Issue 3, 1989
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Synthesis and absolute configuration of optically active selenoxides. X-Ray molecular structure of (–)se-4-menthyloxycarbonylphenyl 2,4,6-tri-isopropylphenyl selenoxide

Toshio Shimizu,   Koichi Kikuchi,   Yoshimitsu Ishikawa,   Isao Ikemoto,   Michio Kobayashi  and  Nobumasa Kamigata  

Abstract

Enantiomerically pure, stable 4-(methoxycarbonyl)phenyl 2,4,6-tri-isopropylphenyl selenoxide (–)-(3) was isolated by fractional recrystallization of diastereoisomeric 4-[(–)-menthyloxycarbonyl]phenyl 2,4,6-tri-isopropylphenyl selenoxide dia.-(1) followed by removal of the chiral source. The absolute configuration around the selenium atom was determined by X-ray crystallographic analysis of diastereomerically pure selenoxide (–)Se-(1).

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Article information

DOI
https://doi.org/10.1039/P19890000597
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1989, 597-602

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Synthesis and absolute configuration of optically active selenoxides. X-Ray molecular structure of (–)se-4-menthyloxycarbonylphenyl 2,4,6-tri-isopropylphenyl selenoxide

T. Shimizu, K. Kikuchi, Y. Ishikawa, I. Ikemoto, M. Kobayashi and N. Kamigata, J. Chem. Soc., Perkin Trans. 1, 1989, 597 DOI: 10.1039/P19890000597

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