 (4) |
C13 | 0.048 (3) | 0.060 (4) | 0.046 (3) | 0.007 (3) | 0.024 (3) | −0.008 (3) |
C14 | 0.091 (5) | 0.073 (4) | 0.045 (4) | 0.017 (4) | 0.034 (4) | −0.015 (3) |
C15 | 0.083 (5) | 0.073 (5) | 0.057 (4) | 0.009 (4) | 0.027 (4) | −0.032 (4) |
C16 | 0.058 (4) | 0.044 (3) | 0.054 (4) | 0.001 (3) | 0.019 (3) | −0.011 (3) |
C17 | 0.034 (3) | 0.039 (3) | 0.037 (3) | 0.013 (2) | 0.012 (2) | −0.005 (2) |
C18 | 0.032 (3) | 0.039 (3) | 0.035 (3) | 0.003 (2) | 0.017 (2) | −0.006 (2) |
C19 | 0.042 (3) | 0.034 (3) | 0.043 (3) | 0.001 (2) | 0.020 (3) | −0.006 (2) |
C20 | 0.047 (4) | 0.047 (4) | 0.045 (3) | −0.004 (2) | 0.018 (3) | −0.015 (3) |
C21 | 0.042 (3) | 0.077 (4) | 0.031 (3) | 0.003 (3) | 0.010 (3) | −0.014 (3) |
C22 | 0.041 (3) | 0.050 (3) | 0.038 (3) | 0.010 (2) | 0.022 (3) | 0.001 (2) |
C23 | 0.086 (5) | 0.062 (4) | 0.042 (3) | 0.012 (4) | 0.035 (4) | 0.008 (3) |
C24 | 0.099 (5) | 0.059 (4) | 0.057 (4) | 0.024 (4) | 0.052 (4) | 0.025 (3) |
C25 | 0.078 (4) | 0.038 (3) | 0.064 (4) | 0.012 (3) | 0.053 (4) | 0.004 (3) |
C26 | 0.041 (3) | 0.037 (3) | 0.043 (3) | 0.007 (2) | 0.030 (3) | 0.001 (2) |
C27 | 0.026 (2) | 0.037 (3) | 0.032 (2) | 0.008 (2) | 0.014 (2) | 0.001 (2) |
C28 | 0.050 (3) | 0.036 (3) | 0.060 (4) | 0.005 (3) | 0.034 (3) | 0.001 (3) |
C29 | 0.045 (4) | 0.042 (3) | 0.073 (4) | 0.017 (3) | 0.030 (3) | 0.006 (3) |
C30 | 0.036 (3) | 0.071 (4) | 0.056 (4) | 0.014 (3) | 0.024 (3) | 0.010 (3) |
C31 | 0.035 (3) | 0.053 (3) | 0.035 (3) | 0.004 (2) | 0.023 (2) | 0.003 (2) |
C32 | 0.048 (4) | 0.065 (4) | 0.061 (4) | −0.008 (3) | 0.038 (3) | 0.003 (3) |
C33 | 0.060 (4) | 0.045 (3) | 0.060 (4) | −0.019 (3) | 0.038 (3) | −0.006 (3) |
C34 | 0.062 (4) | 0.033 (3) | 0.056 (3) | −0.006 (3) | 0.042 (3) | 0.002 (2) |
C35 | 0.044 (3) | 0.035 (3) | 0.041 (3) | −0.001 (2) | 0.029 (3) | 0.001 (2) |
C36 | 0.038 (3) | 0.035 (3) | 0.030 (2) | 0.002 (2) | 0.023 (2) | −0.002 (2) |
Geometric parameters (Å, º) top
Pb1—O1 | 2.433 (3) | C19—C20 | 1.387 (7) |
Pb1—O1i | 2.627 (3) | C20—C21 | 1.365 (7) |
Pb1—O2 | 2.387 (3) | C21—C22 | 1.422 (7) |
Pb1—O2ii | 2.952 (3) | C22—C23 | 1.400 (7) |
Pb1—N1 | 2.528 (4) | C22—C27 | 1.407 (6) |
Pb1—N2 | 2.482 (4) | C23—C24 | 1.339 (8) |
Pb2—O3 | 2.396 (3) | C24—C25 | 1.401 (7) |
Pb2—O3iii | 2.649 (3) | C25—C26 | 1.396 (7) |
Pb2—O4 | 2.416 (3) | C26—C27 | 1.423 (6) |
Pb2—O4iv | 2.763 (3) | C28—C29 | 1.389 (8) |
Pb2—N3 | 2.475 (4) | C29—C30 | 1.371 (7) |
Pb2—N4 | 2.493 (4) | C30—C31 | 1.400 (7) |
O1—C8 | 1.318 (5) | C31—C32 | 1.404 (7) |
O2—C17 | 1.303 (6) | C31—C36 | 1.423 (6) |
O3—C26 | 1.311 (6) | C32—C33 | 1.359 (7) |
O4—C35 | 1.299 (7) | C33—C34 | 1.385 (7) |
N1—C1 | 1.320 (6) | C34—C35 | 1.378 (6) |
N1—C9 | 1.364 (5) | C35—C36 | 1.440 (6) |
N2—C10 | 1.326 (6) | C1—H1 | 0.93 |
N2—C18 | 1.368 (6) | C2—H2 | 0.93 |
N3—C19 | 1.315 (5) | C3—H3 | 0.93 |
N3—C27 | 1.378 (5) | C5—H5 | 0.93 |
N4—C28 | 1.320 (5) | C6—H6 | 0.93 |
N4—C36 | 1.375 (5) | C7—H7 | 0.93 |
C1—C2 | 1.414 (7) | C10—H10 | 0.93 |
C2—C3 | 1.361 (8) | C11—H11 | 0.93 |
C3—C4 | 1.402 (7) | C12—H12 | 0.93 |
C4—C5 | 1.399 (7) | C14—H14 | 0.93 |
C4—C9 | 1.406 (7) | C15—H15 | 0.93 |
C5—C6 | 1.363 (8) | C16—H16 | 0.93 |
C6—C7 | 1.405 (9) | C19—H19 | 0.93 |
C7—C8 | 1.381 (6) | C20—H20 | 0.93 |
C8—C9 | 1.430 (6) | C21—H21 | 0.93 |
C10—C11 | 1.417 (7) | C23—H23 | 0.93 |
C11—C12 | 1.349 (7) | C24—H24 | 0.93 |
C12—C13 | 1.394 (8) | C25—H25 | 0.93 |
C13—C14 | 1.398 (7) | C28—H28 | 0.93 |
C13—C18 | 1.401 (7) | C29—H29 | 0.93 |
C14—C15 | 1.380 (8) | C30—H30 | 0.93 |
C15—C16 | 1.410 (8) | C32—H32 | 0.93 |
C16—C17 | 1.388 (6) | C33—H33 | 0.93 |
C17—C18 | 1.419 (7) | C34—H34 | 0.93 |
O1—Pb1—O1i | 66.0 (1) | C13—C18—C17 | 122.7 (5) |
O1—Pb1—O2 | 138.6 (1) | N3—C19—C20 | 124.1 (5) |
O1—Pb1—O2ii | 149.9 (1) | C21—C20—C19 | 117.7 (5) |
O1—Pb1—N1 | 66.2 (1) | C20—C21—C22 | 121.3 (5) |
O1—Pb1—N2 | 85.2 (1) | C23—C22—C27 | 119.8 (5) |
O1i—Pb1—O2 | 132.3 (1) | C23—C22—C21 | 123.8 (5) |
O1i—Pb1—O2ii | 100.5 (1) | C27—C22—C21 | 116.4 (5) |
O1i—Pb1—N1 | 130.0 (1) | C24—C23—C22 | 118.4 (5) |
O1i—Pb1—N2 | 79.2 (1) | C23—C24—C25 | 123.6 (6) |
O2—Pb1—O2ii | 70.8 (1) | C24—C25—C26 | 120.2 (5) |
O2—Pb1—N1 | 79.8 (1) | O3—C26—C25 | 123.0 (5) |
O2—Pb1—N2 | 67.3 (1) | O3—C26—C27 | 120.4 (4) |
O2ii—Pb1—N1 | 128.6 (1) | C25—C26—C27 | 116.5 (5) |
O2ii—Pb1—N2 | 119.9 (1) | N3—C27—C22 | 121.6 (4) |
N1—Pb1—N2 | 83.3 (1) | N3—C27—C26 | 117.0 (4) |
O3—Pb2—O3iii | 68.3 (1) | C22—C27—C26 | 121.4 (5) |
O3—Pb2—O4 | 144.3 (1) | N4—C28—C29 | 123.5 (5) |
O3—Pb2—O4iv | 121.5 (1) | C30—C29—C28 | 118.5 (5) |
O3—Pb2—N3 | 67.7 (1) | C29—C30—C31 | 120.7 (5) |
O3—Pb2—N4 | 83.3 (1) | C30—C31—C32 | 124.4 (5) |
O3iii—Pb2—O4 | 122.9 (1) | C30—C31—C36 | 117.2 (5) |
O3iii—Pb2—O4iv | 141.3 (1) | C32—C31—C36 | 118.4 (5) |
O3iii—Pb2—N3 | 131.6 (1) | C33—C32—C31 | 119.7 (5) |
O3iii—Pb2—N4 | 81.2 (1) | C32—C33—C34 | 122.2 (5) |
O4—Pb2—O4iv | 73.1 (1) | C33—C34—C35 | 121.9 (5) |
O4—Pb2—N3 | 84.9 (1) | O4—C35—C34 | 124.1 (4) |
O4—Pb2—N4 | 67.1 (1) | O4—C35—C36 | 119.4 (4) |
O4iv—Pb2—N3 | 80.8 (1) | C34—C35—C36 | 116.5 (5) |
O4iv—Pb2—N4 | 134.4 (1) | N4—C36—C31 | 121.2 (4) |
N3—Pb2—N4 | 74.5 (1) | N4—C36—C35 | 117.5 (4) |
C8—O1—Pb1 | 119.4 (3) | C31—C36—C35 | 121.3 (5) |
C8—O1—Pb1i | 126.4 (3) | N1—C1—H1 | 119.3 |
Pb1—O1—Pb1i | 114.1 (1) | C2—C1—H1 | 119.3 |
C17—O2—Pb1 | 119.2 (3) | C3—C2—H2 | 120.1 |
C26—O3—Pb2 | 119.2 (3) | C1—C2—H2 | 120.1 |
C26—O3—Pb2iii | 125.0 (3) | C2—C3—H3 | 120.2 |
Pb2—O3—Pb2iii | 111.7 (1) | C4—C3—H3 | 120.2 |
C35—O4—Pb2 | 120.0 (3) | C6—C5—H5 | 120.3 |
C1—N1—C9 | 119.6 (5) | C4—C5—H5 | 120.3 |
C1—N1—Pb1 | 124.1 (3) | C5—C6—H6 | 119.3 |
C9—N1—Pb1 | 115.8 (3) | C7—C6—H6 | 119.3 |
C10—N2—C18 | 119.4 (5) | C8—C7—H7 | 119.2 |
C10—N2—Pb1 | 124.7 (3) | C6—C7—H7 | 119.2 |
C18—N2—Pb1 | 115.8 (3) | N2—C10—H10 | 119.2 |
C19—N3—C27 | 118.8 (4) | C11—C10—H10 | 119.2 |
C19—N3—Pb2 | 125.5 (3) | C12—C11—H11 | 120.1 |
C27—N3—Pb2 | 115.7 (3) | C10—C11—H11 | 120.1 |
C28—N4—C36 | 118.9 (4) | C11—C12—H12 | 120.3 |
C28—N4—Pb2 | 125.3 (3) | C13—C12—H12 | 120.3 |
C36—N4—Pb2 | 115.5 (3) | C15—C14—H14 | 121.0 |
N1—C1—C2 | 121.4 (5) | C13—C14—H14 | 121.0 |
C3—C2—C1 | 119.8 (6) | C14—C15—H15 | 118.8 |
C2—C3—C4 | 119.6 (5) | C16—C15—H15 | 118.8 |
C3—C4—C5 | 122.3 (5) | C17—C16—H16 | 119.5 |
C3—C4—C9 | 117.9 (5) | C15—C16—H16 | 119.5 |
C5—C4—C9 | 119.8 (5) | N3—C19—H19 | 117.9 |
C6—C5—C4 | 119.4 (5) | C20—C19—H19 | 117.9 |
C5—C6—C7 | 121.3 (5) | C21—C20—H20 | 121.1 |
C8—C7—C6 | 121.6 (5) | C19—C20—H20 | 121.1 |
O1—C8—C7 | 123.4 (5) | C20—C21—H21 | 119.3 |
O1—C8—C9 | 119.6 (4) | C22—C21—H21 | 119.3 |
C7—C8—C9 | 117.0 (5) | C24—C23—H23 | 120.8 |
N1—C9—C4 | 121.7 (5) | C22—C23—H23 | 120.8 |
N1—C9—C8 | 117.4 (4) | C23—C24—H24 | 118.2 |
C4—C9—C8 | 120.9 (5) | C25—C24—H24 | 118.2 |
N2—C10—C11 | 121.5 (5) | C24—C25—H25 | 119.9 |
C12—C11—C10 | 119.7 (6) | C26—C25—H25 | 119.9 |
C11—C12—C13 | 119.4 (6) | N4—C28—H28 | 118.2 |
C12—C13—C14 | 121.2 (6) | C29—C28—H28 | 118.2 |
C12—C13—C18 | 119.1 (5) | C30—C29—H29 | 120.7 |
C14—C13—C18 | 119.7 (6) | C28—C29—H29 | 120.7 |
C15—C14—C13 | 118.0 (6) | C29—C30—H30 | 119.6 |
C14—C15—C16 | 122.4 (5) | C31—C30—H30 | 119.6 |
C17—C16—C15 | 120.9 (6) | C33—C32—H32 | 120.1 |
O2—C17—C16 | 122.8 (5) | C31—C32—H32 | 120.1 |
O2—C17—C18 | 121.0 (4) | C32—C33—H33 | 118.9 |
C16—C17—C18 | 116.2 (5) | C34—C33—H33 | 118.9 |
N2—C18—C13 | 120.8 (5) | C33—C34—H34 | 119.0 |
N2—C18—C17 | 116.4 (5) | C35—C34—H34 | 119.0 |
O2—Pb1—O1—C8 | 48.4 (4) | Pb1—N1—C9—C8 | 7.1 (5) |
N2—Pb1—O1—C8 | 95.6 (3) | C3—C4—C9—N1 | −1.5 (8) |
N1—Pb1—O1—C8 | 10.8 (3) | C5—C4—C9—N1 | 177.2 (5) |
O1i—Pb1—O1—C8 | 175.9 (4) | C3—C4—C9—C8 | 179.7 (5) |
O2ii—Pb1—O1—C8 | −116.0 (3) | C5—C4—C9—C8 | −1.6 (8) |
O2—Pb1—O1—Pb1i | −127.5 (2) | O1—C8—C9—N1 | 2.8 (7) |
N2—Pb1—O1—Pb1i | −80.3 (2) | C7—C8—C9—N1 | −176.1 (4) |
N1—Pb1—O1—Pb1i | −165.0 (2) | O1—C8—C9—C4 | −178.4 (5) |
O1i—Pb1—O1—Pb1i | 0.0 | C7—C8—C9—C4 | 2.8 (7) |
O2ii—Pb1—O1—Pb1i | 68.1 (3) | C18—N2—C10—C11 | −1.8 (8) |
O1—Pb1—O2—C17 | 47.7 (4) | Pb1—N2—C10—C11 | −178.3 (4) |
N2—Pb1—O2—C17 | −4.7 (3) | N2—C10—C11—C12 | 1.0 (9) |
N1—Pb1—O2—C17 | 82.2 (3) | C10—C11—C12—C13 | 0.1 (9) |
O1i—Pb1—O2—C17 | −53.8 (4) | C11—C12—C13—C14 | 177.8 (6) |
O2ii—Pb1—O2—C17 | −140.6 (4) | C11—C12—C13—C18 | −0.4 (8) |
O4—Pb2—O3—C26 | 41.7 (5) | C12—C13—C14—C15 | −179.0 (6) |
N3—Pb2—O3—C26 | −0.9 (4) | C18—C13—C14—C15 | −0.9 (9) |
N4—Pb2—O3—C26 | 75.0 (4) | C13—C14—C15—C16 | 0 (1) |
O3iii—Pb2—O3—C26 | 158.3 (5) | C14—C15—C16—C17 | 0 (1) |
O4iv—Pb2—O3—C26 | −64.0 (4) | Pb1—O2—C17—C16 | −174.1 (4) |
O4—Pb2—O3—Pb2iii | −116.6 (2) | Pb1—O2—C17—C18 | 5.3 (6) |
N3—Pb2—O3—Pb2iii | −159.2 (2) | C15—C16—C17—O2 | −178.7 (5) |
N4—Pb2—O3—Pb2iii | −83.2 (2) | C15—C16—C17—C18 | 1.9 (8) |
O3iii—Pb2—O3—Pb2iii | 0.0 | C10—N2—C18—C13 | 1.4 (7) |
O4iv—Pb2—O3—Pb2iii | 137.8 (1) | Pb1—N2—C18—C13 | 178.3 (4) |
O3—Pb2—O4—C35 | 30.2 (5) | C10—N2—C18—C17 | −179.8 (4) |
N3—Pb2—O4—C35 | 69.2 (4) | Pb1—N2—C18—C17 | −2.9 (5) |
N4—Pb2—O4—C35 | −6.1 (4) | C12—C13—C18—N2 | −0.4 (8) |
O3iii—Pb2—O4—C35 | −68.1 (4) | C14—C13—C18—N2 | −178.6 (5) |
O4iv—Pb2—O4—C35 | 151.1 (5) | C12—C13—C18—C17 | −179.0 (5) |
O2—Pb1—N1—C1 | 23.3 (4) | C14—C13—C18—C17 | 2.8 (8) |
O1—Pb1—N1—C1 | 179.2 (4) | O2—C17—C18—N2 | −1.4 (7) |
N2—Pb1—N1—C1 | 91.4 (4) | C16—C17—C18—N2 | 178.1 (4) |
O1i—Pb1—N1—C1 | 161.2 (4) | O2—C17—C18—C13 | 177.3 (5) |
O2ii—Pb1—N1—C1 | −31.7 (5) | C16—C17—C18—C13 | −3.2 (7) |
O2—Pb1—N1—C9 | −164.8 (3) | C27—N3—C19—C20 | −0.1 (8) |
O1—Pb1—N1—C9 | −9.0 (3) | Pb2—N3—C19—C20 | 179.7 (4) |
N2—Pb1—N1—C9 | −96.7 (3) | N3—C19—C20—C21 | 0.6 (9) |
O1i—Pb1—N1—C9 | −26.9 (4) | C19—C20—C21—C22 | −1.9 (9) |
O2ii—Pb1—N1—C9 | 140.1 (3) | C20—C21—C22—C23 | −176.9 (6) |
O2—Pb1—N2—C10 | −179.4 (4) | C20—C21—C22—C27 | 2.5 (8) |
O1—Pb1—N2—C10 | 32.3 (4) | C27—C22—C23—C24 | 0.5 (9) |
N1—Pb1—N2—C10 | 98.8 (4) | C21—C22—C23—C24 | 179.9 (6) |
O1i—Pb1—N2—C10 | −34.1 (4) | C22—C23—C24—C25 | 0 (1) |
O2ii—Pb1—N2—C10 | −130.1 (4) | C23—C24—C25—C26 | −1 (1) |
O2—Pb1—N2—C18 | 3.9 (3) | Pb2—O3—C26—C25 | 178.6 (4) |
O1—Pb1—N2—C18 | −144.4 (3) | Pb2iii—O3—C26—C25 | −26.3 (7) |
N1—Pb1—N2—C18 | −77.8 (3) | Pb2—O3—C26—C27 | 1.0 (6) |
O1i—Pb1—N2—C18 | 149.2 (3) | Pb2iii—O3—C26—C27 | 156.1 (3) |
O2ii—Pb1—N2—C18 | 53.2 (3) | C24—C25—C26—O3 | −177.3 (5) |
O3—Pb2—N3—C19 | −179.0 (4) | C24—C25—C26—C27 | 0.4 (8) |
O4—Pb2—N3—C19 | 24.3 (4) | C19—N3—C27—C22 | 0.9 (7) |
N4—Pb2—N3—C19 | 92.0 (4) | Pb2—N3—C27—C22 | −179.0 (3) |
O3iii—Pb2—N3—C19 | 154.8 (4) | C19—N3—C27—C26 | 179.2 (4) |
O4iv—Pb2—N3—C19 | −49.4 (4) | Pb2—N3—C27—C26 | −0.7 (5) |
O3—Pb2—N3—C27 | 0.8 (3) | C23—C22—C27—N3 | 177.4 (5) |
O4—Pb2—N3—C27 | −155.8 (3) | C21—C22—C27—N3 | −2.0 (7) |
N4—Pb2—N3—C27 | −88.2 (3) | C23—C22—C27—C26 | −0.8 (8) |
O3iii—Pb2—N3—C27 | −25.3 (4) | C21—C22—C27—C26 | 179.8 (5) |
O4iv—Pb2—N3—C27 | 130.5 (3) | O3—C26—C27—N3 | −0.2 (7) |
O3—Pb2—N4—C28 | 19.0 (4) | C25—C26—C27—N3 | −177.9 (4) |
O4—Pb2—N4—C28 | 178.6 (4) | O3—C26—C27—C22 | 178.1 (5) |
N3—Pb2—N4—C28 | 87.6 (4) | C25—C26—C27—C22 | 0.4 (7) |
O3iii—Pb2—N4—C28 | −50.0 (4) | C36—N4—C28—C29 | 0.2 (8) |
O4iv—Pb2—N4—C28 | 147.4 (4) | Pb2—N4—C28—C29 | −172.6 (5) |
O3—Pb2—N4—C36 | −154.0 (3) | N4—C28—C29—C30 | −0 (1) |
O4—Pb2—N4—C36 | 5.6 (3) | C28—C29—C30—C31 | 0.3 (9) |
N3—Pb2—N4—C36 | −85.3 (3) | C29—C30—C31—C32 | 179.4 (6) |
O3iii—Pb2—N4—C36 | 137.0 (3) | C29—C30—C31—C36 | 1.0 (8) |
O4iv—Pb2—N4—C36 | −25.6 (4) | C30—C31—C32—C33 | −177.6 (5) |
C9—N1—C1—C2 | 0.2 (8) | C36—C31—C32—C33 | 0.9 (8) |
Pb1—N1—C1—C2 | 171.8 (4) | C31—C32—C33—C34 | −0.4 (9) |
N1—C1—C2—C3 | 0.1 (9) | C32—C33—C34—C35 | −0.5 (9) |
C1—C2—C3—C4 | −1.2 (9) | Pb2—O4—C35—C34 | −173.0 (4) |
C2—C3—C4—C5 | −176.9 (6) | Pb2—O4—C35—C36 | 6.0 (6) |
C2—C3—C4—C9 | 1.8 (9) | C33—C34—C35—O4 | 179.8 (5) |
C3—C4—C5—C6 | 177.7 (6) | C33—C34—C35—C36 | 0.9 (8) |
C9—C4—C5—C6 | −0.9 (9) | C28—N4—C36—C31 | 0.5 (7) |
C4—C5—C6—C7 | 2.1 (10) | Pb2—N4—C36—C31 | 173.9 (3) |
C5—C6—C7—C8 | −0.8 (10) | C28—N4—C36—C35 | −178.6 (5) |
Pb1—O1—C8—C7 | 166.9 (4) | Pb2—N4—C36—C35 | −5.2 (5) |
Pb1i—O1—C8—C7 | −17.8 (7) | C30—C31—C36—N4 | −1.0 (7) |
Pb1—O1—C8—C9 | −11.9 (6) | C32—C31—C36—N4 | −179.6 (4) |
Pb1i—O1—C8—C9 | 163.4 (3) | C30—C31—C36—C35 | 178.1 (5) |
C6—C7—C8—O1 | 179.6 (5) | C32—C31—C36—C35 | −0.5 (7) |
C6—C7—C8—C9 | −1.6 (8) | O4—C35—C36—N4 | −0.2 (7) |
C1—N1—C9—C4 | 0.5 (8) | C34—C35—C36—N4 | 178.7 (4) |
Pb1—N1—C9—C4 | −171.8 (4) | O4—C35—C36—C31 | −179.4 (5) |
C1—N1—C9—C8 | 179.3 (5) | C34—C35—C36—C31 | −0.4 (7) |
Symmetry codes: (i) −x+1/2, −y+3/2, −z+1; (ii) −x+1/2, −y+1/2, −z+1; (iii) −x, −y, −z+1; (iv) −x, −y+1, −z+1. |