Issue 6, 1994

Evidence for a template effect in control of organic-inorganic hybrid solid formation by intermolecular interactions

Abstract

Very fast gelation was observed in the sol–gel polycondensation of olefinic trialkoxysilanes when performed in the presence of catalytic amounts of palladium complexes. The palladium activation is proposed as proceeding by a template effect; the condensation occurred in an intramolecular manner within the coordination sphere of the metal.

Article information

Article type
Paper

J. Mater. Chem., 1994,4, 987-989

Evidence for a template effect in control of organic-inorganic hybrid solid formation by intermolecular interactions

R. J. P. Corriu, J. J. E. Moreau, P. Thépot and M. W. C. Man, J. Mater. Chem., 1994, 4, 987 DOI: 10.1039/JM9940400987

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