Issue 0, 1971
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Mössbauer spectra and structures of organotin compounds. The relationship between quadrupole splitting and intermolecular association

A. G. Maddock  and  R. H. Platt  

Abstract

The Mössbauer spectra of cyclohexyltin derivatives and of the compounds Ph2Sn(X)·[CH2]4·Sn(X)Ph2(X = I, OH, O·CO·Me, or Ph), BunSn(O·CO·Me)4–n(n= 2 or 3), and Bu2Sn maleate have been recorded. These data are used to define the range of quadrupole splittings associated with tetrahedral organotin compounds. It is shown that the simple point-charge model does not account for the quadrupole splittings of compounds with differing co-ordination numbers. Quadrupole splitting data are used empirically to discuss intermolecular association in organotin compounds.

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Article information

DOI
https://doi.org/10.1039/J19710001191
Article type
Paper

J. Chem. Soc. A, 1971, 1191-1195

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Mössbauer spectra and structures of organotin compounds. The relationship between quadrupole splitting and intermolecular association

A. G. Maddock and R. H. Platt, J. Chem. Soc. A, 1971, 1191 DOI: 10.1039/J19710001191

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