Volume 66, 1970
From the journal:

Transactions of the Faraday Society

Reappraisal of the energetics of the thallium(I) halides

M. F. C. Ladd  and  W. H. Lee  

Abstract

The crystal energies of the thallium(I) halides, particularly TlF, have been recalculated. The results, in kcal mol–1, are TlF: –196 (–200) TlCl: –169 (–178) TlBr: –163 (–174) TlI: –157 (–168); the values in parentheses have been derived from a Born-Haber cycle. The enthalpy of hydration of the Tl+ ion is –97 kcal mol–1, and the mean molal ionic activity coefficient of TlF in saturated solution is 0.687. The interatomic bonding in the thallium(I) halides is compared with that in the silver halides.

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Article information

DOI
https://doi.org/10.1039/TF9706602767
Article type
Paper

Trans. Faraday Soc., 1970,66, 2767-2769

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Reappraisal of the energetics of the thallium(I) halides

M. F. C. Ladd and W. H. Lee, Trans. Faraday Soc., 1970, 66, 2767 DOI: 10.1039/TF9706602767

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