Issue 0, 1984
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Structures and conformations of (–)-isobicyclogermacrenal and (–)-lepidozenal, two key sesquiterpenoids of the cis- and trans-10,3-bicyclic ring systems, from the liverwort Lepidozia vitrea : X-ray crystal structure analysis of the hydroxy derivative of (–)-isobicyclogermacrenal

Akihiko Matsuo,   Hirōshi Nozaki,   Naoji Kubota,   Seiryo Uto  and  Mitsuru Nakayama  

Abstract

The structures and absolute configurations of the two sesquiterpene aldehydes, (–)-isobicyclogermacrenal (1) and (–)-lepidozenal (2), which were isolated from the liverwort Lepidozia vitrea, have been determined on the basis of chemical and spectroscopic evidence to be (6R,7S)-6,11-cyclogermacra-1(10)-E,4E-dien-14-al and (6R,7S)-lepidoza-1 (10)E,4E-dien-14-al, consisting of the cis- and trans-10,3-bicyclic ring systems. The structure of the former (1) has been confirmed by a single-crystal X-ray analysis of its hydroxy derivative (7). The molecular conformations, biogenetical features, and biological activity are also described.

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Article information

DOI
https://doi.org/10.1039/P19840000203
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1984, 203-214

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Structures and conformations of (–)-isobicyclogermacrenal and (–)-lepidozenal, two key sesquiterpenoids of the cis- and trans-10,3-bicyclic ring systems, from the liverwort Lepidozia vitrea : X-ray crystal structure analysis of the hydroxy derivative of (–)-isobicyclogermacrenal

A. Matsuo, H. Nozaki, N. Kubota, S. Uto and M. Nakayama, J. Chem. Soc., Perkin Trans. 1, 1984, 203 DOI: 10.1039/P19840000203

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