Issue 0, 1971
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Some complexes of Rhodium and Iridium halides with organic sulphides (thioethers)

J. Chatt,   G. J. Leigh,   A. P. Storace,   D. D. A. Squire  and  B. J. Starkey  

Abstract

The reactions of rhodium trichloride with monosulphides give mer-[RhCl3(PhSR)3](R = Me, Et, Prn, or Bun), and fac-[RhCl3(PhSR)3](R = Et, Prn, or Bun). Rhodium(I) sulphide complexes are much more difficult to characterise, and only polymeric materials were isolated. Iridium(I) and iridium(III) have a low affinity for mono- and di-sulphides, and the compounds isolated do not seem to be very like the analogous phosphine complexes.

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Article information

DOI
https://doi.org/10.1039/J19710000899
Article type
Paper

J. Chem. Soc. A, 1971, 899-904

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Some complexes of Rhodium and Iridium halides with organic sulphides (thioethers)

J. Chatt, G. J. Leigh, A. P. Storace, D. D. A. Squire and B. J. Starkey, J. Chem. Soc. A, 1971, 899 DOI: 10.1039/J19710000899

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